Inimer-containing random copolymers and crosslinked copolymer films for dense polymer brush growth
申请人:Wisconsin Alumni Research Foundation
公开号:US10106699B2
公开(公告)日:2018-10-23
Crosslinkable random copolymers comprising atom transfer radical polymerization (ATRP) initiators and crosslinked copolymer films formed from the copolymers are provided. The random copolymers, which are polymerized from one or more alkyl halide functional inimers and one or more monomers having a crosslinkable functionality, are characterized by pendant ATRP initiating groups and pendant crosslinkable groups.
提供了包含原子转移自由基聚合(ATRP)引发剂的可交联无规共聚物以及由该共聚物形成的交联共聚物薄膜。这些无规共聚物由一种或多种烷基卤化物官能团嵌段聚合物和一种或多种具有可交联官能团的单体聚合而成,其特征在于具有悬垂的 ATRP 起始基团和悬垂的可交联基团。