A process for forming a thermosetting resin in a nitrogen atmosphere is provided. The process includes the steps of a) reacting a polycarboxylic acid and/or anhydride and a polyhydric alcohol to provide a hydroxyl-containing intermediate; b) reacting the hydroxyl-containing intermediate with a vinyl-containing organic acid or vinyl containing alkyl ester in the presence of an esterification catalyst, a polymerization inhibitor and an azeotropic agent; and c) reacting any residual vinyl-containing organic acid and residual esterification catalyst with an epoxide.
本发明提供了一种在氮气环境中形成热固性
树脂的工艺。该工艺包括以下步骤:a) 使聚
羧酸和/或酸酐与多元醇反应,生成含羟基的中间体;b) 在酯化催化剂、聚合
抑制剂和共沸剂存在下,使含羟基的中间体与含
乙烯基的有机酸或含
乙烯基的烷基酯反应;以及 c) 使任何残留的含
乙烯基的有机酸和残留的酯化催化剂与
环氧化物反应。