申请人:Tashino Kunihiko
公开号:US20140135205A1
公开(公告)日:2014-05-15
A solid catalyst component for olefin polymerization and a catalyst are disclosed that exhibit high catalytic activity when used for gas-phase polymerization, suppress rapid reactions in the initial stage of polymerization relative to the polymerization activity, and can produce a propylene polymer in high yield while maintaining high stereoregularity. The solid catalyst component for olefin polymerization includes magnesium, titanium, a halogen, and an internal electron donor, the solid catalyst component including an asymmetrical phthalic diester represented by the following general formula (1) in a molar ratio of 0.2 to 0.8 relative to the total content of the internal electron donor.
R
1
k
(C
6
H
4-k
)(COOR
2
)(COOR
3
) (1)
wherein R
1
is an alkyl group or the like, R
2
is a linear or branched alkyl group having 2 to 6 carbon atoms or an alkenyl group, R
3
is a linear or branched alkyl group having 1 to 5 carbon atoms, the number of carbon atoms included in R
3
being smaller than the number of carbon atoms included in R
2
, and k is an integer from 0 to 4 that indicates the number of substituents R
1
.