5-chlorocyclooct-1-ene | 1855-55-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5-chlorocyclooct-1-ene
• 英文别名: 5-chlorocyclooctene
• CAS: 1855-55-6
• 化学式: C₈H₁₃Cl
• 分子量: 144.644
• InChiKey: RBCRLXISAJPFGG-UHFFFAOYSA-N

物化性质

• 沸点：
  71-72 °C(Press: 10 Torr)
• 密度：
  0.97±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,5-cis,cis-cyclooctadiene 在 四氯化碳 、 copper(II) choride dihydrate 、 chromium(III) acetylacetonate 、 水 作用下， 生成 9-oxa-bicyclo[4.2.1]nonane 、 9-oxabicyclo[3.3.1]nonane 、 1,2,3,3a,4,6alpha-六氢并环戊二烯 、 5-chlorocyclooct-1-ene 、 5-hydroxy-1-cyclooctene
  参考文献：
  名称：

  Telomerization of Z,Z-cyclooctadiene with halomethanes catalyzed by chromium, copper, and molybdenum compounds in the presence of water

  摘要：

  The telomerization of 1Z,5Z-cyclooctadiene with halogenated methanes (CCl4, CBrCl3, CHCl3, CH2Cl2) mediated by chromium, copper, and molybdenum complexes has been investigated. It has been shown that the use of water as a nucleophilic additive promotes the formation of 1,4- and 1,5-epoxycyclooctanes and anti-8-(trichloromethyl)bicyclo[3.2.1]octan-exo-2-ol.

  DOI：

  10.1134/s0965544111060107

文献信息

• Telomerization of Z,Z-cyclooctadiene with halomethanes catalyzed by chromium, copper, and molybdenum compounds in the presence of water
  作者：R. I. Khusnutdinov、N. A. Shchadneva、T. M. Oshnyakova、U. M. Dzhemilev

  DOI：10.1134/s0965544111060107

  日期：2011.11

  The telomerization of 1Z,5Z-cyclooctadiene with halogenated methanes (CCl4, CBrCl3, CHCl3, CH2Cl2) mediated by chromium, copper, and molybdenum complexes has been investigated. It has been shown that the use of water as a nucleophilic additive promotes the formation of 1,4- and 1,5-epoxycyclooctanes and anti-8-(trichloromethyl)bicyclo[3.2.1]octan-exo-2-ol.