4-Acetylamino-naphthalsaeure-N-methylimid | 100880-81-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 4-Acetylamino-naphthalsaeure-N-methylimid
• 英文别名: 6-acetylamino-2-methyl-benzo[de]isoquinoline-1,3-dione；N-(2-methyl-1,3-dioxo-2,3-dihydro-1H-benz[de]isoquinolin-6-yl)-acetamide；N-(2-Methyl-1,3-dioxo-2,3-dihydro-1H-benz[de]isochinolin-6-yl)-acetamid；N-(2-methyl-1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinolin-6-yl)acetamide；N-(2-methyl-1,3-dioxobenzo[de]isoquinolin-6-yl)acetamide
• CAS: 100880-81-7
• 化学式: C₁₅H₁₂N₂O₃
• 分子量: 268.272
• InChiKey: MGXJEVIIFCRHSO-UHFFFAOYSA-N

物化性质

• 沸点：
  551.5±33.0 °C(Predicted)
• 密度：
  1.413±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  66.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-Amino-naphthalsaeure-N-methylimid 、 乙酸酐 在 溶剂黄146 作用下， 生成 4-Acetylamino-naphthalsaeure-N-methylimid
  参考文献：
  名称：

  Okazaki et al., Yuki Gosei Kagaku Kyokaishi, 1956, vol. 14, p. 558,561

  摘要：

  DOI：

文献信息

• Fluorescent composition having the ability to change wavelengths of light, shaped article of said composition as a light wavelength converting element, and device for converting optical energy to electrical energy using said element
  申请人：TEIJIN LIMITED

  公开号：EP0041274A1

  公开（公告）日：1981-12-09

  A fluorescent composition consisting essentially of (1) a polymerhaving a solubility parameter of at least about 9, such as polyethylene terephthalate etc., and (2) one or more organic fluorescentsubstances, at leastone of said fluorescent substances showing difficult solubility, such as anthraquinonic pigments, such that when 0.5 part by weight of said at least one fluorescent substance and 100 parts by weight of polypropylene are mixed in the molten state at 300°C for 10 minutes and formed into a film having a thickness of about 1 mm, the film has a non-transmission index ETi (%), as defined by the following equation, of at least 7, wherein EAs is the percent light absorption of said film at 800 nm, and EAb is the percent light absorption at800 nm of a film of polypropylene having a thickness of about 1 mm, said fluorescent composition being characterized by the fact that when it is formed into a film having a thickness of about 1 mm,the film has a non-transmission index PTi (%), as defined by the following equation, of not more than 10, wherein PAs is the percent light absorption at 800 nm of said film of the fluorescent composition, and PAb is the percent light absorption at 800 nm of a film having a thickness of about 1 mm of the polymer in the fluorescent composition. Preferably, the composition is of a non-radiation type and contains at least two organic fluorescent substances, at least one of which shows difficult solubility, and at least two of which are such that the emission spectrum of one organic fluorescent substance has a wavelength common to the absorption spectrum of another organic fluorescent substance. A shaped article composed of the composition is useful for light wavelength conversion.

  一种荧光组合物，主要包括 (1) 一种溶解度参数至少为 9 左右的聚合物，如聚对苯二甲酸乙二醇酯等，以及 (2) 一种或多种有机荧光物质，其中至少有一种荧光物质具有难溶性，如蒽醌颜料。 (2) 一种或多种有机荧光物质，其中至少一种荧光物质具有难溶性，如蒽醌颜料，当 0.5 重量份的至少一种荧光物质和 100 重量份的聚丙烯在 300°C 的熔融状态下混合 10 分钟并形成厚度约为 1 毫米的薄膜时，该薄膜的不透光指数 ETi（%）（如下式定义）至少为 7、 其中 EAs 是所述薄膜在 800 纳米波长处的光吸收百分率，EAb 是厚度约为 1 毫米的聚丙烯薄膜在 800 纳米波长处的光吸收百分率、 所述荧光组合物的特征在于，当它被制成厚度约为 1 毫米的薄膜时，薄膜的非透射指数 PTi（%）（如下式所定义）不超过 10、 其中 PAs 是所述荧光组合物薄膜在 800 纳米波长处的光吸收百分率，PAb 是厚度约为 1 毫米的荧光组合物聚合物薄膜在 800 纳米波长处的光吸收百分率。 优选地，该组合物为非辐射型，包含至少两种有机荧光物质，其中至少一种有机荧光物质具有难溶性，至少两种有机荧光物质的发射光谱与另一种有机荧光物质的吸收光谱具有共同的波长。 由该组合物构成的成型物品可用于光波长转换。
• An organic thin-film el device
  申请人：NEC CORPORATION

  公开号：EP0398764A2

  公开（公告）日：1990-11-22

  An organic thin-film electroluminescence (=EL) device is provided. This device includes as a main constituent of an organic luminescent thin-film layer sandwiched between a couple of electrodes at least one of which is transparent, a naphthalimide derivative represented by the formula (I): wherein R₁, R₂ and R₃ are identical or different from each other and are selected from the group consisting of hydrogen, an alkyl group, an aryl group, a substituted alkyl group, a substituted aryl group, an alkoxyl group, an amino group and an acylamino group.

  提供了一种有机薄膜电致发光（=EL）装置。该装置包括夹在两个电极（其中至少一个是透明的）之间的有机发光薄膜层，其主要成分是由式（I）表示的萘二甲酰亚胺衍生物： 其中 R₁、R₂ 和 R₃ 彼此相同或不同，并且选自由氢、烷基、芳基、取代的烷基、取代的芳基、烷氧基、氨基和酰氨基组成的组。
• INTERLAYER FILM FOR LAMINATED GLASS, AND LAMINATED GLASS
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP3202737A1

  公开（公告）日：2017-08-09

  The present invention aims to provide an interlayer film for laminated glass which prevents a double image phenomenon in a specific area of laminated glass and enables display of high contrast images at a luminance within a certain range. The present invention also aims to provide a laminated glass including the interlayer film for laminated glass. The present invention relates to an interlayer film for laminated glass, having a multilayer structure including a luminescent layer and a resin layer on at least one surface of the luminescent layer. The luminescent layer contains a thermoplastic resin, a plasticizer, and a luminescent material. The resin layer contains a thermoplastic resin and a plasticizer. The interlayer film for laminated glass has a wedge-shaped cross-sectional shape. The luminescent layer has a difference between the maximum thickness and the minimum thickness of 100 µm or less.

  本发明旨在提供一种夹层玻璃用中间膜，它能防止夹层玻璃特定区域出现重影现象，并能在一定亮度范围内显示高对比度图像。本发明还旨在提供一种夹层玻璃，其中包括用于夹层玻璃的中间膜。本发明涉及一种夹层玻璃用中间膜，它具有多层结构，包括发光层和发光层至少一个表面上的树脂层。发光层包含热塑性树脂、增塑剂和发光材料。树脂层包含热塑性树脂和增塑剂。夹层玻璃用中间膜的横截面形状为楔形。发光层的最大厚度与最小厚度之差不超过 100 微米。
• THERMOPLASTIC FILM AND LAMINATED GLASS
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：EP3943295A1

  公开（公告）日：2022-01-26

  A thermoplastic film 10 is a thermoplastic film comprising a light-emitting layer 11, wherein the light-emitting layer 11 comprises a thermoplastic resin and a light-emitting material that emits light by being irradiated with excitation light, and a change in yellowness of laminated glass obtained by bonding two sheets of clear glass in accordance with JIS R 3211(1998) having a thickness of 2.5 mm with the thermoplastic film interposed therebetween after conducting a light resistance test for 2000 hours based on JIS R3205 2005 is 4 or less. The present invention provides a thermoplastic film comprising a light-emitting material, in which the emission intensity is unlikely to lower even when the thermoplastic film is exposed to ultraviolet rays for a long period of time.

  一种热塑性薄膜10是一种包含发光层11的热塑性薄膜，其中发光层11由热塑性树脂和发光材料组成，该发光材料通过被激发光照射而发光，并且在根据JIS R3205 2005进行2000小时耐光性测试后，将两片厚度为2.5毫米、中间夹有热塑性薄膜的符合JIS R 3211(1998)的透明玻璃粘合而得到的夹层玻璃的黄度变化为4或以下。本发明提供了一种包含发光材料的热塑性薄膜，即使该热塑性薄膜长期暴露在紫外线下，其发光强度也不会降低。
• Interlayer film for laminated glass, and laminated glass
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：US10562276B2

  公开（公告）日：2020-02-18

  The present invention aims to provide an interlayer film for laminated glass which prevents a double image phenomenon in a specific area of laminated glass and enables display of high contrast images at a luminance within a certain range. The present invention also aims to provide a laminated glass including the interlayer film for laminated glass. The present invention relates to an interlayer film for laminated glass, having a multilayer structure including a luminescent layer and a resin layer on at least one surface of the luminescent layer. The luminescent layer contains a thermoplastic resin, a plasticizer, and a luminescent material. The resin layer contains a thermoplastic resin and a plasticizer. The interlayer film for laminated glass has a wedge-shaped cross-sectional shape. The luminescent layer has a difference between the maximum thickness and the minimum thickness of 100 μm or less.

  本发明旨在提供一种夹层玻璃用中间膜，它能防止夹层玻璃特定区域出现重影现象，并能在一定亮度范围内显示高对比度图像。本发明还旨在提供一种夹层玻璃，其中包括用于夹层玻璃的中间膜。本发明涉及一种夹层玻璃用中间膜，它具有多层结构，包括发光层和发光层至少一个表面上的树脂层。发光层包含热塑性树脂、增塑剂和发光材料。树脂层包含热塑性树脂和增塑剂。夹层玻璃用中间膜的横截面形状为楔形。发光层的最大厚度与最小厚度之差不超过 100 微米。