[6-(2-Methylprop-2-enoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl] 2-methylprop-2-enoate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃类
• 英文名称: [6-(2-Methylprop-2-enoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl] 2-methylprop-2-enoate
• 英文别名: [6-(2-methylprop-2-enoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl] 2-methylprop-2-enoate
• 化学式: C₁₄H₁₈O₆
• 分子量: 282.293
• InChiKey: PFRZAAUSRRCGRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  isosorbide 、 甲基丙烯酰氯 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以53.55%的产率得到[6-(2-Methylprop-2-enoyloxy)-2,3,3a,5,6,6a-hexahydrofuro[3,2-b]furan-3-yl] 2-methylprop-2-enoate
  参考文献：
  名称：

  CN114409668

  摘要：

  公开号：

文献信息

• VERFAHREN ZUR SYNTHESE VON ISOSORBIDMONO- UND DI-(METH)ACRYLAT
  申请人：BASF SE

  公开号：EP3489241A1

  公开（公告）日：2019-05-29

  Verfahren zur Herstellung von Isosorbid-Estern der (Meth)acrylsäure oder einem Derivat davon durch Umsetzung von (Meth)acrylsäure oder einem Derivat davon mit Isosorbid oder einem Derivat davon in Gegenwart wenigstens eines die Veresterungsreaktion katalysierenden Enzyms bei einer Reaktionstemperatur von 10 bis 100°C.

  一种制备(甲基)丙烯酸或其衍生物的异山梨醇酯的工艺，在至少一种催化酯化反应的酶存在下，在 10 至 100°C 的反应温度下，使(甲基)丙烯酸或其衍生物与异山梨醇或其衍生物反应。
• Process to produce blended (meth)acrylate/vinyl ester resin cross-linkers
  申请人：DREXEL UNIVERSITY

  公开号：US11208420B2

  公开（公告）日：2021-12-28

  This invention outlines a method for synthesizing a blended resin system in a one pot reaction that may utilize, for example, bio-based anhydrosugars such as isosorbide as a principle component to produce isosorbide dimethacrylate and other monomeric materials for thermosetting applications. This invention establishes a one-pot procedure for reacting a hydroxy group containing compound with methacrylic anhydride in the first step and using the by-product methacrylic acid to react with glycidyl ethers to form additional methacrylate compounds in the second step. This methodology can be formulated to produce a wide array of resin systems that have controlled ratios of hydroxy group containing compound/crosslinker/reactive diluent. Additionally, the novel resin systems may be partially to fully biobased, promoting global sustainability and reducing costs, and when free radically polymerized have properties that meet or exceed their petroleum derived counterparts.

  本发明概述了一种在一锅反应中合成混合树脂体系的方法，该方法可利用例如异山梨醇等生物基无水糖作为主要成分，生产异山梨醇二甲基丙烯酸酯和其他热固性应用的单体材料。本发明建立了一种单锅程序，第一步使含有羟基的化合物与甲基丙烯酸酐反应，第二步利用副产物甲基丙烯酸与缩水甘油醚反应生成额外的甲基丙烯酸酯化合物。这种方法可以配制出多种树脂体系，这些体系中含羟基化合物/交联剂/反应稀释剂的比例都是可控的。此外，新型树脂体系可以部分或全部采用生物基，从而促进全球可持续发展并降低成本，而且在自由基聚合时，其性能可以达到或超过石油衍生的同类产品。
• PROCESS FOR PREPARING POLYMERS HAVING ENHANCED GLASS TRANSITION TEMPERATURES FROM RENEWABLE BIO-BASED (METH)ACRYLATED MONOMERS IN THE PRESENCE OF A VINYL ESTER RESIN MONOMER OR UNSATURATED POLYESTER MONOMER
  申请人：Drexel University

  公开号：EP2742055B1

  公开（公告）日：2019-10-16
• RENEWABLE BIO-BASED (METH) ACRYLATED MONOMERS AS VINYL ESTER CROSS-LINKERS
  申请人：Palmese Giuseppe R.

  公开号：US20140249285A1

  公开（公告）日：2014-09-04

  Anhydrosugar-based monomers prepared from isosorbide, isomannide, and isoidide and resin systems containing these anhydrosugar-based monomers that are partially to fully bio-based, which may produce materials having properties that meet or exceed the properties of similar petroleum derived vinyl ester resins.
• MOLECULARLY IMPRINTED POLYMER FOR SELECTIVELY TRAPPING ODOROUS MOLECULES
  申请人：L'OREAL

  公开号：US20150320667A1

  公开（公告）日：2015-11-12

  The invention relates to the use of molecularly imprinted polymer(s) or MIPs, of odorous molecule(s), as deodorant agent in particular for selectively trapping molecules that are the cause of human body odour. More particularly by using MIPs which may be obtained via polymerization, preferably via radical polymerization, of a mixture of: i) optionally one or more polymerization initiator(s); ii) one or more functional monomer(s); iii) one or more crosslinking agent(s); and iv) one or more porogenic solvent(s); it being understood that the polymerization a) or b) is performed in the presence v) of one or more “templates” of target molecule(s) responsible for human body odour. Another subject of the invention concerns a process for preparing MIPs as defined previously, MIPs obtained via this process, and a cosmetic composition comprising at least one MIP as defined previously. Unexpectedly, it appears that the MIPs make it possible to specifically trap precursors of odorous molecules and odorous molecules that may be used in cosmetic formulations, especially those that are the cause of the unpleasant odour of sweat.