N-[4-(2-Cyano-ethylamino)-phenyl]-acetamide | 24598-48-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-(2-Cyano-ethylamino)-phenyl]-acetamide
• 英文别名: N-{4-[(2-cyanoethyl)amino]phenyl}acetamide；N-[4-(2-cyanoethylamino)phenyl]acetamide
• CAS: 24598-48-9
• 化学式: C₁₁H₁₃N₃O
• mdl: MFCD00483483
• 分子量: 203.244
• InChiKey: NBHHORSSNGGFQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.272
• 拓扑面积：
  64.9
• 氢给体数：
  2
• 氢受体数：
  3

文献信息

• Aromatic diazo compounds, production method thereof and photosensitive compositions using the same
  申请人：TOYO GOSEI KOGYO CO., LTD.

  公开号：EP0470581A2

  公开（公告）日：1992-02-12

  57 An aromatic diazo compound having at least two groups of Formula (I) in the molecule. This aromatic diazo compound can be handled under visible light free from ultraviolet, is high in photosensitivity, and can be produced by a simple synthesis method. The diazo compound has a high solubility in organic solvents, appropriate for use as a photosensitive material for a lithographic printing plate, can be easily developed by an alkaline developing solution mainly based on an alkaline aqueous solution, and has a water solubility appropriate for use in a screen printing plate. wherein Z1 indicates (wherein φ1 is arylene or substituted arylene; and -φ2 is lower alkyl, lower alkylene, or aryl or substituted aryl.) R1 and R2 are H, alkyl of C1 to C8, or alkyloxy of C1 to C8; X- is anion; and R3 indicates alkyl, saturated alkyl, aralkyl, substituted aralkyl, or a group similar to

  57 分子中至少含有两个式（I）基团的芳香重氮化合物。这种芳香重氮化合物可在可见光下处理，不受紫外线影响，光敏性高，可通过简单的合成方法制得。该重氮化合物在有机溶剂中的溶解度高，适合用作平版印刷板的感光材料，可以很容易地通过主要基于碱性水溶液的碱性显影液显影，并且具有适合用于丝网印刷板的水溶性。 其中 Z1 表示 (其中 φ1 是芳基或取代芳基；而 -φ2 是 低级烷基、低级亚烷基、芳基或取代芳基）。 R1 和 R2 是 H、C1 至 C8 的烷基或 C1 至 C8 的烷氧基；X- 是阴离子；R3 表示烷基、饱和烷基、芳烷基、取代芳烷基或与之相似的基团。
• Photosensitive polyfunctional aromatic diazo compounds and photosensitive compositions using the same
  申请人：TOYO GOSEI KOGYO CO., LTD.

  公开号：EP0580121A2

  公开（公告）日：1994-01-26

  An aromatic diazo compound is composed mainly of a compound of Formula (I) or Formula (II), and a photosensitive composition using the same. The aromatic diazo compound can be handled under a white light, is highly photosensitive, has good shelf life, is highly soluble in organic solvents, adequate as a photosensitive agent for lithographic printing plates, can be easily developed with a developing solution composed mainly of an alkaline aqueous solution, and has an appropriate water solubility as a screen printing plate: Formula (I) wherein ℓ, m, and n are integers where ℓ = 2 to 10, m = 0 to 5, n = 0 to 5, and ℓ + m + n = 2 to 20. R1 and R2 are independently hydrogen, or alkyl or alkyloxy of 1 to 8 carbon atoms; G1 is a substituent derived from alcoholic hydroxyl group; G2 is hydroxyl or the same group as G1; Q is a polyvalent group generated by reacting a compound having a reactivity to at least two oxiranes with carbon of the oxirane ring; Q1 is a monovalent group generated by reacting a compound having a reactivity to oxirane with carbon of the oxirane ring; R3 is alkyl or substituted alkyl of 1 to 8 carbon atoms, aralkyl or substituted aralkyl of 7 to 14 carbon atoms, or Q1-CH2CHG2-CH2-; X- is an anion based on protonic acid from which a proton is removed. Formula (II) wherein n1 to n' are integers from 0 to 10; n1 + n2 + n3 + ... + ni = 2 to 20; R1, R2, R3 and X- are respectively the same as those in Formula (I); G2 is hydroxyl or the same group as G1 in Formula (I), and the number of hydroxyl groups represented by G2 in one molecule of a diazo compound of Formula (II) is 0 to 10, and the number of groups same as G1 is 2 to 20; Q21 to Q2i and Qs are the same or two or more different groups, and are divalent groups generated by reacting a compound which one molecule being reactable with two oxirane rings with carbons of two oxirane rings; R4 is the same as Q1 or G2 in Formula (I), or Formula (III). Formula (III) wherein X-, R1, R2, and R3 are the same as in Formula (I).

  一种芳香重氮化合物主要由式（I）或式（II）化合物和使用该化合物的感光组合物组成。该芳香重氮化合物可在白光下处理，光敏性强，保存期长，在有机溶剂中的溶解度高，适于作为平版印刷版的感光剂，易于用主要由碱性水溶液组成的显影液显影，作为丝网印版具有适当的水溶性：式（I） 其中 ℓ、m、n 为整数，ℓ = 2 至 10，m = 0 至 5，n = 0 至 5，ℓ + m + n = 2 至 20。 R1 和 R2 独立地为氢、1 至 8 个碳原子的烷基或烷氧基； G1 是由醇羟基衍生的取代基； G2 是羟基或与 G1 相同的基团； Q 是多价基团，通过与至少两个环氧乙烷具有反应活性的化合物与环氧乙烷环的碳反应生成； Q1 是一个单价基团，通过与环氧乙烷具有反应活性的化合物反应生成； R3 是 1 至 8 个碳原子的烷基或取代烷基、7 至 14 个碳原子的芳基或取代芳基或 Q1-CH2CHG2-CH2-； X- 是基于质子酸的阴离子，其中一个质子被去除。式 (II) 其中 n1 至 n' 为 0 至 10 的整数； n1 + n2 + n3 + ...+ ni = 2 至 20；R1、R2、R3 和 X- 分别与式（I）中的相同； G2 是羟基或与式(I)中 G1 相同的基团，在一个分子的式(II)重氮化合物中，G2 所代表的羟基数目为 0 至 10，与 G1 相同的基团数目为 2 至 20； Q21 至 Q2i 和 Qs 是相同的基团或两个或两个以上不同的基团，并且是二价基团，由一个分子可与两个环氧乙烷环反应的化合物与两个环氧乙烷环的碳反应生成； R4 与式（I）或式（III）中的 Q1 或 G2 相同。式 (III) 其中 X-、R1、R2 和 R3 与式（I）中的相同。
• US5206349A
  申请人：——

  公开号：US5206349A

  公开（公告）日：1993-04-27
• US5430130A
  申请人：——

  公开号：US5430130A

  公开（公告）日：1995-07-04
• US5589315A
  申请人：——

  公开号：US5589315A

  公开（公告）日：1996-12-31