(3-Hydroperoxycyclohexyl)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-Hydroperoxycyclohexyl)benzene
• 英文别名: (3-hydroperoxycyclohexyl)benzene
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.25
• InChiKey: GQJGTLODXFMYFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Process for Producing Phenol
  申请人：EXXONMOBIL CHEMICAL PATENTS INC.

  公开号：US20150291493A1

  公开（公告）日：2015-10-15

  In a process for producing phenol and/or cyclohexanone, a cleavage reaction mixture containing cyclohexyl-1-phenyl-hydroperoxide and cyclohexylbenzene is contacted with sulfuric acid and water under cleavage conditions effective to form a cleavage reaction effluent containing phenol, cyclohexanone, cyclohexylbenzene, water, sulfuric acid and 1-phenylcyclohexanol. At least a portion of the cleavage reaction effluent is neutralized with a basic material to produce a neutralized cleavage product and at least a portion of the neutralized cleavage product is supplied in the absence of an added dehydration catalyst to a distillation column. The distillation column is operated so that at least a portion of the neutralized cleavage product is exposed to a temperature greater than 70° C. at at least one location in the distillation column whereby at least a portion of the 1-phenylcyclohexanol in the neutralized cleavage product is dehydrated to phenylcyclohexene.

  在生产苯酚和/或环己酮的过程中，将含有环己基-1-苯基-过氧化氢和环己基苯的裂解反应混合物与硫酸和水接触，在裂解条件下形成含有苯酚、环己酮、环己基苯、水、硫酸和1-苯基环己醇的裂解反应产物。至少将部分裂解反应产物中和成为中性的裂解产物，并将至少部分中性的裂解产物在无脱水催化剂的情况下供应到蒸馏塔中。蒸馏塔的操作使得至少部分中性的裂解产物在蒸馏塔的至少一个位置暴露于大于70℃的温度，从而使中性的裂解产物中的1-苯基环己醇的至少部分被脱水成为苯基环己烯。
• Process for Concentrating a Mixture Containing Organic Hydroperoxide
  申请人：EXXONMOBIL CHEMICAL PATENTS INC.

  公开号：US20160122298A1

  公开（公告）日：2016-05-05

  Method for concentrating an organic hydroperoxide mixture comprising a hydrocarbon and a hydroperoxide corresponding thereto comprises evaporating a first liquid mixture in a thin-film evaporation device followed by separation in a separation zone. Both the evaporation device and the separation zone operate at a low absolute pressure at a temperature lower than the thermal degradation temperature of the hydroperoxide to prevent thermal decomposition thereof. The process is particularly useful for concentrating an oxidation product made from the oxidation of cyclohexylbenzene.

  一种用于浓缩含有碳氢化合物和相应的有机过氧化物的混合物的方法，包括在薄膜蒸发装置中蒸发第一液体混合物，然后在分离区分离。蒸发装置和分离区都在低于过氧化物热降解温度的温度下以低绝对压力运行，以防止其热分解。该过程特别适用于浓缩由环己基苯氧化而成的氧化产物。
• PROCESS FOR CONCENTRATING A MIXTURE CONTAINING ORGANIC HYDROPEROXIDE
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP3013795B1

  公开（公告）日：2019-07-24
• Process for Producing Phenol and/or Cyclohexanone from Cyclohexylbenzene
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20150218075A1

  公开（公告）日：2015-08-06

  In a process for producing phenol and/or cyclohexanone, cyclohexylbenzene is contacted with an oxygen-containing gas to produce an oxidation effluent containing cyclohexylbenzene hydroperoxide. At least a portion of the cyclohexylbenzene hydroperoxide is then contacted with a cleavage catalyst to produce a cleavage effluent containing phenol and cyclohexanone and by-products including phenylcyclohexanol. The cleavage effluent or a neutralized product thereof also comprises at least one compound comprising an atom not being carbon, hydrogen or oxygen, which is separated from the cleavage effluent and/or the neutralized product thereof to leave a cleavage fraction lean in the compound comprising an atom not being carbon, hydrogen or oxygen and containing at least a portion of the phenylcyclohexanol. At least a portion of the phenylcyclohexanol is then contacted with a dehydration catalyst comprising a molecular sieve of the MCM-22 type to convert at least a portion of the phenylcyclohexanol to phenyl cyclohexene.
• US9278897B2
  申请人：——

  公开号：US9278897B2

  公开（公告）日：2016-03-08