2-Sulfanylideneindene-1,3-dione | 289899-83-8

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 2-Sulfanylideneindene-1,3-dione
• 英文别名: 2-sulfanylideneindene-1,3-dione
• CAS: 289899-83-8
• 化学式: C₉H₄O₂S
• 分子量: 176.196
• InChiKey: XEVAYOIXRJHPEW-UHFFFAOYSA-N

物化性质

• 沸点：
  339.0±25.0 °C(Predicted)
• 密度：
  1.47±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  反式环辛烯 、 2-Sulfanylideneindene-1,3-dione 以 甲苯 、 苯 为溶剂， 反应 0.08h， 生成 trans-2,3-[1',2',3',4',5',6'-hexahydrocycloocta]-2,3-dihydro-indeno[1,2-b][1,4]oxathiin-9-one
  参考文献：
  名称：

  An α,α‘-Dioxothione and Its [4 + 2] Cycloaddition with trans-Cyclooctene in the Reaction of Ninhydrin with Potassium Thiotosylate

  摘要：

  [GRAPHICS]In the reaction of Ninhydrin (1a)/1,2,3 indantrione (1b) with potassium thiotosylate, 1,4-oxathiin 6 is formed in up to 63% yield as the trapping product of the intermediary alpha,alpha'-dioxothione 1c with trans-cyclooctene (3a). Additionally, up to 18% of the available sulfur is transferred to olefin 3a to thiirane 3b through the intermediary oxathiirane.

  DOI：

  10.1021/ol000154j
• 作为产物：
  描述：

  1,2,3-茚满三酮 在 劳森试剂 作用下， 以 甲苯 、 苯 为溶剂， 反应 0.08h， 生成 2-Sulfanylideneindene-1,3-dione
  参考文献：
  名称：

  An α,α‘-Dioxothione and Its [4 + 2] Cycloaddition with trans-Cyclooctene in the Reaction of Ninhydrin with Potassium Thiotosylate

  摘要：

  [GRAPHICS]In the reaction of Ninhydrin (1a)/1,2,3 indantrione (1b) with potassium thiotosylate, 1,4-oxathiin 6 is formed in up to 63% yield as the trapping product of the intermediary alpha,alpha'-dioxothione 1c with trans-cyclooctene (3a). Additionally, up to 18% of the available sulfur is transferred to olefin 3a to thiirane 3b through the intermediary oxathiirane.

  DOI：

  10.1021/ol000154j

文献信息

• An α,α‘-Dioxothione and Its [4 + 2] Cycloaddition with <i>trans</i>-Cyclooctene in the Reaction of Ninhydrin with Potassium Thiotosylate
  作者：Waldemar Adam、Bettina Fröhling

  DOI：10.1021/ol000154j

  日期：2000.8.1

  [GRAPHICS]In the reaction of Ninhydrin (1a)/1,2,3 indantrione (1b) with potassium thiotosylate, 1,4-oxathiin 6 is formed in up to 63% yield as the trapping product of the intermediary alpha,alpha'-dioxothione 1c with trans-cyclooctene (3a). Additionally, up to 18% of the available sulfur is transferred to olefin 3a to thiirane 3b through the intermediary oxathiirane.