N,N'-bis(9-phenylcarbazol-3-yl)-N,N'-diphenyl-benzene-1,3-diamine | 934817-17-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-bis(9-phenylcarbazol-3-yl)-N,N'-diphenyl-benzene-1,3-diamine
• 英文别名: 1-N,3-N-diphenyl-1-N,3-N-bis(9-phenylcarbazol-3-yl)benzene-1,3-diamine
• CAS: 934817-17-1
• 化学式: C₅₄H₃₈N₄
• 分子量: 742.923
• InChiKey: JYLIWIHHHFIIJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.5
• 重原子数：
  58
• 可旋转键数：
  8
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,9-二苯基-9H-咔唑-3-胺 、 1,3-二溴苯 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 xylene 为溶剂， 反应 5.0h， 以54%的产率得到N,N'-bis(9-phenylcarbazol-3-yl)-N,N'-diphenyl-benzene-1,3-diamine
  参考文献：
  名称：

  Aromatic amine compound, and light emitting element, light emitting device, and electronic device using aromatic amine compound

  摘要：

  提供一种具有优异耐热性的芳香胺化合物是一个目标。另一个目标是提供一个具有优异耐热性的发光元件、发光装置和电子设备。提供了由通用式（1）表示的芳香胺化合物。由通用式（1）表示的芳香胺化合物具有较高的玻璃转变温度和优异的耐热性。通过将由通用式（1）表示的芳香胺化合物用于发光元件、发光装置和电子设备，可以获得具有优异耐热性的发光元件、发光装置和电子设备。

  公开号：

  US20070096639A1

文献信息

• Light-Emitting Element, Lighting Device, Light-Emitting Device, and Electronic Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160343968A1

  公开（公告）日：2016-11-24

  A light-emitting element includes a first electrode; a first light-emitting layer over the first electrode, containing a first phosphorescent compound and a first host material; a second light-emitting layer over the first light-emitting layer, containing a second phosphorescent compound and a second host material; a third light-emitting layer over the second light-emitting layer, containing a third phosphorescent compound and a third host material; and a second electrode over the third light-emitting layer. Between peaks of emission spectra of the first, second, and third phosphorescent compounds, the peak of the emission spectrum of the second phosphorescent compound is on the longest wavelength side and that of the emission spectrum of the third phosphorescent compound is on the shortest wavelength side. The third host material has higher triplet excitation energy than the first host material and the second host material.

  一个发光元件包括：第一电极；设置在第一电极上的第一发光层，包含第一磷光化合物和第一主体材料；设置在第一发光层上的第二发光层，包含第二磷光化合物和第二主体材料；设置在第二发光层上的第三发光层，包含第三磷光化合物和第三主体材料；以及设置在第三发光层上的第二电极。在第一、第二和第三磷光化合物的发射光谱的峰值之间，第二磷光化合物的发射光谱峰值位于最长波长侧，而第三磷光化合物的发射光谱峰值位于最短波长侧。第三主体材料具有高于第一主体材料和第二主体材料的三重态激发能。
• [EN] ORGANIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE<br/>[FR] COMPOSÉ ORGANIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2018167606A1

  公开（公告）日：2018-09-20

  A novel organic compound is provided. That is, a novel organic compound that is effective in improving reliability of a light-emitting element is provided. The organic compound includes a condensed ring including a pyrimidine ring and is represented by General Formula (G1). In General Formula (G1), A represents a group having 6 to 100 carbon atoms and includes at least one of an aromatic ring and a heteroaromatic ring. The aromatic ring and the heteroaromatic ring may each include a substituent. Furthermore, Q represents oxygen or sulfur. A ring X represents a substituted or unsubstituted naphthalene ring or a substituted or unsubstituted phenanthrene ring.

  提供了一种新的有机化合物。也就是说，提供了一种能够提高发光元件可靠性的新型有机化合物。该有机化合物包括一个包含嘧啶环的缩合环，并由通用式（G1）表示。在通用式（G1）中，A代表含有6至100个碳原子的基团，并且至少包括一个芳香环和一个杂芳环中的一个。芳香环和杂芳环中每个都可以包括一个取代基。此外，Q代表氧或硫。环X代表取代或未取代的萘环或取代或未取代的菲环。
• Light-Emitting Device, Electronic Device, and Lighting Device Utilizing Phosphorescence
  申请人：Seo Satoshi

  公开号：US20120274201A1

  公开（公告）日：2012-11-01

  A new light-emitting device utilizing phosphorescence is provided. Further, an electronic device and a lighting device which utilize phosphorescence are provided. One embodiment of the present invention is a light-emitting device including a phosphorescent organometallic iridium complex comprising iridium and either pyrimidine having an aryl group at the 4-position or 1,3,5-triazine having an aryl group at the 2-position. One of nitrogen in the pyrimidine or 1,3,5-triazine is coordinated to the iridium. Also, each of the pyrimidine and 1,3,5-triazine has a substituent such as an alkyl group or an aryl group. Further the ortho position of the aryl group which is bonded to the 4-position of the pyrimidine or the 2-position of the 1,3,5-triazine is bonded to the iridium.

  提供了一种利用磷光的新型发光装置。此外，还提供了利用磷光的电子设备和照明设备。本发明的一个实施例是包括铱和在4-位具有芳基的嘧啶或在2-位具有芳基的1,3,5-三嗪的磷光有机金属铱配合物的发光装置。嘧啶或1,3,5-三嗪中的氮原子之一与铱配位。此外，嘧啶和1,3,5-三嗪中的每一个都具有诸如烷基或芳基等取代基。而且，与嘧啶的4-位或1,3,5-三嗪的2-位结合的芳基的邻位与铱结合。
• Organic Light-Emitting Element, Organometallic Complex, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120264936A1

  公开（公告）日：2012-10-18

  Disclosed is a phosphorescent organometallic complex having: a 6-membered aromatic heterocycle having a nitrogen atom; iridium or platinum to which the nitrogen atom coordinates; and an aryl group which is bonded to an α-carbon of the nitrogen atom and is ortho-metalated with the iridium or platinum, where at least one of the aromatic heterocycle and the aryl group has an alicyclic hydrocarbon having an intramolecular carbon-carbon bridged bond as a substituent. The ability of the bulky structure of the alicyclic hydrocarbon to inhibit aggregation of the organometallic complex, concerted with the strong electron-donating property of the alicyclic hydrocarbon to the aromatic heterocycle or the aryl group, contributes to the increase in absorption coefficient and phosphorescent efficiency of the organometallic complex. The improved absorption coefficient and the phosphorescent efficiency allow the formation of a light-emitting element with excellent external quantum efficiency over 25%.

  本发明揭示了一种磷光有机金属配合物，其具有：含有氮原子的6元芳香杂环；氮原子与铱或铂配位；以及与氮原子的α-碳键合并与铱或铂发生邻位金属化的芳基基团，其中至少有芳香杂环和芳基基团中的一个具有作为取代基的脂环烃，其具有分子内碳-碳桥键。脂环烃的臃肿结构能够抑制有机金属配合物的聚集，与脂环烃对芳香杂环或芳基基团的强电子给体性质协同作用，有助于提高有机金属配合物的吸收系数和磷光效率。改进的吸收系数和磷光效率使得形成的发光元件具有优异的外部量子效率超过25%。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20130137866A1

  公开（公告）日：2013-05-30

  As a novel substance having a novel skeleton, a novel organometallic complex that can emit phosphorescence in the green to red wavelength region and has high emission efficiency and a high yield of synthesis is provided. One embodiment of the present invention is an organometallic complex in which a diketone having a five-membered or six-membered alicyclic structure composed of carbon and hydrogen is a ligand. In the formula, L represents a bidentate aromatic ligand and has at least a bond between carbon of an aromatic ring in the aromatic ligand and Ir. X represents a five-membered or six-membered alicycle composed of carbon and hydrogen. Further, R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms.

  作为一种具有新颖骨架的新颖物质，提供了一种可以在绿色到红色波长区发射磷光且具有高发射效率和高合成产率的新颖有机金属配合物。本发明的一个实施例是一种有机金属配合物，其中一种含有由碳和氢组成的五元或六元脂环结构的二酮作为配体。在公式中，L代表一个双齿芳香配体，并且至少有一种键连接芳香配体中芳香环的碳和铱。X代表由碳和氢组成的五元或六元脂环。此外，R1代表具有1至4个碳原子的取代或未取代的烷基基团。