phenol trimethylamine complex | 65886-46-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: phenol trimethylamine complex
• 英文别名: phenol; compound with trimethylamine；Phenol; Verbindung mit Trimethylamin；phenol, compound with trimethylamine (1:1)；Trimethylammonium phenoxide；trimethylazanium;phenoxide
• CAS: 65886-46-6
• 化学式: C₃H₉N*C₆H₆O
• 分子量: 153.224
• InChiKey: YLKXGVSMBYZCSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.57
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三甲胺 、 苯酚 以 gaseous matrix 为溶剂， 生成 phenol trimethylamine complex
  参考文献：
  名称：

  氢键复合酚三甲胺的质量选择双色多光子电离：质子化离子三甲基铵（1+）的产生

  摘要：

  DOI：

  10.1021/j100304a022

文献信息

• 1-Amido-3-(2-hydroxyphenoxy)-2-propanol derivatives and a process for preparing 2-amidomethyl-1,4-benzodioxane derivatives
  申请人：Miki Yasushi

  公开号：US20060019993A1

  公开（公告）日：2006-01-26

  An 1-amido-3-(2-hydroxyphenoxy)-2-propanol derivative represented by the following formula (1), wherein cycle A may have further 1 to 4 substituents, and said substituent means a substituent selected from the group consisting of saturated or unsaturated C1-4 alkyl group, aralkyl group in which alkyl moiety has 1 to 4 carbon atoms, aryl group, halogen atom, halogenated C1-4 alkyl group, C2-5 alkanoyl group, mono or dialkylcarbamoyl group in which alkyl moiety has 1 to 4 carbon atoms, cyano group and nitro group, and the substituents at positions 3 and 6, or at positions 4 and 5 on the cycle A are different each other. Other ring may be fused at positions 3 and 4, or at positions 5 and 6 on the cycle A to form a condensed polycyclic hydrocarbon with the cycle A. R 1 is alkanoyl group or aroyl group, and R 2 is hydrogen atom, alkanoyl group or aroyl group, or R 1 and R 2 may be combined together with the N atom to form a cyclic imido group, which is useful as an intermediate of medicines, etc.

  由以下公式（1）表示的1-酰胺-3-(2-羟基苯氧基)-2-丙醇衍生物，其中环A可能有进一步的1到4个取代基，所述取代基是从饱和或不饱和的C1-4烷基，含有1到4个碳原子的芳基烷基，芳基，卤素原子，卤代C1-4烷基，C2-5烷酰基，单或二烷基氨基基，其中烷基部分含有1到4个碳原子，氰基和硝基中选择的取代基，并且在环A上的位置3和6，或在位置4和5上的取代基彼此不同。其他环可能在环A上的位置3和4，或在位置5和6上与环A融合，形成与环A的紧缩多环碳氢化合物。R1是烷酰基或芳酰基，R2是氢原子，烷酰基或芳酰基，或R1和R2可以与N原子结合在一起形成环亚胺基团，可用作药物等的中间体。
• Trifunctional olefinic-capped polymers and compositions that include such polymers
  申请人：——

  公开号：US20030032732A1

  公开（公告）日：2003-02-13

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应端或挂链官能团的聚合物，该聚合物已被三官能基烯烃化合物封顶。该聚合物可以通过将至少具有一个反应端或挂链官能团的基础聚合物与三官能基烯烃化合物接触，在有效反应条件下至少反应一个端或挂链官能团与三官能基烯烃化合物。封顶的聚合物在多组分组成物中特别适用于交联增韧剂，例如粘合剂、涂料和复合材料基体。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• TRIFUNCTIONAL OLEFINIC-CAPPED POLYMERS AND COMPOSITIONS THAT INCLUDE SUCH POLYMERS
  申请人：——

  公开号：US20020128418A1

  公开（公告）日：2002-09-12

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应末端或挂链官能团，并已用三官能双键化合物封顶的聚合物。该聚合物可以通过将至少具有一个反应末端或挂链官能团的基础聚合物与三官能双键化合物接触，在有效反应条件下使末端或挂链官能团中的至少一个与三官能双键化合物反应而制得。封顶聚合物特别适用于多组分组合物中的交联增韧剂，例如粘合剂、涂料和复合材料基体。
• 5,6,8,9-Tetrahydro-7H-dibenz(d,f)azonine derivatives, the production thereof and compositions containing them
  申请人：GÖDECKE AKTIENGESELLSCHAFT

  公开号：EP0035360A2

  公开（公告）日：1981-09-09

  The present invention provides 5.6;8,9-tetrahydro-7H-di- benz(d,f)azonine derivatives of the formula: wherein R1 and R2, which are the same or different, are hydrogen or halogen atoms or lower alkyl or lower alkoxy radicals, R3 is a hydrogen atom or a lower alkyl radical, R4 is a hydrogen atom or a lower alkyl or lower alkanoyl radical and n is 1 or 2; and the pharmaceutically acceptable salts thereof formed with inorganic and organic acids; but excluding 6-benzyl-2,12-dimethoxy-1-hydroxy-7-methyl-5,6;8,9-tetrahy- dro-7H-dibenz(d,f)azonine in which case R1, R2 and R4 are hydrogen, n is 1 and R3 is methyl. The lower alkyl, lower alkanoyl and lower alkoxy radicals are straight chain or branched radicals containing 1 to 5 carbon atoms. The present invention also provides a process for the production of these compounds, as well as pharmaceutical compositions containing them. The compounds are useful as antiarrhythmic agents and as local anaesthetics; they do not cause some of the unsatisfactory side effects associated with known agents.

  本发明提供式 5.6;8,9-四氢-7H-二苯并(d,f)唑嗪衍生物： 其中 R1 和 R2（相同或不同）为氢原子或卤素原子或低级烷基或低级烷氧基，R3 为氢原子或低级烷基，R4 为氢原子或低级烷基或低级烷酰基，n 为 1 或 2；及其与无机酸和有机酸形成的药学上可接受的盐；但不包括 6-苄基-2,12-二甲氧基-1-羟基-7-甲基-5,6;8,9-四氢-7H-二苯并(d,f)唑嗪，在这种情况下，R1、R2 和 R4 为氢原子，n 为 1，R3 为甲基。低级烷基、低级烷酰基和低级烷氧基是含有 1 至 5 个碳原子的直链或支链基。 本发明还提供了生产这些化合物的工艺以及含有这些化合物的药物组合物。 这些化合物可用作抗心律失常药剂和局部麻醉剂；它们不会引起与已知药剂相关的某些令人不满意的副作用。