1,1'-[Sulfonylbis(4,1-phenylenesulfonyl)]bis(4-chlorobenzene)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1'-[Sulfonylbis(4,1-phenylenesulfonyl)]bis(4-chlorobenzene)
• 英文别名: 1-(4-chlorophenyl)sulfonyl-4-[4-(4-chlorophenyl)sulfonylphenyl]sulfonylbenzene
• 化学式: C₂₄H₁₆Cl₂O₆S₃
• 分子量: 567.5
• InChiKey: IGDYFOQZXDPWGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  128
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• Process for the production of aromatic sulfide/sulfone polymers
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0033906A1

  公开（公告）日：1981-08-19

  Aromatic sulfide/sulfone polymers are prepared by initially contacting a dihaloaromatic sulfone, an alkali metal sulfide, an organic amide, and, optionally, an alkali metal carboxylate under polymerization conditions and subsequently at or near completion of the polymerization reaction, adding an end-capping agent comprising additional dihaloaromatic sulfone to the reaction mixture producing a polymer exhibiting improved physical properties including melt flow stability. The resulting polymers have utility as coatings, films, molded objects, filaments, fibers, and the like.

  芳香族硫化物/砜聚合物的制备方法是：在聚合条件下，先将二卤代芳香族砜、碱金属硫化物、有机酰胺和（可选）碱金属羧酸盐接触，然后在聚合反应完成或接近完成时，向反应混合物中加入由额外的二卤代芳香族砜组成的末端封端剂，从而产生一种具有更佳物理性能（包括熔体流动稳定性）的聚合物。这种聚合物可用作涂层、薄膜、模制件、长丝、纤维等。
• Aromatic sulfide/sulfone polymer production
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0301566A2

  公开（公告）日：1989-02-01

  A process is provided for the production of aromatic sulfide/sulfone polymers which involves contacting under suitable polymerization reaction conditions: (1) at least one dihaloaromatic sulfone, (2) at least one organic amide, (3) at least one alkali metal hydrosulfide, (4) water, and (5) at least one member selected from the group consisting of (a) alkali metal carbonates and (b) mixtures of alkali metal carbonates with alkali metal hydroxides wherein said mixtures have at least about 0.5 mole percent alkali metal carbonate.

  本发明提供了一种生产芳香族硫化物/砜聚合物的工艺，该工艺涉及在合适的聚合反 应条件下接触：(1) 至少一种二卤代芳香族砜，(2) 至少一种有机酰胺，(3) 至少一种碱金属硫 化氢，(4) 水，和 (5) 至少一种选自以下组别的成员：(a) 碱金属碳酸盐和 (b) 碱金属碳酸盐与碱金属氢氧化物的混合物，其中所述混合物具有至少约 0.5 摩尔%的碱金属碳酸盐。
• Production of aromatic sulfide/sulfone polymers
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0309954A1

  公开（公告）日：1989-04-05

  Process for the production of high molecular weight aromatic sulfide/sulfone polymer comprising contacting under suitable polymerization conditions: (a) an organic amide, (b) an alkali metal sulfide or hydrosulfide, (c) water, and (d) a dihaloaromatic sulfone wherein the molar ratio of (a) to (b) is about 2:1 to about 24:1, the improvement comprising employing a molar ratio of (a) to (c) of about 0.4:1 to about 1.3:1.

  生产高分子量芳香族硫化物/砜聚合物的工艺，包括在合适的聚合条件下接触：(a)有机酰胺，(b)碱金属硫化物或硫氢化物，(c)水和(d)二卤代芳香族砜，其中(a)与(b)的摩尔比约为 2:1 至约 24:1，改进包括采用(a)与(c)的摩尔比约为 0.4:1 至约 1.3:1。
• Production of poly (arylene sulfide sulfone)
  申请人：Tosoh Corporation

  公开号：EP0348189A2

  公开（公告）日：1989-12-27

  An improved process for producing poly(arylene sulfide sulfone) of increased molecular weight is provided. The process employs an Li salt of C₁ - C₂₀ carboxylic acid as a polymerization auxiliary and is carried out in an organic amide solvent by reacting a dihalogenated aromatic sulfone with an alkali metal sulfide in the presence of 10 - 15 moles of water per mole of the alkali metal sulfide at temperatures within the range of from 160°C to 230°C.

  本发明提供了一种生产分子量增大的聚芳基砜的改进工艺。该工艺采用 C₁ - C₂₀ 羧酸的锂盐作为聚合助剂，在有机酰胺溶剂中进行，方法是在每摩尔碱金属硫化物含有 10-15 摩尔水的情况下，在 160°C 至 230°C 的温度范围内，使二卤化芳砜与碱金属硫化物反应。
• Treatment of polyarylene sulfide/sulfone polymers
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0427134A1

  公开（公告）日：1991-05-15

  Poly(arylene sulfide/sulfone) polymers are treated in order to increase melt stability and decrease impurities by contacting the poly(arylene sulfide/sulfone) polymer with a soluble zinc compound, followed by contacting the polymer with an acidic solution.

  聚(芳基砜/砜)聚合物的处理方法是将聚(芳基砜/砜)聚合物与可溶性锌化合物接触，然后再将聚合物与酸性溶液接触，以提高熔体稳定性并减少杂质。