2,5-Bis(2-hexyldecyl)-6-[5-(4-methyl-9,10-diphenyl-8-oxa-3,15-dithiatetracyclo[10.3.0.02,6.07,11]pentadeca-1,4,6,9,11,13-hexaen-14-yl)thiophen-2-yl]-1-methylidene-3-(5-methylthiophen-2-yl)pyrrolo[3,4-c]pyrrol-4-one

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 2-芳基苯并呋喃类黄酮
• 英文名称: 2,5-Bis(2-hexyldecyl)-6-[5-(4-methyl-9,10-diphenyl-8-oxa-3,15-dithiatetracyclo[10.3.0.02,6.07,11]pentadeca-1,4,6,9,11,13-hexaen-14-yl)thiophen-2-yl]-1-methylidene-3-(5-methylthiophen-2-yl)pyrrolo[3,4-c]pyrrol-4-one
• 英文别名: 2,5-bis(2-hexyldecyl)-6-[5-(4-methyl-9,10-diphenyl-8-oxa-3,15-dithiatetracyclo[10.3.0.02,6.07,11]pentadeca-1,4,6,9,11,13-hexaen-14-yl)thiophen-2-yl]-1-methylidene-3-(5-methylthiophen-2-yl)pyrrolo[3,4-c]pyrrol-4-one
• 化学式: C₇₃H₉₀N₂O₂S₄
• 分子量: 1155.8
• InChiKey: GCKFPBRQJHHSEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.8
• 重原子数：
  81
• 可旋转键数：
  33
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  150
• 氢给体数：
  0
• 氢受体数：
  7

文献信息

• [EN] DITHIENOBENZOFURAN POLYMERS AND SMALL MOLECULES FOR ELECTRONIC APPLICATION<br/>[FR] POLYMÈRES DE DITHIÉNOBENZOFURANE ET PETITES MOLÉCULES POUR APPLICATION ÉLECTRONIQUE
  申请人：BASF SE

  公开号：WO2014016219A1

  公开（公告）日：2014-01-30

  The present invention relates to polymers comprising a repeating unit of the formula (I), and compounds of formula (VIII), or (IX), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (I), and their use as organic semiconductor in organic electronic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics (solar ells) and photodiodes.

  本发明涉及具有重复单元式(I)的聚合物以及式(VIII)或(IX)的化合物，其中Y、Y15、Y16和Y17各自独立地是式(I)的基团，并且它们在有机电子器件中的用途，特别是在有机光伏和光电二极管中作为有机半导体，或在包含二极管和/或有机场效应晶体管的器件中。本发明中的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。此外，当本发明中的聚合物和化合物用于有机场效应晶体管、有机光伏（太阳电池）和光电二极管时，可以观察到高效率的能量转换、优异的场效应迁移率、良好的开/关电流比和/或优异的稳定性。