{6-[(E)-2-(benzothiazol-2-yl)vinyl]}-N,N-bis-{6-[(E)-2-(benzothiazol-2-yl)vinyl]naphth-2-yl}-2-naphthylamine | 1092716-61-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: {6-[(E)-2-(benzothiazol-2-yl)vinyl]}-N,N-bis-{6-[(E)-2-(benzothiazol-2-yl)vinyl]naphth-2-yl}-2-naphthylamine
• 英文别名: 6-[(E)-2-(1,3-benzothiazol-2-yl)ethenyl]-N,N-bis[6-[(E)-2-(1,3-benzothiazol-2-yl)ethenyl]naphthalen-2-yl]naphthalen-2-amine
• CAS: 1092716-61-4
• 化学式: C₅₇H₃₆N₄S₃
• 分子量: 873.138
• InChiKey: SENUFGCRRSWECX-NTFFSUIMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.2
• 重原子数：
  64
• 可旋转键数：
  9
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  diethyl (1,3-benzothiazol-2-ylmethyl)phosphonate 、 6-[N,N-bis(6-formyl-2-naphthyl)amino]-2-naphthaldehyde 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 0.17h， 以73%的产率得到{6-[(E)-2-(benzothiazol-2-yl)vinyl]}-N,N-bis-{6-[(E)-2-(benzothiazol-2-yl)vinyl]naphth-2-yl}-2-naphthylamine
  参考文献：
  名称：

  Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence

  摘要：

  The synthesis of a novel pi-conjugated trinaphthylamines series is described. These original push-pull octupolar systems exhibit large two-photon action cross section (sigma(phi) up to 510 GM) increased by a factor of 2-3 as compared to their triphenylamines analogues. This substantial improvement of the two-photon absorption properties is attributed to the stronger donor character of the trinaphthyl core.

  DOI：

  10.1021/ja8055112

文献信息

• Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence
  作者：Guillaume Bordeau、Rémy Lartia、Germain Metge、Céline Fiorini-Debuisschert、Fabrice Charra、Marie-Paule Teulade-Fichou

  DOI：10.1021/ja8055112

  日期：2008.12.17

  The synthesis of a novel pi-conjugated trinaphthylamines series is described. These original push-pull octupolar systems exhibit large two-photon action cross section (sigma(phi) up to 510 GM) increased by a factor of 2-3 as compared to their triphenylamines analogues. This substantial improvement of the two-photon absorption properties is attributed to the stronger donor character of the trinaphthyl core.