2-[Bis(methylamino)phosphanyl]benzenesulfonic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[Bis(methylamino)phosphanyl]benzenesulfonic acid
• 英文别名: 2-[bis(methylamino)phosphanyl]benzenesulfonic acid
• 化学式: C₈H₁₃N₂O₃PS
• 分子量: 248.24
• InChiKey: DFYUZSDKFIMXEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.5
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  86.8
• 氢给体数：
  3
• 氢受体数：
  5

文献信息

• PRODUCTION METHOD OF POLAR GROUP-CONTAINING OLEFIN POLYMERS
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US20150368376A1

  公开（公告）日：2015-12-24

  The present invention relates to a method for producing a homopolymer of olefin represented by formula (1): CH 2 ═CHR 1 (R 1 is a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more thereof or a method for producing a copolymer of olefin represented by formula (1) with olefin containing a polar group represented by formula (2): CH 2 ═CHR 2 R 3 (R 2 is a hydrogen atom or methyl group, R 3 is —COOR 12 , —CN, —OCOR 12 , —OR 12 , —CH 2 —OCOR 12 , —CH 2 OH, —CH 2 —N(R 13 ) 2 or —CH 2 -Hal (R 12 , R 13 and Hal have the same meanings as stated in the description), using as a catalyst a metal complex of group 10 elements in the periodic system typified by the structure represented by formula 1 (“Men” represents a menthyl group and “Me” represents a methyl group). The present invention enables the production of high molecular weight polymers of the polar group-containing monomers such as polar group-containing allyl compounds.

  本发明涉及一种制备一种由式(1)表示的烯烃的同聚物的方法：CH2═CHR1(R1是氢原子或具有1到20个碳原子的烃基)，或两种或更多烯烃的共聚物，或者一种由式(1)表示的烯烃与含有极性基团的烯烃的共聚物的方法，该极性基团由式(2)表示： ═CHR2R3(R2是氢原子或甲基基团，R3是—COOR12、—CN、—OCOR12、—OR12、— —OCOR12、— OH、— —N(R13)2或— -Hal(R12、R13和Hal的含义与说明中所述相同)，使用一种以1号周期表的10族元素的金属配合物为催化剂，以式1所表示的结构为代表的金属配合物(“Men”表示薄荷基团，“Me”表示甲基基团)。本发明能够生产具有高分子量的极性基团含量的单体，例如极性基团含有烷基化合物的聚合物。
• METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN POLYMER
  申请人：The University of Tokyo

  公开号：EP3214100A1

  公开（公告）日：2017-09-06

  The present invention relates to a method for producing a copolymer of ethylene and a polar group-containing olefin using as a catalyst a metal complex of group 10 elements having a structure represented by formula (C4) and (C5) (in the formula, "Men" represents a menthyl group and "Me" represents a methyl group). The method of the present invention makes it possible to produce a polar group-containing olefin polymer available for various applications, as being a high molecular weight body, which has been difficult to produce, and to produce the polymer in a molecular weight range such that the polymer has good moldability.

  本发明涉及一种生产乙烯和含极性基团烯烃共聚物的方法，该方法使用具有式 (C4) 和 (C5) 所代表结构的第 10 族元素金属络合物作为催化剂 (式中，"Men "代表薄荷基，"Me "代表甲基）。通过本发明的方法，可以生产出用于各种用途的含极性基团的烯烃聚合物，这种聚合物是一种高分子量体，很难生产，而且生产出的聚合物分子量范围大，具有良好的成型性。
• US9499644B2
  申请人：——

  公开号：US9499644B2

  公开（公告）日：2016-11-22
• [EN] PRODUCTION METHOD OF POLAR GROUP-CONTAINING OLEFIN POLYMERS<br/>[FR] PROCÉDÉ DE PRODUCTION DE POLYMÈRES D'OLÉFINE CONTENANT UN GROUPE POLAIRE
  申请人：UNIV TOKYO

  公开号：WO2014115895A1

  公开（公告）日：2014-07-31

  The present invention relates to a method for producing a homopolymer of olefin represented by formula (1): CH2=CHR1 (R1 is a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more thereof or a method for producing a copolymer of olefin represented by formula (1) with olefin containing a polar group represented by formula (2) : CH2=CHR2R3 (R2 is a hydrogen atom or methyl group, R3 is -COOR12, -CN, -OCOR12, -OR12, -CH2-OCOR12, -CH2OH, -CH2-N(R13)2 or -CH2-Hal (R12, R13 and Hal have the same meanings as stated in the description), using as a catalyst a metal complex of group 10 elements in the periodic system typified by the structure represented by formula 1 ("Men" represents a menthyl group and "Me" represents a methyl group). The present invention enables the production of high molecular weight polymers of the polar group-containing monomers such as polar group-containing allyl compounds.
• [EN] METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN POLYMER<br/>[FR] PROCÉDÉ DE PRODUCTION DE POLYMÈRE OLÉFINIQUE CONTENANT UN GROUPE POLAIRE<br/>[JA] 極性基含有オレフィン系重合体の製造方法
  申请人：UNIV TOKYO

  公开号：WO2016067776A1

  公开（公告）日：2016-05-06

  　本発明は、下記式（Ｃ４）、（Ｃ５）に代表される構造を有する周期表第１０族金属錯体を触媒として用いる、エチレンと極性基を有するオレフィンとの共重合体の製造方法に関する。（式中、Ｍｅｎはメンチル基を表し、Ｍｅはメチル基を表す。）　本発明の方法によれば、種々の応用が可能な極性基を有するオレフィン重合体を、これまで製造が困難であった高分子量体として、かつ成形加工性良好な分子量範囲で製造することができる。