2,3-Dibutylnaphthalene-1-sulfonate;triphenylphosphanium

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-Dibutylnaphthalene-1-sulfonate;triphenylphosphanium
• 英文别名: 2,3-dibutylnaphthalene-1-sulfonate;triphenylphosphanium
• 化学式: C36H39O3PS
• 分子量: 582.7
• InChiKey: ZHUPNBNJBPQIGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.61
• 重原子数：
  41
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  65.6
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• AROMATIC POLYCARBONATE RESIN COMPOSITION AND ARTICLES MOLDED THEREFROM
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP2735589A1

  公开（公告）日：2014-05-28

  To provide an aromatic polycarbonate resin composition which has an impact resistance improved by blending of an impact strength improver and which also has an excellent transparency and a good surface hardness. The aromatic polycarbonate resin composition includes, with respect to 100 parts by mass of a resin component containing 55 to 85 percent by mass of an aromatic polycarbonate resin (A) having a mass average molecular weight of 15,000 to 40,000 and 15 to 45 percent by mass of a (meth)acrylate copolymer (B) which has a mass average molecular weight of 5,000 to 30,000 and which is composed of an aromatic (meth)acrylate unit (b1) and a methyl (meth)acrylate unit (b2) at a mass ratio (b1/b2) of 5 to 50/50 to 95, 1 to 20 parts by mass of an impact strength improver (C). A refractive index nab of the resin component at a wavelength of 589 nm and a refractive index nc of the impact strength improver (C) at a wavelength of 589 nm satisfy the following formula i). Formula i) -0.01 ≤ nab - nc ≤ +0.01

  提供一种芳香族聚碳酸酯树脂组合物，该组合物通过掺入抗冲击强度改进剂提高了抗冲击性，同时还具有极佳的透明度和良好的表面硬度。芳香族聚碳酸酯树脂组合物包括：相对于 100 质量份的树脂组分，含有 55-85%质量份的芳香族聚碳酸酯树脂 (A)，其质量平均分子量为 15,000-40、(甲基)丙烯酸酯共聚物 (B)，其平均分子量为 5,000 至 30,000，由芳香族 (甲基)丙烯酸酯单元 (b1) 和甲基 (甲基)丙烯酸酯单元 (b2) 以 5 至 50/50 的质量比 (b1/b2) 组成。树脂组分在 589 纳米波长处的折射率 nab 和抗冲击强度改进剂 (C) 在 589 纳米波长处的折射率 nc 符合下式 i)。公式 i) -0.01 ≤ nab - nc ≤ +0.01
• AROMATIC POLYCARBONATE RESIN COMPOSITION, AND MOLDED ARTICLE COMPRISING SAME
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2752458A1

  公开（公告）日：2014-07-09

  An aspect of the present invention relates to an aromatic polycarbonate resin composition, which comprises per 100 mass parts of an aromatic polycarbonate resin (A) comprising an aromatic polycarbonate resin (a1) with a viscosity average molecular weight of 3 x 103 to 2.5 x 104 and an aromatic polycarbonate resin (a2) with a viscosity average molecular weight of 5 x 104 to 9 x 104 in a ratio such that, when a total quantity of aromatic polycarbonate resins (a1) and (a2) is denoted as 100 mass percent, (a1):(a2) = 99 mass percent to 50 mass percent: 1 mass percent to 50 mass percent; 0.01 to 10 mass parts of microparticles (B) selected from the group consisting of polyorganosilsesquioxane microparticles and (meth)acrylic resin microparticles; and 0.005 mass part to 0.1 mass part of a flame retardant (C) in the form of organic sulfonic acid metal salt; wherein a molten resin quantity Q value flowing out of an orifice 1mm in diameter x 10 mm in length at a temperature of 280°C at a load of 1.57 x 107 Pa using a constant-load orifice-type flow tester is equal to or greater than 0.01 cm3/second and equal to or lower than 0.1 cm3/second.

  本发明的一个方面涉及一种芳香族聚碳酸酯树脂组合物，该组合物包括每 100 质量份的芳香族聚碳酸酯树脂（A），其中芳香族聚碳酸酯树脂（a1）的平均粘度分子量为 3 x 103 至 2.5 x 104 的芳香族聚碳酸酯树脂 (a2) 和粘度平均分子量为 5 x 104 至 9 x 104 的芳香族聚碳酸酯树脂 (a1)，其比例为：当芳香族聚碳酸酯树脂 (a1) 和 (a2) 的总量表示为 100 质量份时，(a1):(a2) = 99 质量份至 50 质量份：1 质量份至 50 质量份；0.01 至 10 质量份的微粒子 (B)，选自聚有机硅倍半氧烷微粒子和（甲基）丙烯酸树脂微粒子组成的组；以及 0.005 质量份至 0.1质量份的有机磺酸金属盐形式的阻燃剂(C)；其中，在温度为280℃、负载为1.57×107帕的条件下，使用恒定负载孔口型流量测试仪，从直径为1毫米×长度为10毫米的孔口流出的熔融树脂量Q值等于或大于0.01立方厘米/秒，等于或小于0.1立方厘米/秒。
• REINFORCED AROMATIC POLYCARBONATE RESIN SHEET OR FILM
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3133109A1

  公开（公告）日：2017-02-22

  Provided is an aromatic polycarbonate resin sheet/film which has excellent bending characteristics and surface smoothness. It is found that a sheet having excellent surface smoothness, which cannot be achieved by conventional sheets, can be obtained by adjusting sheet extrusion conditions for a polycarbonate resin sheet/film into which a reinforcing filler is blended. It is also found that a thermally shaped article having excellent appearance can be obtained by using this sheet in pressure molding or in thermal press molding.

  本文提供了一种芳香族聚碳酸酯树脂片材/薄膜，它具有优异的弯曲特性和表面平滑度。研究发现，通过调整掺入了增强填料的聚碳酸酯树脂片材/薄膜的片材挤压条件，可以获得具有传统片材无法达到的优异表面平滑度的片材。此外，还发现通过在压力成型或热压成型中使用这种片材，可以获得具有出色外观的热成型制品。
• POLYCARBONATE RESIN HAVING AMINE RESISTANCE
  申请人：Teijin Limited

  公开号：EP3369759A1

  公开（公告）日：2018-09-05

  A polycarbonate copolymer or copolymerized polycarbonate blend having excellent amine resistance, which has, as main constituent units, (A) constituent units each represented by the following formula (1): wherein, in the formula (1), each of R1 and R2 is independently a hydrogen atom, a hydrocarbon group having 1 to 9 carbon atoms and optionally containing an aromatic group, or a halogen atom, (B) constituent units each represented by the following formula (2): wherein, in the formula (2), each of R3 and R4 is independently an alkyl group having 1 to 6 carbon atoms or a halogen atom, and X is a single bond, a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkylidene group, a sulfur atom, or an oxygen atom, and (C) constituent units each represented by the following formula (3): wherein, in the formula (3), W represents a single bond, a substituted or unsubstituted alkylene group, a substituted or unsubstituted alkylidene group, a sulfur atom, or an oxygen atom, wherein the amount of the constituent units (A) is 5 to 15 mol%, the amount of the constituent units (B) is 20 to 60 mol%, and the amount of the constituent units (C) is 25 to 75 mol%, based on the mole of the all constituent units, and the polycarbonate copolymer or copolymerized polycarbonate blend is excellent in scratch resistance, impact resistance, heat resistance, and amine resistance.

  一种具有优异耐胺性的聚碳酸酯共聚物或共聚聚碳酸酯混合物，其主要组成单元为 (A) 下式 (1) 所示的各组成单元： 其中，在式 (1) 中，R1 和 R2 各自独立地为氢原子、具有 1 至 9 个碳原子且可选含有芳香族基团的烃基或卤素原子、 (B) 各由下式（2）表示的组成单元： 其中，在式 (2) 中，R3 和 R4 各自独立地为具有 1 至 6 个碳原子的烷基或卤素原子，X 为单键、取代或未取代的亚烷基、取代或未取代的亚烷基、硫原子或氧原子，以及 (C) 各由下式（3）表示的组成单元： 其中，在式 (3) 中，W 代表单键、取代或未取代亚烷基、取代或未取代亚烷基、硫原子或氧原子、 其中，基于所有组成单元的摩尔数，组成单元（A）的量为 5 至 15 摩尔%，组成单元（B）的量为 20 至 60 摩尔%，组成单元（C）的量为 25 至 75 摩尔%，聚碳酸酯共聚物或共聚聚碳酸酯混合物具有优异的抗划伤性、抗冲击性、耐热性和耐胺性。
• THERMOPLASTIC RESIN COMPOSITION, AND METHOD FOR MANUFACTURING MOLDED ARTICLE
  申请人：Mitsubishi Engineering-Plastics Corporation

  公开号：EP3822319A2

  公开（公告）日：2021-05-19

  A thermoplastic resin composition including a thermoplastic resin component and a glass filler (C), the thermoplastic resin component including a polycarbonate resin (A) having a viscosity-average molecular weight of 13,000 to 22,000 and a polyester resin (B) including a terephthalic acid residue, a 1,4-cyclohexanedimethanol residue, and a 2,2,4,4-tetramethyl-1,3-cyclobutanediol residue. The amounts of the polycarbonate resin (A) and the polyester resin (B) are 25 to 65 parts by mass and 75 to 35 parts by mass, respectively, relative to 100 parts by mass of the total amount of the polycarbonate resin (A) and the polyester resin (B). The amount of the glass filler (C) is 10 to 45 parts by mass relative to 100 parts by mass of the thermoplastic resin component. A molded article is produced by performing injection molding of the thermoplastic resin composition with a heat-insulation mold or heat-and-cool molding of the thermoplastic resin composition.

  一种热塑性树脂组合物，包括热塑性树脂组分和玻璃填料 (C)，热塑性树脂组分包括粘均分子量为 13,000 至 22,000 的聚碳酸酯树脂 (A) 和聚酯树脂 (B)，聚酯树脂 (B) 包括对苯二甲酸残留物、1,4-环己烷二甲醇残留物和 2,2,4,4-四甲基-1,3-环丁二醇残留物。相对于 100 份聚碳酸酯树脂（A）和聚酯树脂（B）的总量，聚碳酸酯树脂（A）和聚酯树脂（B）的用量分别为 25 至 65 份（质量分数）和 75 至 35 份（质量分数）。玻璃填料（C）的用量相对于 100 份热塑性树脂组分的质量为 10 至 45 份。使用隔热模具对热塑性树脂组合物进行注塑成型，或对热塑性树脂组合物进行热冷成型，从而生产出模塑制品。