[4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl] 2-methylprop-2-enoate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: [4-(1,1,1,3,3,3-Hexafluoro-2-hydroxypropan-2-yl)phenyl] 2-methylprop-2-enoate
• 英文别名: [4-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenyl] 2-methylprop-2-enoate
• 化学式: C₁₃H₁₀F₆O₃
• 分子量: 328.21
• InChiKey: SAVABULJQOEHJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  9

文献信息

• POLYMERIZABLE MONOMER, POLYMER COMPOUND FOR CONDUCTIVE POLYMER, AND METHOD FOR PRODUCING THE POLYMER COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20200247926A1

  公开（公告）日：2020-08-06

  Polymerization reaction is performed using a polymerizable monomer shown by the following general formula (1) and at least one monomer selected from monomers each having a structure of a salt among a lithium salt, a sodium salt, a potassium salt, and a nitrogen compound salt of a fluorosulfonic acid or the like; then, the structure of the salt of the repeating unit of a polymer obtained by the polymerization reaction is changed to the fluorosulfonic acid or the like by ion exchange. Thus, the present invention provides a polymer compound for a conductive polymer and a method for producing the polymer compound which is suitably used as a dopant for a fuel cell and a conductive material, and which is a copolymer containing a repeating unit of styrene having a 3,3,3-trifluoro-2-hydroxy-2-trifluoromethylisobutyl ether group, and a repeating unit having any of a fluorosulfonic acid, a fluorosulfonimide group, and a n-carbonyl-fluoro-sulfonamide group.

  聚合反应使用以下一般式（1）所示的可聚合单体和至少一种选择自锂盐、钠盐、钾盐和氟磺酸盐等盐结构的单体中的单体进行；然后，通过离子交换将聚合反应得到的聚合物的重复单元的盐结构改变为氟磺酸盐或类似物。因此，本发明提供了一种用作导电聚合物的聚合物化合物以及用作燃料电池和导电材料的掺杂剂的聚合物化合物的生产方法，该聚合物是含有3,3,3-三氟-2-羟基-2-三氟甲基异丁基醚基的苯乙烯重复单元和具有氟磺酸、氟磺酰亚胺基团和n-羰基-氟磺酰胺基团中的任何一种的重复单元的共聚物。
• Polymerizable monomer, polymer compound, biological electrode composition, biological electrode, and method for producing biological electrode
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10726967B2

  公开（公告）日：2020-07-28

  The present invention provides: a biological electrode composition formable a living body contact layer for a biological electrode which is excellent in conductivity and biocompatibility, as well as light in the weight thereof and producible at a low cost, and in addition, which does not cause a significant decrease in the conductivity thereof regardless of under a water-wet condition and a dry condition; a polymer compound which can be suitably used for the biological electrode composition; a polymerizable monomer suitable as a raw material of the polymer compound; a biological electrode having a living body contact layer formed of the biological electrode composition; and a method for producing the same; and wherein, the polymerizable monomer is represented by the following general formula (1).

  本发明提供了一种可形成生物电极活体接触层的生物电极组合物，该组合物具有优异的导电性和生物相容性，且重量轻、生产成本低廉，此外，无论在水湿条件下还是在干燥条件下，其导电性都不会显著降低；可适当用于生物电极组合物的高分子化合物；适于作为该高分子化合物原料的可聚合单体；具有由该生物电极组合物形成的活体接触层的生物电极；以及生产该生物电极的方法；其中，可聚合单体由以下通式（1）表示。
• Bio-electrode composition, bio-electrode, and method for manufacturing bio-electrode
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US11071485B2

  公开（公告）日：2021-07-27

  The present invention provides a bio-electrode composition including a polymer compound having both an ionic repeating unit A and a (meth)acrylate repeating unit B, wherein the ionic repeating unit A is a repeating unit selected from the group consisting of sodium salt, potassium salt, and ammonium salt having either or both partial structures shown by the following general formulae (1-1) and (1-2), and the (meth)acrylate repeating unit B is a repeating unit shown by the following general formula (2). This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility, and light weight, which can be manufactured at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried.

  本发明提供了一种生物电极组合物，该组合物包括同时具有离子型重复单元 A 和（甲基）丙烯酸酯重复单元 B 的聚合物化合物，其中离子型重复单元 A 是选自由钠盐、钾盐和铵盐组成的组中的重复单元，具有以下通式（1-1）和（1-2）所示的部分结构中的一种或两种，而（甲基）丙烯酸酯重复单元 B 是以下通式（2）所示的重复单元。 这样就可以形成生物电极的活体接触层，该层具有优异的导电性、生物相容性和轻质，可以低成本制造，即使被水浸湿或干燥也不会导致导电性大幅降低。
• Biomedical electrode composition, biomedical electrode and method for manufacturing the biomedical electrode
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US11357970B2

  公开（公告）日：2022-06-14

  The present invention provides a biomedical electrode composition capable of forming a living body contact layer for a biomedical electrode that is excellent in conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in conductivity even though the biomedical electrode is soaked in water or dried. The present invention was accomplished by a biomedical electrode composition including a polymer compound having both the ionic repeating unit “a” and the repeating unit “b” of (meth)acrylate, in which the ionic repeating unit “a” is a repeating unit of sodium salt, potassium salt, or ammonium salt including a partial structure represented by the following general formula (1), and the repeating unit “b” of (meth)acrylate is a repeating unit represented by the following general formula (2).

  本发明提供了一种能够为生物医学电极形成活体接触层的生物医学电极组合物，该组合物具有优异的导电性和生物相容性，重量轻，可低成本制造，即使生物医学电极浸泡在水中或干燥，也能控制导电性的显著降低。本发明是通过一种生物医学电极组合物实现的，该组合物包括同时具有离子型重复单元 "a "和（甲基）丙烯酸酯的重复单元 "b "的聚合物化合物，其中离子型重复单元 "a "是钠盐、钾盐或铵盐的重复单元，包括由以下通式（1）表示的部分结构，而（甲基）丙烯酸酯的重复单元 "b "是由以下通式（2）表示的重复单元。
• COPOLYMER AND ASSOCIATED LAYERED ARTICLE, AND DEVICE-FORMING METHOD
  申请人：The University of Queensland

  公开号：US20170037171A1

  公开（公告）日：2017-02-09

  A copolymer is prepared by the polymerization of monomers that include an ultraviolet absorbing monomer, and a base-solubility-enhancing monomer. The copolymer is useful for forming a topcoat layer for electron beam and extreme ultraviolet lithographies. Also described are a layered article including the topcoat layer, and an associated method of forming an electronic device.