4-[Benzoyl(methyl)amino]pentyl benzoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[Benzoyl(methyl)amino]pentyl benzoate
• 英文别名: 4-[benzoyl(methyl)amino]pentyl benzoate
• 化学式: C₂₀H₂₃NO₃
• 分子量: 325.4
• InChiKey: JJOKQHOYZVBAHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS
  申请人：TAFTAF Mansour

  公开号：US20160340293A1

  公开（公告）日：2016-11-24

  A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R 8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

  一种催化剂组合物，包括作为内部电子给体的化合物I的公式，其中：R1、R2、R3、R4、R5和R6分别独立地选择自由氢、直链、支链和环烷基和芳香族取代和未取代的烃基，碳原子数为1至20；R7选择自由直链、支链和环烷基和芳香族取代和未取代的烃基，碳原子数为1至20；R8选择自由芳香族取代和未取代的烃基，碳原子数为6至20。还公开了制备所述聚合催化剂组合物的方法；包括所述催化剂组合物、共催化剂和可选的外部电子给体的聚合催化剂体系；通过该方法可获得的聚烯烃；以及在烯烃聚合催化剂中使用化合物I作为内部电子给体的用途。
• POLYPROPYLENE FOR USE IN BOPP APPLICATIONS
  申请人：SABIC Global Technologies B.V.

  公开号：EP3309183A1

  公开（公告）日：2018-04-18

  The invention relates to a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most 1.0 wt% based on the propylene-ethylene copolymer having an Mw/Mn in the range from 5.0 to 12, wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight and wherein Mw and Mn are measured according to ASTM D6474-12, an XS in the range from 1.0 to 6.0 wt%, wherein XS stands for the amount of xylene solubles which are measured according to ASTM D 5492-10, a melt flow rate in the range of 1 to 10 dg/min as measured according to ISO1133 (2.16 kg/230°C) and a crystal size distribution as indicated by a height/width ratio of the highest peak of the first cooling curve of at least 0.70 J/°C as determined by ASTM D3418-08 using a heating and cooling rate of 10°C/min. Such propylene homopolymer and/or propylene-ethylene copolymer can suitably be used for the preparation of a biaxially oriented polypropylene (BOPP) film.

  本发明涉及一种丙烯均聚物或丙烯-乙烯共聚物，其乙烯含量至多为 1.0 wt%，基于丙烯-乙烯共聚物，其 Mw/Mn 在 5.0 至 12 之间，其中 Mw 代表重量平均分子量，Mn 代表数均分子量，其中 Mw 和 Mn 根据 ASTM D6474-12 测量；XS 在 1.0 至 6.0 wt%，其中 XS 代表二甲苯溶质的量，根据 ASTM D 5492-10 测量；熔体流动速率在 1 至 10 dg/min 范围内，根据 ISO1133 测量（2.16 kg/230°C）；晶体尺寸分布，根据 ASTM D3418-08 测量（加热和冷却速率为 10°C/min），第一冷却曲线最高峰的高度/宽度比至少为 0.70 J/°C。这种丙烯均聚物和/或丙烯-乙烯共聚物可用于制备双向拉伸聚丙烯（BOPP）薄膜。
• Catalyst composition for polymerization of olefins
  申请人：SAUDI BASIC INDUSTRIES CORPORATION

  公开号：US10059656B2

  公开（公告）日：2018-08-28

  A catalyst composition including the compound of Formula I as an internal electron donor, wherein: R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also disclosed is a process for preparing said polymerization catalyst composition; a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor; a polyolefin obtainable by the process; and use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

  一种催化剂组合物，包括作为内部电子供体的式 I 化合物、 其中 R1、R2、R3、R4、R5 和 R6 独立地选自氢、具有 1 至 20 个碳原子的直链、支链和环状烷基以及芳香取代和未取代的烃基；R7 选自具有 1 至 20 个碳原子的直链、支链和环状烷基以及芳香取代和未取代的烃基；以及 R8 选自具有 6 至 20 个碳原子的芳香取代和未取代的烃基。还公开了制备所述聚合催化剂组合物的工艺；包含所述催化剂组合物、助催化剂和可选的外部电子供体的聚合催化剂体系；可通过该工艺获得的聚烯烃；以及式 I 化合物作为内部电子供体在烯烃聚合催化剂中的用途。
• Procatalyst for polymerization of olefins comprising an aminobenzoate internal donor and a 1,3-diether internal donor in a specific ratio
  申请人：SABIC Global Technologies B.V.

  公开号：US10730971B2

  公开（公告）日：2020-08-04

  A process for preparing a procatalyst for polymerization of olefins, comprising contacting a magnesium-containing support with a halogen-containing titanium compound, a first internal electron donor represented by Formula A, a second internal electron donor represented by Formula B, and an activator; wherein the molar ratio of the first internal donor to the second internal donor is between 0.01 and 0.7; wherein in Formula A each R80 group is independently a substituted or unsubstituted aromatic group; and R81, R82, R83, R84, R85, R86 and R87 are each independently selected from a hydrogen or a hydrocarbyl group; wherein in Formula B R51 and R52 are each independently selected from a hydrogen or a hydrocarbyl group; and R53 and R54 are each independently selected from hydrogen, a halide or a hydrocarbyl group.

  一种制备烯烃聚合用催化剂的工艺，包括将含镁载体与含卤钛化合物、由式 A 表示的第一内部电子供体、由式 B 表示的第二内部电子供体和活化剂接触；其中第一内部供体与第二内部供体的摩尔比在 0.01 至 0.7 之间； 其中在式 A 中，每个 R80 基团独立地为取代或未取代的芳香基团；R81、R82、R83、R84、R85、R86 和 R87 基团各自独立地选自氢或烃基；其中在式 B 中，R51 和 R52 基团各自独立地选自氢或烃基；R53 和 R54 基团各自独立地选自氢、卤化物或烃基。
• Polypropylene for use in BOPP applications
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US11001651B2

  公开（公告）日：2021-05-11

  The invention relates to a biaxially oriented polypropylene (BOPP) film comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most 1.0 wt % based on the propylene-ethylene copolymer having an Mw/Mn in the range from 5.0 to 12, wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight and wherein Mw and Mn are measured according to ASTM D6474-12, an XS in the range from 1.0 to 6.0 wt %, wherein XS stands for the amount of xylene solubles which are measured according to ASTM D 5492-10, a melt flow rate in the range of 1 to 10 dg/min as measured according to IS01133 (2.16 kg/230° C.) and a crystal size distribution as indicated by a height/width ratio of the highest peak of the first cooling curve of at least 0.70 W/g° C. as determined by ASTM D3418-08 using a heating and cooling rate of 10° C./min.

  本发明涉及一种双向拉伸聚丙烯（BOPP）薄膜，该薄膜由丙烯均聚物或丙烯-乙烯共聚物组成，其乙烯含量最多为 1.0 wt %（基于丙烯-乙烯共聚物），Mw/Mn 在 5.0 至 12 之间，其中 Mw 代表重量平均分子量，Mn 代表数均分子量，其中 Mw 和 Mn 根据 ASTM D6474-12 测量；XS 在 1.0 至 6.0 wt % 之间，其中 XS 代表二甲苯溶质量，根据 ASTM D 5492-10 测量；熔体流动速率在 1 至 10 dg/min 之间。其中，XS 代表二甲苯溶质的量，根据 ASTM D 5492-10 测量；熔体流动速率在 1 至 10 dg/min 范围内，根据 IS01133 测量（2.16 kg/230°C）；晶体尺寸分布，根据 ASTM D3418-08 测定，第一冷却曲线最高峰的高度/宽度比至少为 0.70 W/g°C，加热和冷却速率为 10° C./min。