4-Phenyl-4-penten-2-on | 827-68-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Phenyl-4-penten-2-on
• 英文别名: 4-Phenylpent-4-en-2-one
• CAS: 827-68-9
• 化学式: C₁₁H₁₂O
• 分子量: 160.216
• InChiKey: DFKKDUXNFSECIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-Methyl-3-phnenylperlaevulincarbonsaeure-tert.-butylester 以 二苯醚 为溶剂， 生成 4-Phenyl-4-penten-2-on
  参考文献：
  名称：

  Acyl rearrangements in radical reactions

  摘要：

  DOI：

  10.1021/jo00983a009

文献信息

• Oligomers and homopolymers of meta- or para-isopropenyl-alpha,alpha-dimethylbenzylisocyanate
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0130313A2

  公开（公告）日：1985-01-09

  Aromatic solvent-soluble linear oligomers or homopolymers of meta- or para-isopropenyl-a,a-dimethylbenzyl- isocyanate characterized by high isocyanate content are disclosed. Such oligomers or homopolymers are made by catalytic solution polymerization of the monomer in methylene chloride and/or toluene solution at a temperature of from about -80°C to about -25°C, followed by low- temperature neutralization of the polymerization catalyst.

  本发明公开了以高异氰酸酯含量为特征的偏异丙烯基或对位异丙烯基-a,a-二甲基苄基异氰酸酯的芳香族溶剂可溶线性低聚物或均聚物。这种低聚物或均聚物是通过单体在二氯甲烷和/或甲苯溶液中在约-80℃至约-25℃的温度下进行催化溶液聚合，然后对聚合催化剂进行低温中和而制成的。
• Preparation and decarboxylative rearrangement of (Z)-enyne esters
  作者：Jacqueline C.S. Woo、Shawn D. Walker、Margaret M. Faul

  DOI：10.1016/j.tetlet.2007.06.012

  日期：2007.8

  A method to assemble (Z)-enyne esters via palladium-catalyzed cross coupling reactions of enol tosylates is reported. A base-mediated one-pot decarboxylative rearrangement of the enynes to enones is described. The scope of this process is examined. (c) 2007 Elsevier Ltd. All rights reserved.
• Synthesis of β,γ-Unsaturated Ketones via Cerium-Mediated Addition of Organolithiums to Silylated Enaminones
  作者：Renato Dalpozzo、Antonio De Nino、Giuseppe Bartoli、Marcella Bosco、Letizia Sambri、Enrico Marcantoni

  DOI：10.1021/jo971520o

  日期：1998.5.1
• [EN] REMOVAL OF METAL CONTAMINANTS FROM POLYETHYLENE<br/>[FR] ÉLIMINATION DE CONTAMINANTS MÉTALLIQUES DU POLYÉTHYLÈNE
  申请人：EQUISTAR CHEM LP

  公开号：WO2009078902A1

  公开（公告）日：2009-06-25

  A process to remove metal contaminants from a hydrocarbon solution of polyethylene is disclosed. The process comprises adding a primary alcohol and a ß-diketone to a solution of polyethylene at a temperature within the range of 120°C to 300°C and contacting the solution with basic alumina. The process removes metal contaminants and minimizes degradation and condensation products, which can have a detrimental effect on polyethylene properties. The process provides polyethylene with low metal residues and good properties.
• Acyl rearrangements in radical reactions
  作者：Curtis L. Karl、E. Jerome Maas、William Reusch

  DOI：10.1021/jo00983a009

  日期：1972.9