The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.
本公开提供了一种用于醇解含有聚
碳酸酯和含有
磷系阻燃剂、
丙烯腈-
丁二烯-
苯乙烯或
磷系阻燃剂和
丙烯腈-
丁二烯-
苯乙烯组合物的组合物的方法。该方法包括将该组合物与形成该组分的溶剂接触,该溶剂形成该组分的溶液或可过滤悬浮液但不形成聚
碳酸酯的溶液或可过滤悬浮液;将溶液或可过滤悬浮液与聚
碳酸酯分离;在醇和催化剂的存在下,在70℃至200℃的温度和5毫巴至40巴的压力下加热聚
碳酸酯,足以使聚
碳酸酯去聚合并产生二羟基芳香化合物和二烷基
碳酸酯。