Bis-(2-hydroxy-5-methyl-3-t-butylphenyl)sulfoxide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis-(2-hydroxy-5-methyl-3-t-butylphenyl)sulfoxide
• 英文别名: 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfinyl-4-methylphenol
• 化学式: C₂₂H₃₀O₃S
• 分子量: 374.5
• InChiKey: UYCYHQZXSNDUEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  76.7
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Organoaluminum catalyst
  申请人：——

  公开号：US20040142814A1

  公开（公告）日：2004-07-22

  An organoaluminum reaction product of A.) a ligand of the formula I, wherein R 1 represents an alkyl, aryl, arylalkyl, or alkylaryl group, a C 3-24 silyl group, or hydrogen, R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 12 , and R 13 are the same or different and represent an alkyl, aryl, arylalkyl, or alkylaryl group, a C 3-24 silyl group, halide, or hydrogen, with the proviso that at least one of the groups R 4 and R 13 represents hydrogen, R 8 represents an alkoxy, alkyl, aryl, arylalkyl, or alkylaryl group, a C 3-24 silyl group, halide, hydroxyl radical, or hydrogen, E represents O, S, Se, or Te, and n is an integer from 1 to 4, and B.) an aluminum compound of formula AlR 9 R 10 R 11 , wherein R 9 and R 10 are the same or different and represent C 1-20 alkyl, aryl, arylalkyl, or alkylaryl group, or hydrogen, and R 11 is a C 1-20 alkyl, aryl, arylalkyl, alkylaryl or alkoxy group, hydrogen, or halogen is useful as a polymerization catalyst, particularly for the homopolymerization or copolymerization of an alkylene oxide.

  一种有机铝反应产物，其包括A.) 公式I的配体，其中R1代表烷基、芳基、芳基烷基或烷基芳基、C3-24硅基或氢原子，R2、R3、R4、R5、R6、R7、R12和R13相同或不同，代表烷基、芳基、芳基烷基或烷基芳基、C3-24硅基、卤素或氢原子，但至少其中的一个R4和R13代表氢原子，R8代表烷氧基、烷基、芳基、芳基烷基或烷基芳基、C3-24硅基、卤素、氢氧自由基或氢原子，E代表O、S、Se或Te，n为1至4的整数，以及B.) 公式AlR9R10R11的铝化合物，其中R9和R10相同或不同，代表C1-20烷基、芳基、芳基烷基或烷基芳基或氢原子，而R11为C1-20烷基、芳基、芳基烷基、烷基芳基或烷氧基、氢原子或卤素，可用作聚合催化剂，特别适用于烷基氧化物的均聚或共聚。
• Olefin polymerization catalysts and olefin polymer production methods using said olefin polymerization catalysts
  申请人：JSR Corporation

  公开号：EP1046654A1

  公开（公告）日：2000-10-25

  An object of this invention is to provide a polymerization catalyst that can be used for the polymerization of olefins. Another object of this invention is to present a method of producing excellent olefin polymers with high copolymerization properties and high molecular weight using the polymerization catalyst. The catalyst of this invention is an olefin polymerization catalyst which contains a reaction product obtained from vanadium oxytrichloride and 2,2'-thiobis(6-5-butyl-4-methylphenyl), an organic aluminum compound, such as trimethylaluminum, and an ionized ionic compound, such as N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, and the like. By using this catalyst to polymerize ethylene with an α-olefin, such as propylene, 1-heptene, 1-octene, and the like., or a non-conjugated diene, such as 5-ethylidene-2-norbornene, and the like., a polymer of high copolymerization properties can be obtained.

  本发明的一个目的是提供一种可用于烯烃聚合的聚合催化剂。本发明的另一个目的是提出一种使用该聚合催化剂生产具有高共聚合性能和高分子量的优良烯烃聚合物的方法。本发明的催化剂是一种烯烃聚合催化剂，它含有由三氯氧钒和 2,2'-硫代双（6-5-丁基-4-甲基苯基）、有机铝化合物（如三甲基铝）和离子化离子化合物（如 N,N-二甲基苯胺四（五氟苯基）硼酸酯）等得到的反应产物。使用这种催化剂使乙烯与α-烯烃（如丙烯、1-庚烯、1-辛烯等）或非共轭二烯（如 5-亚乙基-2-降冰片烯等）聚合，可获得共聚性能高的聚合物。
• Organic semiconductor composition, organic thin film transistor, electronic paper and display device
  申请人：FUJIFILM CORPORATION

  公开号：US10008682B2

  公开（公告）日：2018-06-26

  The present invention provides an organic semiconductor composition, which improves the insulation reliability of an organic thin film transistor without greatly reducing the mobility of the organic thin film transistor, and an organic thin film transistor, electronic paper, and a display device which are prepared by using the organic semiconductor composition. The organic semiconductor composition of the present invention contains an organic semiconductor material and an anti-migration agent containing at least either a compound X, which contains at least two or more groups selected from the group consisting of a group represented by Formula (A) and a group represented by Formula (B), or a compound Y which is represented by Formula (C).

  本发明提供了一种有机半导体组合物，它能在不大大降低有机薄膜晶体管的迁移率的情况下，提高有机薄膜晶体管的绝缘可靠性，还提供了使用该有机半导体组合物制备的有机薄膜晶体管、电子纸和显示装置。本发明的有机半导体组合物含有一种有机半导体材料和一种抗迁移剂，其中至少含有一种化合物 X（该化合物含有至少两个或两个以上选自由式（A）表示的基团和由式（B）表示的基团组成的组的基团）或一种由式（C）表示的化合物 Y。
• ORGANOALUMINIUM CATALYST, ITS PREPARATION AND ITS USE IN A PROCESS FOR THE POLYMERIZATION OF ALKYLENE OXIDES
  申请人：Union Carbide Chemicals & Plastics Technology LLC

  公开号：EP1406726B1

  公开（公告）日：2009-08-26
• COMPOSITION FOR FORMING ORGANIC SEMICONDUCTOR FILM, ORGANIC THIN FILM TRANSISTOR, ELECTRONIC PAPER, AND DISPLAY DEVICE
  申请人：FUJIFILM CORPORATION

  公开号：US20170346018A1

  公开（公告）日：2017-11-30

  An object of the present invention is to provide a composition for forming an organic semiconductor film that is excellent in printing properties and makes is possible to prepare an organic thin film transistor excellent in mobility and insulation reliability. Another object of the present invention is to provide an organic thin film transistor, electronic paper, and a display device. The composition for forming an organic semiconductor film of the present invention contains an organic semiconductor material, a phenolic reductant, a polymer compound having a weight-average molecular weight of equal to or greater than 500,000, a surfactant, and an organic solvent having a standard boiling point of equal to or higher than 150° C., in which a ratio of a content of the organic semiconductor material to a content of the polymer compound is 0.02 to 10 based on mass, and a ratio of a content of the phenolic reductant to the content of the polymer compound is 0.1 to 5 based on mass.