1-Methylsulfanyl-2-(trichloromethyl)imidazolidine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 1-Methylsulfanyl-2-(trichloromethyl)imidazolidine
• 英文别名: 1-methylsulfanyl-2-(trichloromethyl)imidazolidine
• 化学式: C₅H₉Cl₃N₂S
• 分子量: 235.6
• InChiKey: SBIZFMISSJBVJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.6
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Ruthenium complex ligand, ruthenium complex and the use of the complex as a catalyst in olefin metathesis reactions
  申请人：Zannan Scitech Co., Ltd.

  公开号：EP2886549A1

  公开（公告）日：2015-06-24

  The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands and ruthenium complexes in metathesis reactions as catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures:

  本发明公开了一种钌络合物配体、钌络合物和固定化钌络合物催化剂。本发明还涉及新型钌络合物配体和钌络合物的制备和在偏析反应中的使用，作为催化剂，新型钌络合物和钌络合物具有催化活性高、稳定性强、易于回收和重复使用等显著优点。本发明中的钌络合物配体 I 和钌络合物 II 具有如下结构：
• RUTHENIUM COMPLEX LIGAND, RUTHENIUM COMPLEX, CARRIED RUTHENIUM COMPLEX CATALYST AND THE PREPARING METHODS AND THE USE THEREOF
  申请人：Zannan Scitech Co., Ltd.

  公开号：EP1905777B1

  公开（公告）日：2015-05-06
• HIGHLY ACTIVE METATHESIS CATALYSTS SELECTIVE FOR ROMP AND RCM REACTIONS
  申请人：ZHAN Zheng-Yun James

  公开号：US20140080984A1

  公开（公告）日：2014-03-20

  The present invention relates to a kind of novel carbene ligands and ruthenium catalysts, which is highly active and selective for ROMP and RCM reactions, respectively. It discloses the significant electronic and steric effect of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes; some of novel ruthenium complexes in the invention can be broadly used as catalysts highly effectively and selective for ROMP and RCM reactions. The invention also relates to preparation of new ruthenium catalysts and the uses in metathesis. Moreover, the invention also provides effective methods of making various functional polymers by ROMP reaction in the presence of new ruthenium catalysts.