9,9-dimethyl-N-phenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine | 1160294-59-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9,9-dimethyl-N-phenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine
• 英文别名: methyl 2-bromoacetate；9,9-dimethyl-N-phenyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-fluoren-2-amine；9,9-dimethyl-N-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]fluoren-2-amine
• CAS: 1160294-59-6
• 化学式: C₄₅H₃₄N₂
• 分子量: 602.778
• InChiKey: QUSBGJQBCNEPES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺	4-(9-phenyl-9H-carbazol-3-yl)diphenylamine	1072194-21-8	C30H22N2	410.518
  2-氨基-9,9-二甲基芴	9,9-dimethyl-9H-fluoren-2-amine	108714-73-4	C15H15N	209.291
  3-(4-溴苯基)-9-苯基咔唑	3-(4-bromophenyl)-9-phenyl-9H-carbazole	1028647-93-9	C24H16BrN	398.302

反应信息

• 作为产物：
  描述：

  2-氨基-9,9-二甲基芴 在 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 38.0h， 生成 9,9-dimethyl-N-phenyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluoren-2-amine
  参考文献：
  名称：

  정공수송 화합물 및 이를 포함한 유기 발광 소자

  摘要：

  这项发明涉及化学式1所表示的正电荷传输化合物及包含它的有机发光器件：[化学式1]

  公开号：

  KR20210070469A

文献信息

• [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE<br/>[FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2009072587A1

  公开（公告）日：2009-06-11

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independenly 0 or 1.

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。
• ORGANOMETALLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20170033300A1

  公开（公告）日：2017-02-02

  An organometallic compound represented by Formula 1: wherein, in Formula 1, groups and variables are the same as described in the specification.

  由Formula 1表示的一个有机金属化合物： 在Formula 1中，各个基团和变量与说明书中描述的相同。
• Organic Compound, Light-Emitting Element, Display Module, Lighting Module, Light-Emitting Device, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150243892A1

  公开（公告）日：2015-08-27

  A light-emitting element with high emission efficiency. The light-emitting element includes a pair of electrodes and an EL layer between the pair of electrodes. In the light-emitting element, the EL layer contains at least a light-emitting material, the light-emitting material is a 1,6-bis(diphenylamino)pyrene derivative, and a structural change between an excited state and a ground state in the 1,6-bis(diphenylamino)pyrene derivative is smaller than that in a 1,6-bis(diphenylamino)pyrene derivative in which hydrogen is bonded to ortho positions of two phenyl groups of each of two diphenylamino groups.

  一个发光效率高的发光元件。该发光元件包括一对电极和一对电极之间的EL层。在发光元件中，EL层包含至少一种发光材料，发光材料为1,6-双(二苯基氨基)芘衍生物，且1,6-双(二苯基氨基)芘衍生物在激发态和基态之间的结构变化小于在每个二苯基氨基组的两个苯基的邻位上连接氢的1,6-双(二苯基氨基)芘衍生物。
• COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20200270283A1

  公开（公告）日：2020-08-27

  Provided is a compound represented by Formula 1 and an organic light-emitting device including the same. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1.

  提供的是由公式1表示的化合物以及包括该化合物的有机发光设备。所述有机发光设备包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，所述有机层包括发射层和由公式1表示的化合物。
• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND DIAGNOSTIC COMPOSITION INCLUDING THE ORGANOMETALLIC COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20210347798A1

  公开（公告）日：2021-11-11

  Provided are an organometallic compound represented by Formula 1, an organic light-emitting device including the organometallic compound, and a diagnostic composition including the organometallic compound. In Formula 1, substituents may be understood as described in the detailed description.

  提供了一种由公式1表示的有机金属化合物、包括该有机金属化合物的有机发光二极管以及包括该有机金属化合物的诊断组合物。在公式1中，取代基可以理解为如详细描述中所述。