2,3-Bis(4-bromophenyl)aniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-Bis(4-bromophenyl)aniline
• 英文别名: 2,3-bis(4-bromophenyl)aniline
• 化学式: C₁₈H₁₃Br₂N
• 分子量: 403.1
• InChiKey: DJGUDFRUEHRVDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• CROSS-LINKING POLYMER AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2770006A1

  公开（公告）日：2014-08-27

  A polymer including structural units represented by the following formulas (A) and (B). In the formula (A), P is a group derived from a compound represented by the formula (P). L1 is a linkage group. In the formula (B), Q is a group derived from a compound represented by the formula (Q). L2 is a linkage group. In the formula (B), at least one of "c"Qs and "d"L2s includes a cross-linkable group.

  一种聚合物，包括由以下式子(A)和(B)代表的结构单元。 在式 (A) 中，P 是由式 (P) 所代表的化合物衍生的基团。L1 是连接基团。在式(B)中，Q 是由式(Q)代表的化合物衍生的基团。L2 是连接基团。在式 (B) 中，"c "Qs 和 "d "L2s 中至少有一个包括可交联基团。
• METHOD FOR PRODUCING POLYMER COMPOUND
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3489275A1

  公开（公告）日：2019-05-29

  To provide a polymer compound production method capable of obtaining a polymer compound having sufficiently large molecular weight. A production method of a polymer compound having a constitutional unit represented by the formula (3-1) and a constitutional unit represented by the formula (3-2), comprising a reaction step of reacting a compound represented by the formula (1) and a compound represented by the formula (2) in the presence of a transition metal complex, a base and an organic solvent having a peroxide amount of 15 ppm by weight or less: [wherein, Ar1 and Ar2 represent a divalent aromatic hydrocarbon group, a divalent heteroaromatic group, a group represented by the formula (4) or the like. X1 represents a bromine atom or the like. X2 represents -B(OH)2, a borane residue, a borate ester residue or the like.] [wherein, Ar represents a divalent aromatic hydrocarbon group, a divalent heteroaromatic group or the like. Ar' represents an aryl group or a monovalent heteroaromatic group. m represents an integer of 0 to 2.].

  提供一种能获得分子量足够大的聚合物化合物的聚合物化合物生产方法。 一种具有由式（3-1）表示的组成单元和由式（3-2）表示的组成单元的聚合物化合物的生产方法，包括以下反应步骤：在过渡金属络合物、碱和过氧化物含量不超过 15ppm （以重量计）的有机溶剂存在下，使由式（1）表示的化合物和由式（2）表示的化合物反应： [其中，Ar1 和 Ar2 代表二价芳烃基团、二价杂芳烃基团、式 (4) 所代表的基团或类似基团。X1 代表溴原子或类似物。X2 代表-B(OH)2、硼烷残基、硼酸酯残基或类似物]。 [其中，Ar 代表二价芳烃基团、二价杂芳烃基团或类似基团。Ar'代表芳基或一价杂芳族基团。m 代表 0 至 2 的整数。］
• Production method of polymer compound
  申请人：Sumitomo Chemical Company, Limited

  公开号：US10717809B2

  公开（公告）日：2020-07-21

  The invention provides a production method of a polymer compound having a constitutional unit represented by the formula (3-1) and a constitutional unit represented by the formula (3-2), which contains a step of reacting a compound represented by the formula (1) and a compound represented by the formula (2) in the presence of a transition metal complex, a base and an organic solvent having a peroxide amount of 15 ppm by weight or less: wherein Ar1 and Ar2 represent a divalent aromatic hydrocarbon group, a divalent heteroaromatic group, a group represented by the formula (4) or the like; X1 represents a bromine atom or the like; X2 represents —B(OH)2, a borane residue, a borate ester residue or the like; wherein Ar represents a divalent aromatic hydrocarbon group, a divalent heteroaromatic group or the like, Ar′ represents an aryl group or a monovalent heteroaromatic group, m represents an integer of 0-2.

  本发明提供了一种具有由式（3-1）表示的构型单元和由式（3-2）表示的构型单元的聚合物化合物的生产方法，该方法包含以下步骤：在过渡金属络合物、碱和过氧化物含量不超过 15 ppm（重量）的有机溶剂存在下，使由式（1）表示的化合物和由式（2）表示的化合物发生反应： 其中 Ar1 和 Ar2 代表二价芳烃基团、二价杂芳烃基团、式（4）代表的基团或类似基团；X1 代表溴原子或类似原子；X2 代表-B(OH)2、硼烷残基、硼酸酯残基或类似残基； 其中 Ar 代表二价芳香烃基团、二价杂芳香族基团或类似基团，Ar′ 代表芳基或一价杂芳香族基团，m 代表 0-2 的整数。
• PRODUCTION METHOD OF POLYMER COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20190185613A1

  公开（公告）日：2019-06-20

  The invention provides a production method of a polymer compound having a constitutional unit represented by the formula (3-1) and a constitutional unit represented by the formula (3-2), which contains a step of reacting a compound represented by the formula (1) and a compound represented by the formula (2) in the presence of a transition metal complex, a base and an organic solvent having a peroxide amount of 15 ppm by weight or less: wherein Ar 1 and Ar 2 represent a divalent aromatic hydrocarbon group, a divalent heteroaromatic group, a group represented by the formula (4) or the like; X 1 represents a bromine atom or the like; X 2 represents —B(OH) 2 , a borane residue, a borate ester residue or the like; wherein Ar represents a divalent aromatic hydrocarbon group, a divalent heteroaromatic group or the like, Ar′ represents an aryl group or a monovalent heteroaromatic group, m represents an integer of 0-2.
• US9917273B2
  申请人：——

  公开号：US9917273B2

  公开（公告）日：2018-03-13