Cinnamyl valerate | 10482-65-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cinnamyl valerate
• 英文别名: [(E)-3-phenylprop-2-enyl] pentanoate
• CAS: 10482-65-2
• 化学式: C₁₄H₁₈O₂
• mdl: MFCD00797975
• 分子量: 218.29
• InChiKey: FLSKWIBFXUNBAW-JXMROGBWSA-N

物化性质

• 沸点：
  328.8±21.0 °C(Predicted)
• 密度：
  1.008±0.06 g/cm3(Predicted)
• LogP：
  4.212 (est)
• 保留指数：
  1705

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.357
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Method for Producing Optically Active Alpha-Ionone
  申请人：Yamamoto Tetsuya

  公开号：US20090216039A1

  公开（公告）日：2009-08-27

  Provided that a method for inexpensively producing optically active α-ionone with a high yield and a high asymmetric yield and with good workability in a short process, and a perfume composition comprising the optically active α-ionone obtained by the aforementioned method. A method for producing optically active α-ionone, comprising allowing α-ionone as a mixture of optical isomers to react with an esterification agent, and hydrolyzing the obtained α-ionone enol ester; a method for producing optically active α-ionone comprising subjecting α-ionone as a mixture of optical isomers to an asymmetric reduction, allowing the obtained optically active α-ionol to react with an esterification agent to give an optically active α-ionol ester, hydrolyzing the obtained optically active α-ionol ester after purification as necessary, and then oxidizing the obtained optically active α-ionol; and a perfume composition comprising thus obtained optically active α-ionone.

  提供一种以低成本高产率和高对映选择性的方法制备光学活性α-离子酮，并在短时间内具有良好的可操作性，以及包括上述方法获得的光学活性α-离子酮的香水组合物。一种制备光学活性α-离子酮的方法，包括将光学异构体混合物α-离子酮与酯化剂反应，并水解所得的α-离子酮烯醇酯；一种制备光学活性α-离子酮的方法，包括将光学异构体混合物α-离子酮进行不对称还原，使得所得的光学活性α-离子醇与酯化剂反应，得到光学活性α-离子醇酯，必要时纯化后水解所得的光学活性α-离子醇酯，然后氧化所得的光学活性α-离子醇；以及包括上述所得光学活性α-离子酮的香水组合物。
• METHOD FOR PRODUCING OPTICALLY ACTIVE a-IONONE
  申请人：Yamamoto Tetsuya

  公开号：US20110118500A1

  公开（公告）日：2011-05-19

  Provided that a method for inexpensively producing optically active α-ionone with a high yield and a high asymmetric yield and with good workability in a short process, and a perfume composition comprising the optically active α-ionone obtained by the aforementioned method. A method for producing optically active α-ionone, comprising allowing α-ionone as a mixture of optical isomers to react with an esterification agent, and hydrolyzing the obtained α-ionone enol ester; a method for producing optically active α-ionone comprising subjecting α-ionone as a mixture of optical isomers to an asymmetric reduction, allowing the obtained optically active α-ionol to react with an esterification agent to give an optically active α-ionol ester, hydrolyzing the obtained optically active α-ionol ester after purification as necessary, and then oxidizing the obtained optically active α-ionol; and a perfume composition comprising thus obtained optically active α-ionone.

  提供一种廉价高产、高对映选择性并具有良好可操作性的短流程制备光学活性α-离子酮的方法，以及包含上述方法得到的光学活性α-离子酮的香料组合物。制备光学活性α-离子酮的方法包括将光学异构体混合物的α-离子酮与酯化试剂反应，并水解所得的α-离子酮烯醇酯；制备光学活性α-离子酮的方法包括将光学异构体混合物的α-离子酮进行不对称还原，使所得的光学活性α-离子醇与酯化试剂反应以得到光学活性α-离子醇酯，在必要时经过纯化后水解所得的光学活性α-离子醇酯，然后将所得的光学活性α-离子醇进行氧化；以及包含所得光学活性α-离子酮的香料组合物。
• US7902404B2
  申请人：——

  公开号：US7902404B2

  公开（公告）日：2011-03-08
• US8053592B2
  申请人：——

  公开号：US8053592B2

  公开（公告）日：2011-11-08