(5E)-5-{[4-(Diethylamino)phenyl]methylidene}-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (5E)-5-{[4-(Diethylamino)phenyl]methylidene}-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one
• 英文别名: (5E)-5-[[4-(diethylamino)phenyl]methylidene]-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one
• 化学式: C₁₆H₂₀N₂OS₂
• 分子量: 320.48
• InChiKey: TWKOYFGTDBBTBN-SDNWHVSQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  80.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-乙基-2-硫代-4-噻唑烷二酮 、 N,N-二乙基-4-氨基苯甲醛 在 哌啶 作用下， 以 乙醇 为溶剂， 生成 (5E)-5-{[4-(Diethylamino)phenyl]methylidene}-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one
  参考文献：
  名称：

  Rhodanine-methine as π-electron acceptor in second-order nonlinear optical chromophores

  摘要：

  DOI：

  10.1016/s0040-4039(00)76683-4

文献信息

• Oxime derivatives and their use in photopolymerizable compositions for colour filters
  申请人：FUJIFILM Corporation

  公开号：EP2105443A1

  公开（公告）日：2009-09-30

  The present invention provides a compound represented by the following Formula (1): wherein R, Y1 and Z each independently represent a monovalent substituent, n1 represents an integer of 0 to 4, Y1 and Z may be bound to each other to form a ring, and A represents a divalent linking group.

  本发明提供了由下式（1）表示的化合物： 其中 R、Y1 和 Z 各自独立地代表一价取代基，n1 代表 0 至 4 的整数，Y1 和 Z 可相互结合形成环，A 代表二价连接基团。
• Polymerizable composition, light-shielding color filter, black curable composition, light-shielding color filter for solid-state image pickup device and method of producing the same, and solid-state image pickup device
  申请人：FUJIFILM Corporation

  公开号：EP2112182A1

  公开（公告）日：2009-10-28

  A polymerizable composition includes a titanium black dispersion containing titanium black and an alkali-soluble resin having at least one unsaturated double bond, a polymerizable compound, and a photopolymerization initiator. A black curable composition includes titanium black, an alkali-soluble resin having a weight average molecular weight of from 2000 to less than 20,000 or a weight average molecular weight of 20,000 to 100,000, a solvent, a photopolymerization initiator, and a compound having an ethylenic unsaturated double bond. A light-shielding color filter having a colored region is formed using the polymerizable composition or the black curable composition. A solid-state image pickup device has the light-shielding color filter.

  一种可聚合组合物包括含有钛黑和至少有一个不饱和双键的碱溶性树脂的钛黑分散体、一种可聚合化合物和一种光聚合引发剂。一种黑色固化组合物包括钛黑、重量平均分子量为 2000 至小于 20000 或重量平均分子量为 20000 至 100000 的碱溶性树脂、溶剂、光聚合引发剂和具有乙烯不饱和双键的化合物。利用可聚合组合物或黑色固化组合物形成具有彩色区域的遮光彩色滤光片。固态图像拾取装置具有该遮光彩色滤光片。
• Novel compound, polymerizable composition, color filter and production method thereof, solid-state imaging device, and planographic printing plate precursor
  申请人：FUJIFILM Corporation

  公开号：EP2141206A1

  公开（公告）日：2010-01-06

  A photopolymerizable composition is obtained which has a high sensitivity to light sources having wavelengths of around 365 nm, excellent storage stability, and can form a cured film which can prevent deterioration in film properties thereof due to heat aging. The photopolymerizable composition includes (A) an oxime polymerization initiator which has, in ethyl acetate, a molar absorption coefficient of 20,000 or more at a λmax within the wavelength range of 300 nm or more and less than 400 nm and a molar absorption coefficient of 400 or less at (λmax + 20 nm) and (B) a polymerizable compound.

  我们获得了一种可光聚合组合物，该组合物对波长约为 365 纳米的光源具有高灵敏度，贮存稳定性极佳，并可形成固化薄膜，防止因热老化而导致薄膜性能下降。该光聚合组合物包括 (A) 肟聚合引发剂，该引发剂在乙酸乙酯中，λmax 在波长范围 300 nm 以上 400 nm 以下时的摩尔吸收系数为 20,000 或更高，(λmax + 20 nm) 时的摩尔吸收系数为 400 或更低，以及 (B) 可聚合化合物。
• DISPERSION COMPOSITION, POLYMERIZABLE COMPOSITION, LIGHT-SHIELDING COLOR FILTER, SOLID-STATE IMAGE PICK-UP ELEMENT, LIQUID CRYSTAL DISPLAY DEVICE, WAFER LEVEL LENS, AND IMAGE PICK-UP UNIT
  申请人：Nagata Yuzo

  公开号：US20110124824A1

  公开（公告）日：2011-05-26

  A dispersion composition is provided in which the dispersibility of titanium black is high, the sedimentation of titanium black over time is suppressed, and overall dispersibility and storage stability are high. Further, a polymerizable composition is provided in which favorable coating property on a substrate and even film thickness can be obtained, generation of residue in an unexposed region when a pattern is formed can be suppressed, and favorable pattern shape having any steps after exposure/development can be obtained. The dispersion composition contains (A) titanium black, (B) a graft copolymer and (C) a solvent.
• NOVEL COMPOUND, POLYMERIZABLE COMPOSITION, COLOR FILTER, AND METHOD OF PRODUCING THE SAME, SOLID-STATE IMAGING DEVICE, AND PLANOGRAPHIC PRINTING PLATE PRECURSOR
  申请人：Makino Masaomi

  公开号：US20110267714A1

  公开（公告）日：2011-11-03

  Provided is a photopolymerizable composition that is highly sensitive to light having wavelengths of 365 nm and 405 nm, and is capable of forming a curable film that can suppress deterioration in physical properties of the film due to heat-aging. The photopolymerizable composition include: (A) an oxime polymerization initiator which includes a condensed ring formed by containing two or more rings selected from an aromatic ring and a heterocyclic ring, and a cyclic structure which is connected to the condensed ring, the cyclic structure containing a carbonyl group and having an oxime group directly connected to the carbonyl group; and (B) a polymerizable compound.