2-benzoylamino-1,3-bis-benzoyloxy-propane | 71811-34-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-benzoylamino-1,3-bis-benzoyloxy-propane
• 英文别名: O.O.N-Tribenzoyl-β-amino-trimethylenglykol；N-(β.β'-Dibenzoyloxy-isopropyl)-benzamid；2-Benzoylamino-1,3-bis-benzoyloxy-propan；2-(Benzoylamino)propane-1,3-diyl dibenzoate；(2-benzamido-3-benzoyloxypropyl) benzoate
• CAS: 71811-34-2
• 化学式: C₂₄H₂₁NO₅
• 分子量: 403.434
• InChiKey: XCOPAQRFOWAUFZ-UHFFFAOYSA-N

物化性质

• 沸点：
  631.1±50.0 °C(Predicted)
• 密度：
  1.230±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  30
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  81.7
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  N-[2-hydroxy-1-(hydroxymethyl)ethyl]benzamide 、 苯甲酰氯 在 喹啉 作用下， 生成 2-benzoylamino-1,3-bis-benzoyloxy-propane
  参考文献：
  名称：

  Schmidt,E.; Wilkendorf, Chemische Berichte, 1919, vol. 52, p. 393,395

  摘要：

  DOI：

文献信息

• Palladium-Catalyzed Selective Amino- and Alkoxycarbonylation of Iodoarenes with Aliphatic Aminoalcohols as Heterobifunctional O,N-Nucleophiles
  作者：László Kollár、Attila Takács、Csilla Molnár、Andrew Kovács、László T. Mika、Péter Pongrácz

  DOI：10.1021/acs.joc.2c02712

  日期：2023.4.21

  heteroaromatic substrates and numerous related nucleophiles were tested under optimized conditions, providing moderate to good yields of the target compounds. Reactions of serinol and 1,3-diamino-2-propanol as model trifunctional compounds showed particularly high chemoselectivity on amide ester products. Considering the coordinative properties of the applied nucleophiles, a rational catalytic cycle was proposed

  在脂肪族异双功能 N,O-亲核试剂存在的情况下，研究了钯催化的芳基碘化物的氨基和烷氧基羰基化反应。实现了酰胺醇和酰胺酯的选择性合成，由碱和底物的比例控制。还研究了碘苯取代基对产物选择性的影响，结果令人惊讶。除了模型乙醇胺/碘苯系统外，还在优化条件下测试了各种杂芳基底物和许多相关亲核试剂，提供了中等至良好的目标化合物收率。丝氨醇和 1,3-二氨基-2-丙醇作为模型三官能化合物的反应对酰胺酯产物显示出特别高的化学选择性。考虑到所应用的亲核试剂的配位性质，
• Cellulose ester film, polarizing plate, and liquid crystal display device
  申请人：FUJIFILM Corporation

  公开号：US10338290B2

  公开（公告）日：2019-07-02

  A cellulose ester film contains a compound having a structural unit denoted by —NR—(C═O)— in which R represents a hydrogen atom or a substituent, a surface having knoop hardness of greater than or equal to 210 N/mm2 is provided, and loss tangent tan δ at 25° C. is greater than or equal to 0.03.

  一种纤维素酯薄膜含有一种化合物，其结构单元用-NR-(C═O)-表示，其中R代表氢原子或取代基，表面硬度大于或等于210牛顿/平方毫米，25°C时的损耗正切tanδ大于或等于0.03。
• CELLULOSE ACYLATE FILM, PROTECTIVE FILM FOR POLARIZING PLATE, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM CORPORATION

  公开号：US20130120839A1

  公开（公告）日：2013-05-16

  There is provided a cellulose acylate film, containing a hindered amin-based compound, wherein the hindered amine-based compound is contained in an amount of 0.001% by mass to 5% by mass based on cellulose acylate, a minimum value of Knoop hardness is 170 N/mm 2 to 220 N/mm 2 , and the Knoop hardness is measured several times by a Knoop indenter, the Knoop indenter is rotated by a given angle in each measurement, and a rotation axis of the Knoop indenter is orthogonal to an upper surface of the cellulose acylate film.
• PROTECTIVE FILM FOR POLARIZING PLATE, POLARIZING PLATE AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20140185135A1

  公开（公告）日：2014-07-03

  A protective film for polarizing plate contains a resin, an ultraviolet absorbing agent A having an absorption maximum in a wavelength range of from 350 to 400 nm and an ultraviolet absorbing agent B having an absorption maximum in a wavelength range of from 270 to 330 nm, and a content of the ultraviolet absorbing agent A is from 0.1 to 5% by weight relative to the resin, a content of the ultraviolet absorbing agent B is from 0.1 to 5% by weight relative to the resin, and the protective film fulfills the requirements (a) to (d) as defined herein.
• CELLULOSE ESTER FILM, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160370522A1

  公开（公告）日：2016-12-22

  A cellulose ester film contains a compound having a structural unit denoted by —NR—(C═O)— in which R represents a hydrogen atom or a substituent, a surface having knoop hardness of greater than or equal to 210 N/mm 2 is provided, and loss tangent tan δ at 25° C. is greater than or equal to 0.03.