N-(trifluoromethylsulfonyl)phenylsulfonimidoyl fluoride | 156427-83-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(trifluoromethylsulfonyl)phenylsulfonimidoyl fluoride
• 英文别名: N-(Trifluoromethylsulfonyl)benzenesulfonimidic acid fluoride；1,1,1-trifluoro-N-(fluoro-oxo-phenyl-λ6-sulfanylidene)methanesulfonamide
• CAS: 156427-83-7
• 化学式: C₇H₅F₄NO₃S₂
• 分子量: 291.247
• InChiKey: OAXQPHZGSIIMRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N-(trifluoromethylsulfonyl)phenylsulfonimidoyl fluoride 在 硫酸 、 氨 作用下， 生成 N-(amino-oxo-phenyl-lambda6-sulfanylidene)-1,1,1-trifluoromethanesulfonamide
  参考文献：
  名称：

  The unusual reactivity of the mono- and bis- N-(trifluoromethylsulfonyl)-substituted azaanalogs of arenesulfonochlorides

  摘要：

  The reactions of N-(trifluoromethylsulfonyl)arenesulfonimidoyl- and N, N'- bis(trifluoromethylsulfonyl)arenesulfonodiimidoyl chlorides of general formulas Ar-S(0)(=NSO2CF3)Cl (1) and Ar-S(=NSO2CF3)(2)Cl (2) with ammonia have been investigated and found to yield the ammonium salts of [N-(trifluoromethylsulfonyl)arenesulfinylimino]-N' (trifluoromethylsulfonyl)amides. The high oxidative ability of the chlorides (1,2) have been shown. Thus, chlorides (2) react with benzene or trifluoromethylbenzene, to form the chlorobenzene or 3-chloro- trifluoromethylbenzene. The fluorides of the general formulas Ar-S(0)(=NSO2CF3)F and Ar-S(=NSO2CF3)(2)F have been prepared. Their interaction with ammonia leads to the usual formation of corresponding amides. The electron nature of new electron withdrawing substituents have been investigated.

  DOI：

  10.1016/s0040-4020(01)81341-7
• 作为产物：
  描述：

  N-(chloro-oxo-phenyl-lambda6-sulfanylidene)-1,1,1-trifluoromethanesulfonamide 在 dichlorotrifluoromethanesulfonamide 、 三氟化锑 作用下， 反应 0.05h， 生成 N-(trifluoromethylsulfonyl)phenylsulfonimidoyl fluoride
  参考文献：
  名称：

  The unusual reactivity of the mono- and bis- N-(trifluoromethylsulfonyl)-substituted azaanalogs of arenesulfonochlorides

  摘要：

  The reactions of N-(trifluoromethylsulfonyl)arenesulfonimidoyl- and N, N'- bis(trifluoromethylsulfonyl)arenesulfonodiimidoyl chlorides of general formulas Ar-S(0)(=NSO2CF3)Cl (1) and Ar-S(=NSO2CF3)(2)Cl (2) with ammonia have been investigated and found to yield the ammonium salts of [N-(trifluoromethylsulfonyl)arenesulfinylimino]-N' (trifluoromethylsulfonyl)amides. The high oxidative ability of the chlorides (1,2) have been shown. Thus, chlorides (2) react with benzene or trifluoromethylbenzene, to form the chlorobenzene or 3-chloro- trifluoromethylbenzene. The fluorides of the general formulas Ar-S(0)(=NSO2CF3)F and Ar-S(=NSO2CF3)(2)F have been prepared. Their interaction with ammonia leads to the usual formation of corresponding amides. The electron nature of new electron withdrawing substituents have been investigated.

  DOI：

  10.1016/s0040-4020(01)81341-7

文献信息

• Ionic compounds with delocalized anionic charge, and their use as ion conducting components or as catalysts
  申请人：ACEP Inc.

  公开号：US06340716B1

  公开（公告）日：2002-01-22

  The invention relates to an ionic compound corresponding to the formula [R1X1(Z1)—Q−—X2(Z2)—R2]m Mm+ in which Mm+ is a cation of valency m, each of the groups Xi is S═Z3, S═Z4, P—R3 or P—R4; Q is N, CR5, CCN or CSO2R5, each of the groups Zi is ═O, ═NC≡N, ═C(C≡N)2, ═NS(═Z)2R6 or ═C[S(═Z)2R6]2, each of the groups Ri, is Y, YO—, YS—, Y2N— or F, Y represents a monovalent organic radical or alternatively Y is a repeating unit of a polymeric frame. The compounds are useful for producing ion conducting materials or electrolytes, as catalysts and for doping polymers.

  该发明涉及与公式[R1X1(Z1)—Q−—X2(Z2)—R2]mMm+相对应的离子化合物，其中Mm+是价态为m的阳离子，每个Xi基团是S•Z3、S•Z4、P—R3或P—R4；Q是N、CR5、CCN或CSO2R5，每个Zi基团是•O、•NC≡N、•C(C≡N)2、•NS(•Z)2R6或•C[S(•Z)2R6]2，每个Ri基团是Y、YO—、YS—、Y2N—或F，Y代表一价有机基团，或者Y是聚合骨架的重复单元。这些化合物可用于制备离子导电材料或电解质，作为催化剂以及用于掺杂聚合物。
• Synthesis of new organic super acids—N-(trifluoromethylsulfonyl)imino derivatives of trifluoromethanesulfonic acid and bis(trifluoromethylsulfonyl)imide
  作者：Romute Yu Garlyauskayte、Alexander N. Chernega、Christophe Michot、Michel Armand、Yurii L. Yagupolskii、Lev M. Yagupolskii

  DOI：10.1039/b503286p

  日期：——

  N-trifluoromethylsulfonyl derivatives of trifluoromethyl- and phenylsulfonimidoyl imides have been synthesized by two different routes. Both methods are one-pot reactions, that run in mild conditions with good yields. Two novel organic super acids: bis[N-(trifluoromethylsulfonyl)trifluoromethanesulfonimidoyl]imide and N,N'-bis(trifluoromethyl-sulfonyl)diimino trifluoromethanesulfonic acid were prepared and

  三氟甲基和苯基磺酰亚胺基酰亚胺的N-三氟甲基磺酰基衍生物的盐已经通过两种不同的途径合成。两种方法都是一锅法反应，在温和条件下以高收率运行。制备了两种新型的有机超酸：双[N-（三氟甲基磺酰基）三氟甲烷磺酰亚胺基]亚胺和N，N'-双（三氟甲基磺酰基）二亚氨基三氟甲烷磺酸，并通过单晶X射线衍射获得了其钾盐的结构。 。
• Ionic compounds with a delocalized anionic charge, and their use as ion conducting components or as catalysts
  申请人：Armand Michel

  公开号：US20050158631A1

  公开（公告）日：2005-07-21

  The invention relates to an ionic compound corresponding to the formula [R 1 X 1 (Z 1 )-Q − X 2 (Z 2 )—R 2 ] m M m+ in which M m+ is a cation of valency m, each of the groups X i is S=Z 3 , S=Z 4 , P—R 3 or P—R 4 ; Q is N, CR 5 , CCN or CSO 2 R 5 , each of the groups Z i is ═O, ═NC≡N, ═C(C≡N) 2 , ═NS(=Z) 2 R 6 or ═C[S(=Z) 2 R 6 ] 2 , each of the groups R i , is Y, YO—, YS—, Y 2 N— or F, Y represents a monovalent organic radical or alternatively Y is a repeating unit of a polymeric frame. The compounds are useful for producing ion conducting materials or electrolytes, as catalysts and for doping polymers.

  本发明涉及一种离子化合物，其化学式为[R 1 X 1 (Z 1 )-Q - X 2 (Z 2 )-R 2 ] m M m+ 其中 M m+ 是化合价为 m 的阳离子，每个基团 X i 为 S=Z 3 ，S=Z 4 , P-R 3 或 P-R 4 Q 为 N、CR 5 、CCN 或 CSO 2 R 5 ，每个基团 Z i 是 ═O、═NC≡N、═C(C≡N) 2 ，═NS(=Z) 2 R 6 或 ═C[S(=Z) 2 R 6 ] 2 ，R i 是 Y、YO-、YS-、Y 2 N- 或 F，Y 代表一价有机基，或者 Y 是聚合物框架的重复单元。这些化合物可用于生产离子导电材料或电解质，也可用作催化剂和掺杂聚合物。
• Garlyauskajte Romute Yu., Sereda Sergej V., Yagupolskii Lev M., Tetrahedron, 50 (1994) N 23, S 6891-6906
  作者：Garlyauskajte Romute Yu., Sereda Sergej V., Yagupolskii Lev M.

  DOI：——

  日期：——
• US6340716B1
  申请人：——

  公开号：US6340716B1

  公开（公告）日：2002-01-22