6-hexyltetralin | 56598-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 6-hexyltetralin
• 英文别名: 6-Hexyl-1,2,3,4-tetrahydronaphthalene
• CAS: 56598-72-2
• 化学式: C₁₆H₂₄
• 分子量: 216.367
• InChiKey: XEERAPSBBRYSRL-UHFFFAOYSA-N

物化性质

• 沸点：
  154.0-155.4 °C(Press: 5 Torr)
• 密度：
  0.9224 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-hexyltetralin 在 三氯化铝 、 copper oxide-chromium oxide 、 硝基苯 作用下， 195.0 ℃ 、19.12 MPa 条件下， 生成 6,7-dihexyl-1,2,3,4-tetrahydro-naphthalene
  参考文献：
  名称：

  234.高分子量烃的合成。第二部分 一些二和三正烷基萘

  摘要：

  DOI：

  10.1039/jr9510001061
• 作为产物：
  描述：

  1-(5,6,7,8-tetrahydro-[2]naphthyl)-hexan-1-one 在 copper oxide-chromium oxide 作用下， 210.0 ℃ 、7.84 MPa 条件下， 生成 6-hexyltetralin
  参考文献：
  名称：

  234.高分子量烃的合成。第二部分 一些二和三正烷基萘

  摘要：

  DOI：

  10.1039/jr9510001061

文献信息

• Reduction of Molybdenum(V) Chloride with Various Reducing Metals: Reactivity Correlations with the Descendant Lewis Acids
  作者：Ryuichiro Hara、Qiaoxia Guo、Tamotsu Takahashi

  DOI：10.1246/cl.2000.140

  日期：2000.2

  Reactivity of low-valent molybdenum prepared from MoCl5 with various reducing metals in DME, was dependent on the reducing metals in the order of Al > Sn, In > Zn, Mg, Li in the case of cyclotrimerization of alkynes. This order is parallel to the acidity of the descendant Lewis acids.

  来自MoCl5与各种还原金属在DME中制备的低价钼的反应性，依赖于还原金属，对于炔烃的环三聚化反应，其顺序为：Al > Sn, In > Zn, Mg, Li。这个顺序与后续路易斯酸的酸性相对应。
• A Versatile, Functional Group‐Tolerant, and Bench‐Stable Iron Precatalyst for Building Arene and Triazine Rings by [2+2+2] Cycloadditions
  作者：William Parisot、Mansour Haddad、Phannarath Phansavath、Guillaume Lefèvre、Virginie Ratovelomanana‐Vidal

  DOI：10.1002/chem.202400096

  日期：2024.4.16

  A new [2+2+2] cycloaddition procedure relying on the use of an air-stable iron precatalyst is described, which allows the construction of aromatic and nitrogen-containing heteroaromatic rings in green solvents and mild conditions. Cycloadditions and cross-cycloadditions between 1,6- or 1,7-diynes and alkynes are reported, with a broad functional tolerance, leading to a variety of functionalizable scaffolds

  描述了一种依赖于使用空气稳定的铁预催化剂的新的[2+2+2]环加成过程，该过程允许在绿色溶剂和温和条件下构建芳香环和含氮杂芳环。据报道，1,6-或1,7-二炔与炔之间的环加成和交叉环加成具有广泛的功能耐受性，从而产生各种可功能化的支架。
• Alkyl Tetrahydronaphthalenes. II
  作者：Robert T. Hart、W. J. Georgitis、R. H. Wells

  DOI：10.1021/ja01159a050

  日期：1950.3
• Substituted benzocyclobutenes, indans, and tetralins via cobalt-catalyzed cooligomerization of .alpha.,.omega.-diynes with substituted acetylenes. Formation and synthetic utility of trimethylsilylated benzocycloalkenes
  作者：R. L. Hillard、K. Peter C. Vollhardt

  DOI：10.1021/ja00454a026

  日期：1977.6
• Construction of Hyperbranched Poly(alkenephenylene)s by Diyne Polycyclotrimerization:  Single-Component Catalyst, Glycogen-like Macromolecular Structure, Facile Thermal Curing, and Strong Thermolysis Resistance
  作者：Ronghua Zheng、Hongchen Dong、Han Peng、Jacky W. Y. Lam、Ben Zhong Tang

  DOI：10.1021/ma049871+

  日期：2004.7.1

  A "simple" catalyst of TaBr5, NbBr5, or (NbBr3CH3O)-C-.(CH2)(2)OCH3 is developed, which readily effects polycyclotrimerizations of alpha,omega-alkenediynes HCequivalent toC(CH2)(m)Cequivalent toCH, m = 4-6 [1(m)]} at room temperature, giving hyperbranched poly(alkenephenylene)s [hb-P1(m)] with high molecular weights (M. up to similar to270 x 10(3)) in high yields (normally >80%). The polymers prepared under optimal reaction conditions are completely soluble in common organic solvents such as toluene, THF, and chloroform. Spectroscopic characterizations prove that the polymers comprise of linear (L) and dendritic units (D) of 1,2,4/1,3,5-trialkylbenzenes and terminal unit (T) of 1,2,4-trialkylbenzene (or 6-alkyltetralin). The L and D units are generated by geostructurally different addition modes, similar to those used by nature to create L and D units of glycogen, a hyperbranched biopolymer. With the aids of model reactions and simulations, detailed structural analyses reveal that hb-P1(4) possesses a degree of branching of 64% and consists of 36%, 32%, and 32% of L, D, and T units, respectively, with 1,2,4-trialkylbenzene being the predominant isomeric structure (74%). The polymer shows outstanding thermal properties: it readily cures when baked at a moderate temperature of 100 degreesC and loses little of its weight when heated to a high temperature of similar to500 degreesC.