3,5,11,13,19,30,32,38,40,42-Decamethyl-22,45-dioxa-19-aza-42-azonia-8,35-diphosphadodecacyclo[33.10.1.02,7.08,26.09,14.015,24.018,23.025,44.028,43.029,34.036,41.042,46]hexatetraconta-2,4,6,9,11,13,15(24),16,18(23),25,27,29,31,33,36,38,40,43-octadecaene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5,11,13,19,30,32,38,40,42-Decamethyl-22,45-dioxa-19-aza-42-azonia-8,35-diphosphadodecacyclo[33.10.1.02,7.08,26.09,14.015,24.018,23.025,44.028,43.029,34.036,41.042,46]hexatetraconta-2,4,6,9,11,13,15(24),16,18(23),25,27,29,31,33,36,38,40,43-octadecaene
• 英文别名: 3,5,11,13,19,30,32,38,40,42-decamethyl-22,45-dioxa-19-aza-42-azonia-8,35-diphosphadodecacyclo[33.10.1.02,7.08,26.09,14.015,24.018,23.025,44.028,43.029,34.036,41.042,46]hexatetraconta-2,4,6,9,11,13,15(24),16,18(23),25,27,29,31,33,36,38,40,43-octadecaene
• 化学式: C50H47N2O2P2+
• 分子量: 769.9
• InChiKey: RIIBFWYBYKVMSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  56
• 可旋转键数：
  0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• NOVEL RUTHENIUM COMPLEX AND PROCESS FOR PRODUCING OPTICALLY ACTIVE ALCOHOL COMPOUND USING SAME AS CATALYST
  申请人：Hori Kiyoto

  公开号：US20140187809A1

  公开（公告）日：2014-07-03

  The present invention provides a novel ruthenium complex which has an excellent catalytic activity in terms of reactivity for an asymmetric reduction of a carbonyl compound and enantioselectivity, a catalyst using the ruthenium complex, and a method for preparing optically active alcohol compounds using the ruthenium complex. The present invention relates to a ruthenium complex having a ruthenacycle structure, a catalyst for an asymmetric reduction consisting of the ruthenium complex, and a method for preparing optically active alcohol compounds using the ruthenium complex.

  本发明提供了一种新型的钌配合物，其在对羰基化合物的不对称还原反应中具有优异的催化活性和对映选择性，还提供了使用该钌配合物制备光学活性醇化合物的催化剂和方法。本发明涉及一种具有钌环结构的钌配合物、用于不对称还原反应的催化剂，以及使用该钌配合物制备光学活性醇化合物的方法。
• US9255049B2
  申请人：——

  公开号：US9255049B2

  公开（公告）日：2016-02-09