Anisole;cumene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Anisole;cumene
• 英文别名: anisole;cumene
• 化学式: C16H20O
• 分子量: 228.33
• InChiKey: MORPQKWFZKBMAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.51
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• PURIFICATION METHOD OF ALDEHYDE COMPOUND
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20150291513A1

  公开（公告）日：2015-10-15

  The purification method of an aldehyde compound of the present invention includes a step of neutralizing a reaction solution containing an aldehyde compound by adding water and a base compound to the reaction solution, and a step of distilling the neutralized reaction solution, in which the reaction solution is obtained by reacting a compound represented by the following Formula (a1) or (a2) with hydrogen and carbon monoxide in the presence of a metal compound of groups 8 to 10 and a phosphorus compound, the phosphorus compound is represented by Formula (R 1 O) 3 P, and the base compound is at least one kind selected from among carbonate and hydrogen carbonate of metals of group I on the periodic table and carbonate and hydrogen carbonate of metals of group II on the periodic table.

  本发明的醛化合物的纯化方法包括以下步骤：通过向含有醛化合物的反应溶液中加入水和碱性化合物来中和反应溶液，以及蒸馏中和后的反应溶液。其中，该反应溶液是通过在8至10族金属化合物和磷化合物存在下，将以下式（a1）或（a2）所代表的化合物与氢气和一氧化碳反应而得到的。磷化合物由式（R1O）3P表示，碱性化合物是周期表上I族金属的碳酸盐和氢碳酸盐以及II族金属的碳酸盐和氢碳酸盐中至少选择一种。
• PROCESS FOR PRODUCING CYANONORBORNENE
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20200239408A1

  公开（公告）日：2020-07-30

  A process for producing cyanonorbornene of the present invention includes Step 1 of preparing a mixture solution including 0.5% by weight to 28% by weight of methyl bicyclononadiene, with respect to a total amount of 100% by weight of dicyclopentadiene, acrylonitrile, and the methyl bicyclononadiene, in a container, and Step 2 of reacting the bicyclopentadiene with the acrylonitrile in the presence of the methyl bicyclononadiene, in the mixture solution.

  本发明的一种生产氰基莫尔比烯的工艺包括以下步骤：第1步，准备一个混合溶液，其中包括相对于二环戊二烯、丙烯腈和甲基双环壬二烯总重量100%的混合溶液中的0.5%至28%的甲基双环壬二烯；第2步，在容器中，在甲基双环壬二烯的存在下，将二环戊二烯与丙烯腈反应。
• PROCESS FOR PRODUCING ALDEHYDE COMPOUNDS
  申请人：Kuma Shigetoshi

  公开号：US20140088321A1

  公开（公告）日：2014-03-27

  A process for producing an aldehyde compound of the invention comprising: reacting a compound represented by the following formula (a1) or (a2) with a hydrogen and a carbon monoxide in a presence of a compound containing a metal belonging to Groups 8 to 10 and a phosphorous compound so as to satisfy the following conditions (1) and (2) to synthesize an aldehyde compound; wherein the condition (1) is that a content of a metal included in the compound containing a metal belonging to Groups 8 to 10 is 0.01 ppmmol to 300 ppmmol with respect to 1 mol of the compound represented by the formula (a1) or (a2), and wherein the condition (2) is that a molar ratio represented by the phosphorous compound (mol)/the metal (mol) is 100 or more;

  一种制备本发明醛化合物的方法，包括：将下式（a1）或（a2）所表示的化合物与氢和一氧化碳在含有属于8到10族金属的化合物和磷化合物的存在下反应，以满足以下条件（1）和（2）来合成醛化合物；其中条件（1）是所含有的属于8到10族金属的化合物中金属的含量相对于下式（a1）或（a2）的1摩尔为0.01 ppmmol至300 ppmmol，条件（2）是磷化合物（mol）/金属（mol）的摩尔比为100或更多。
• METHOD FOR PURIFYING ALDEHYDE COMPOUND
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2918577A1

  公开（公告）日：2015-09-16

  The purification method of an aldehyde compound of the present invention includes a step of neutralizing a reaction solution containing an aldehyde compound by adding water and a base compound to the reaction solution, and a step of distilling the neutralized reaction solution, in which the reaction solution is obtained by reacting a compound represented by the following Formula (a1) or (a2) with hydrogen and carbon monoxide in the presence of a metal compound of groups 8 to 10 and a phosphorus compound, the phosphorus compound is represented by Formula (R1O)3P, and the base compound is at least one kind selected from among carbonate and hydrogen carbonate of metals of group I on the periodic table and carbonate and hydrogen carbonate of metals of group II on the periodic table.

  本发明的醛化合物的纯化方法包括通过向含有醛化合物的反应溶液中加入水和碱化合物来中和反应溶液的步骤，以及蒸馏中和反应溶液的步骤，其中反应溶液是由下式(a1)或(a2)表示的化合物在第8至10族金属化合物和磷化合物存在下与氢气和一氧化碳反应得到的、磷化合物由式 (R1O)3P 表示，而碱化合物至少是一种选自元素周期表中第 I 族金属的碳酸盐和碳酸氢盐以及元素周期表中第 II 族金属的碳酸盐和碳酸氢盐。
• METHOD FOR PRODUCING CYANONORBORNENE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3663280A1

  公开（公告）日：2020-06-10

  A process for producing cyanonorbornene of the present invention includes Step 1 of preparing a mixture solution including 0.5% by weight to 28% by weight of methyl bicyclononadiene, with respect to a total amount of 100% by weight of dicyclopentadiene, acrylonitrile, and the methyl bicyclononadiene, in a container, and Step 2 of reacting the bicyclopentadiene with the acrylonitrile in the presence of the methyl bicyclononadiene, in the mixture solution.

  本发明生产降冰片烯的工艺包括步骤 1：在容器中制备混合物溶液，其中包括 0.5%（重量）至 28%（重量）的甲基双环戊二烯（相对于总量为 100%（重量）的双环戊二烯、丙烯腈和甲基双环戊二烯）；步骤 2：在混合物溶液中，在甲基双环戊二烯存在的情况下，使双环戊二烯与丙烯腈反应。