1-oxido-N-(pyridin-2-ylmethylideneamino)pyridin-1-ium-4-carboxamide | 305340-67-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-oxido-N-(pyridin-2-ylmethylideneamino)pyridin-1-ium-4-carboxamide
• CAS: 305340-67-4
• 化学式: C₁₂H₁₀N₄O₂
• 分子量: 242.237
• InChiKey: IPBUEDVAIFDVKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  79.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  nickel(II) perchlorate hexahydrate 、 1-oxido-N-(pyridin-2-ylmethylideneamino)pyridin-1-ium-4-carboxamide 以 not given 为溶剂， 生成 mer-Ni(C5H4NCHNNHCOC5H4NO)(C5H4NCHNNCOC5H4NO)ClO4
  参考文献：
  名称：

  Lanthanide−Transition Heterometallic Extended Structures with Novel Orthogonal Metalloligand as Building Block

  摘要：

  One-dimensional lanthanice-transition heterometallic chains of squares, {LnNi(2)L(3)(HL)(DMF)(4)(CIO4)(4).S}(infinity) (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and {LnNi(2)L(4)-(DMF)(4)(CIO4)(3).S}(infinity) (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L](+) and the Ln(III) ions, which act as the bridging units and nodes, respectively.

  DOI：

  10.1021/ic026271n

文献信息

• Lanthanide−Transition Heterometallic Extended Structures with Novel Orthogonal Metalloligand as Building Block
  作者：Zheng He、Cheng He、En-Qing Gao、Zhe-Ming Wang、Xiao-Fan Yang、Chun-Sheng Liao、Chun-Hua Yan

  DOI：10.1021/ic026271n

  日期：2003.4.1

  One-dimensional lanthanice-transition heterometallic chains of squares, LnNi(2)L(3)(HL)(DMF)(4)(CIO4)(4).S}(infinity) (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and LnNi(2)L(4)-(DMF)(4)(CIO4)(3).S}(infinity) (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L](+) and the Ln(III) ions, which act as the bridging units and nodes, respectively.