4,4'-((1E,1'E)-anthracene-9,10-diylbis(ethene-2,1-diyl))bis(N,N-diphenylaniline)

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-((1E,1'E)-anthracene-9,10-diylbis(ethene-2,1-diyl))bis(N,N-diphenylaniline)
• 英文别名: 9,10-Bis[4-(diphenylamino)styryl]anthracene；N,N-diphenyl-4-[(E)-2-[10-[(E)-2-[4-(N-phenylanilino)phenyl]ethenyl]anthracen-9-yl]ethenyl]aniline
• 化学式: C₅₄H₄₀N₂
• 分子量: 716.925
• InChiKey: HKRPPAJYAMXRHZ-CFTRLRGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.4
• 重原子数：
  56
• 可旋转键数：
  10
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-二苯胺基苯甲醛 、 9,10-双(二乙基膦甲基)蒽 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 18.5h， 以91%的产率得到4,4'-((1E,1'E)-anthracene-9,10-diylbis(ethene-2,1-diyl))bis(N,N-diphenylaniline)
  参考文献：
  名称：

  9-苯乙烯基蒽的发光体的结构见解：几何控制与机械荧光致变色和传感特性

  摘要：

  有机发光体已越来越多地应用于各个领域，相应的结构研究也成为热门话题，它们提供了有关分子结构与光物理性质之间关系的基本信息。本文中，方便地合成了一系列具有不同几何形状（对称DTVA，不对称TVA和CPVA）的基于9苯乙烯基蒽的发光体，以进行系统的光物理研究。靶标在固态下表现出可逆的和多样的机械荧光致变色。尤其是DTVA和TVA表现出明显更高的固态荧光量子效率和独特的AIE活性行为，在外力作用下发生相反的发射位移。此外，DTVA和TVA对聚集状态的苦味酸（PA）检测具有很高的灵敏度。这项研究可能有助于揭示发光材料的结构本质，并为新型功能发光材料的发展铺平道路。

  DOI：

  10.1002/asia.201700183

文献信息

• ALUMINUM CHELATE COMPLEX FOR ORGANIC EL MATERIAL
  申请人：MATSUO Shinji

  公开号：US20100256377A1

  公开（公告）日：2010-10-07

  This invention provides an organic EL material useful for the emissive layer of an organic EL element which deteriorates little in luminance when operated over a prolonged period of time and shows excellent durability. The material is an aluminum chelate complex which is represented by general formula (1) in which Ar 1 is a mono- or bicylic arylene group, Ar 2 is a mono- or bicyclic aryl group, R 1 -R 6 are hydrogen or hydrocarbon groups containing 1-8 carbon atoms and contains a compound represented by general formula (1) in which Ar 2 is a halogen as an impurity in an amount of 350 wt ppm or less.

  这项发明提供了一种有机EL材料，适用于有机EL元件的发射层，在长时间运行时，其亮度几乎不会退化，并且具有出色的耐久性。该材料是一种铝螯合物复合物，其由一般式（1）表示，其中Ar1是单环或双环芳烃基团，Ar2是单环或双环芳基团，R1-R6是含有1-8个碳原子的氢或烃基团，并且含有一种以卤素为杂质的化合物，其以350重量ppm或更少的量表示。
• Aluminum chelate complex for organic el material
  申请人：Matsuo Shinji

  公开号：US20070054148A1

  公开（公告）日：2007-03-08

  This invention provides an organic EL material useful for the emissive layer of an organic EL element which deteriorates little in luminance when operated over a prolonged period of time and shows excellent durability. The material is an aluminum chelate complex which is represented by general formula (1) in which Ar 1 is a mono- or bicylic arylene group, Ar 2 is a mono- or bicyclic aryl group, R 1 —R 6 are hydrogen or hydrocarbon groups containing 1-8 carbon atoms and contains a compound represented by general formula (1) in which Ar 2 is a halogen as an impurity in an amount of 350 wt ppm or less.

  本发明提供了一种有机EL材料，可用于有机EL元件的发光层，该材料在长时间运行时发光度几乎不会降低，并表现出优异的耐久性。该材料是一种铝螯合物复合物，其由一般式（1）表示，其中Ar1是单环或双环芳基烃基，Ar2是单环或双环芳基基团，R1-R6是含有1-8个碳原子的氢或碳氢基团，并且含有一种以卤素为杂质的化合物，其量为350重量ppm或以下。
• Organic optoelectronic device and display device
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US10522766B2

  公开（公告）日：2019-12-31

  The present invention relates to an organic photoelectronic device and a display device comprising the organic photoelectronic device, the organic photoelectronic device comprising: an anode; a cathode facing the anode; a light-emitting layer interposed between the anode and cathode; a hole transport layer interposed between the anode and the light-emitting layer; and an auxiliary hole transport layer interposed between the hole transport layer and the light-emitting layer, wherein the hole transport layer comprises a compound represented by Chemical formula I, and the auxiliary hole transport layer comprises a compound represented by Chemical formula II. Chemical formulas I and II are the same as set forth in the description.

  本发明涉及一种有机光电子器件和一种包含该有机光电子器件的显示装置，该有机光电子器件包括一个阳极；一个面向阳极的阴极；一个介于阳极和阴极之间的发光层；一个介于阳极和发光层之间的空穴传输层；以及一个介于空穴传输层和发光层之间的辅助空穴传输层，其中空穴传输层包括由化学式I表示的化合物，而辅助空穴传输层包括由化学式II表示的化合物。化学式 I 和 II 与说明中所述相同。
• Organic electroluminescent display device and chemical compounds for liquid crystals
  申请人：Kido Junji

  公开号：US20070164257A1

  公开（公告）日：2007-07-19

  The new organic electroluminescent display device has a carrier-transporting layer and/or an organic luminous layer composed of a nematic liquid crystal or a liquid crystal dispersing a carrier-transporting low-molecule therein. When the organic luminous layer is to be bestowed with faculty as a liquid crystal, it is made of a nematic liquid crystal. Both the carrier-transporting layer and the organic luminous layer may be bestowed with faculty as a liquid crystal. Since the liquid crystal is incorporated in the carrier-transporting layer and/or the organic luminous layer, the display device can be driven as a liquid crystal display device in a dark place by charging with a voltage lower than a light emission initiating potential. Of course, it is driven as an electroluminescent display device when it is charged with a voltage higher than the light emission initiating potential. Use of an electroluminescent liquid crystal as a organic luminous layer enables omission of a carrier-transporting layer.
• Organic Electroluminescent Display Device and Chemical Compounds for Liquid Crystals
  申请人：Kido Junji

  公开号：US20090058277A1

  公开（公告）日：2009-03-05

  The new organic electroluminescent display device has a carrier-transporting layer and/or an organic luminous layer composed of a nematic liquid crystal or a liquid crystal dispersing a carrier-transporting low-molecule therein. When the organic luminous layer is to be bestowed with faculty as a liquid crystal, it is made of a nematic liquid crystal. Both the carrier-transporting layer and the organic luminous layer may be bestowed with faculty as a liquid crystal. Since the liquid crystal is incorporated in the carrier-transporting layer and/or the organic luminous layer, the display device can be driven as a liquid crystal display device in a dark place by charging with a voltage lower than a light emission initiating potential. Of course, it is driven as an electroluminescent display device when it is charged with a voltage higher than the light emission initiating potential. Use of an electroluminescent liquid crystal as a organic luminous layer enables omission of a carrier-transporting layer.