3-methyl-5-phenyl-5H-dibenzo[b,f]azepine | 1414856-74-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-methyl-5-phenyl-5H-dibenzo[b,f]azepine
• 英文别名: 2-Methyl-11-phenylbenzo[b][1]benzazepine
• CAS: 1414856-74-8
• 化学式: C₂₁H₁₇N
• 分子量: 283.373
• InChiKey: QQIWZDXJNHRDQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (Z)-2-bromo-1-(2-bromostyryl)-4-methylbenzene 、 苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 caesium carbonate 、 双(2-二苯基磷苯基)醚 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以67%的产率得到3-methyl-5-phenyl-5H-dibenzo[b,f]azepine
  参考文献：
  名称：

  Palladium-catalyzed double N-arylation to synthesize multisubstituted dibenzoazepine derivatives

  摘要：

  Palladium-catalyzed double N-arylation of primary amines with (Z)-1,2-bis(2-bromophenyl)ethenes was investigated. A variety of dibenzoazepine derivatives were synthesized in good to excellent yields. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.09.042

文献信息

• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Shin Hyo Nim

  公开号：US20090260686A1

  公开（公告）日：2009-10-22

  The present invention relates to novel organic electroluminescent compounds, and organic electroluminescent devices employing the same as electroluminescent material. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, A and B independently represent CR 7 or N, provided that both A and B cannot be CR 7 or N at the same time; and X is O or S. Since the organic electroluminescent compounds according to the invention have good luminous efficiency and excellent color purity and life property of material, OLED's having very good operation life can be manufactured therefrom.
• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Eum Sung Jin

  公开号：US20100033083A1

  公开（公告）日：2010-02-11

  Provided are novel organic electroluminescent compounds, and organic electroluminescent devices and organic solar cells employing the same. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, A, B, C and D independently represent CR 5 or N, provided that A, B, C and D cannot represent CR 5 all at the same time. Since the organic electroluminescent compounds according to the invention have good luminous efficiency and excellent color purity and life property of material, OLED's having very good operation life can be manufactured therefrom.
• Novel organic electroluminescent compounds and organic electrouminescent device using the same
  申请人：EUM SUNG JIN

  公开号：US20100096982A1

  公开（公告）日：2010-04-22

  Provided are novel organic electroluminescent compounds and organic electroluminescent devices and organic solar cells comprising the same. Specifically, the organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, R 1 through R 10 cannot be hydrogen all at the same time. The organic electroluminescent compounds according to the invention exhibit high luminous efficiency and excellent color purity and life property of material, so that an OLED having very good operation life can be manufactured therefrom.
• US7888863B2
  申请人：——

  公开号：US7888863B2

  公开（公告）日：2011-02-15
• US8153279B2
  申请人：——

  公开号：US8153279B2

  公开（公告）日：2012-04-10