bis<2-(N-benzoyl-N-methylamino)phenyl> disulfide | 57682-33-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis<2-(N-benzoyl-N-methylamino)phenyl> disulfide
• 英文别名: Di-(N-benzoyl-2-methylamino-phenyl)-disulfid；o-(N-Benzoyl-N-methylamino)-phenyldisulfid；(N-Benzoyl-N-methylamino)-phenyldisulfid；bis-[2-(benzoyl-methyl-amino)-phenyl]-disulfide；2.2'-Bis-(methyl-benzoyl-amino)-diphenyldisulfid；Bis-[2-(benzoyl-methyl-amino)-phenyl]-disulfid；N-[2-[[2-[benzoyl(methyl)amino]phenyl]disulfanyl]phenyl]-N-methylbenzamide
• CAS: 57682-33-4
• 化学式: C₂₈H₂₄N₂O₂S₂
• 分子量: 484.643
• InChiKey: UFODCAQVFFMGJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  91.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium hydroxide 、 碘 作用下， 生成 bis<2-(N-benzoyl-N-methylamino)phenyl> disulfide
  参考文献：
  名称：

  Clark, Journal of the Chemical Society, 1925, vol. 127, p. 974

  摘要：

  DOI：

文献信息

• [EN] METHODS FOR PRODUCING ARYLSULFUR PENTAFLUORIDES<br/>[FR] PROCÉDÉS DE PRODUCTION DE PENTAFLUORURES DE SOUFRE ARYLÉS
  申请人：IM & T RES INC

  公开号：WO2010014665A1

  公开（公告）日：2010-02-04

  Novel methods for preparing arylsulfur pentafluorides are disclosed. Arylsulfur halotetrafluoride is reacted with a fluoride source under hydrous conditions to form an arylsulfur pentafluoride. The purification method is also disclosed.

  揭示了制备芳基硫五氟化物的新方法。芳基硫卤四氟化物在湿润条件下与氟化物源反应，形成芳基硫五氟化物。还公开了纯化方法。
• PROCESS FOR PRODUCING ARYLSULFUR PENTAFLUORIDES
  申请人：UMEMOTO TERUO

  公开号：US20080234520A1

  公开（公告）日：2008-09-25

  Novel processes for preparing arylsulfur pentafluorides are disclosed. Processes include reacting at least one aryl sulfur compound with a halogen and a fluoro salt to form an arylsulfur halotetrafluoride. The arylsulfur halotetrafluoride is reacted with a fluoride source to form a target arylsulfur pentafluoride.

  揭示了制备芳基硫五氟化物的新工艺。该工艺包括将至少一种芳基硫化合物与卤素和氟盐反应，形成芳基硫卤四氟化物。然后将芳基硫卤四氟化物与氟化物源反应，形成目标芳基硫五氟化物。
• The reaction of 3-methylthiazolium derivatives with superoxide
  作者：Takashi Itoh、Kazuhiro Nagata、Mamiko Okada、Akio Ohsawa

  DOI：10.1016/s0040-4020(01)80403-8

  日期：1993.5

  3-Methylbenzothiazolium salts were allowed to react with superoxide to afford dimeric bis[o-(N-formyl-N-methylamino)phenyl]disulfides and 3-methyl-2-benzothiazolones. The reaction was applied to monocyclic thiazolium salts, and novel ten-membered ring compounds were formed whose structures were elucidated by X-ray crystallographic analysis. These results prompted us to alternative synthesis of the

  3-甲基苯并噻唑盐使其与过氧化物反应以得到二聚双[ ø - （Ñ甲酰基Ñ甲氨基）苯基]二硫化物和3-甲基-2- benzothiazolones。该反应被应用于单环噻唑鎓盐，并形成了新颖的十元环化合物，其结构通过X射线晶体学分析得以阐明。这些结果促使我们选择了另一种环化合物的合成方法，并显示了重氮唑盐可通过与超氧化物反应而得到。
• Process for producing arylsulfur halotetrafluorides
  申请人：UBE Industries, Ltd.

  公开号：EP2468722A1

  公开（公告）日：2012-06-27

  Novel processes for preparing arylsulfur pentafluorides are disclosed. Processes include reacting at least one aryl sulfur compound with a halogen and a fluoro salt to form an arylsufur halotetrafluoride. The arylsulfur halotetrafluoride is reacted with a fluoride source to form a target arylsulfur pentafluoride.

  本发明公开了制备芳基五氟化硫的新工艺。该工艺包括将至少一种芳基硫化合物与卤素和氟盐反应生成芳基硫卤四氟化物。该芳基四氟化硫与氟化源反应生成目标芳基五氟化硫。
• Reductive dimerization of benzothiazolium salts
  作者：Aijaz Shaikh、Satyajit Sahoo、Seth R. Marder、Stephen Barlow、Swagat K. Mohapatra

  DOI：10.1039/d3ob01871g

  日期：2024.3.6

  bibenzo[d]thiazoles. The products were obtained in a moderate to good yield, and the structures were confirmed using single-crystal X-ray diffraction. The electrochemistry and further reactivity towards different oxidants of the dimeric compounds were studied; the 2,2′-bibenzo[d]thiazoles show oxidation potentials similar to that of ferrocene and are converted back to the corresponding benzothiazolium cations by

  使用Na:Hg (1 wt%)还原2-取代的3-甲基苯并噻唑鎓盐获得了三种不同类型的反应产物。根据2-取代基的不同，获得了两种类型的二聚化合物：2-环己基-、2-苯基-和2-(对甲苯基)-取代的物质被还原为相应的2,2'-联苯并[ d] ]噻唑，而它们的 2-(( p -OMe)C 6 H 4 )- 和 2-(( p -NMe 2 )C 6 H 4 )-取代的衍生物提供顺式-[1,4]苯并噻嗪[3,2 - b ][1,4]苯并噻嗪。此外，在分子O 2存在下，由联苯并[ d ]噻唑得到了新的二硫化物衍生物。产物以中等至良好的产率获得，并且使用单晶X射线衍射证实了结构。研究了二聚化合物的电化学和对不同氧化剂的进一步反应活性； 2,2'-联苯并[ d ]噻唑表现出与二茂铁相似的氧化电位，并被TCNQ等温和氧化剂转化回相应的苯并噻唑鎓阳离子。相比之下，苯并噻嗪基-苯并噻嗪在 THF 溶剂窗口中没有显示出氧化。