4-Fluoro-2,6-bis(methylsulfanyl)phenol

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 4-Fluoro-2,6-bis(methylsulfanyl)phenol
• 英文别名: 4-fluoro-2,6-bis(methylsulfanyl)phenol
• 化学式: C₈H₉FOS₂
• 分子量: 204.3
• InChiKey: FDDOUQRWIURGSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  70.8
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• MOLYBDENUM AND TUNGSTEN COMPLEXES AS OLEFIN METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS
  申请人：XiMo AG

  公开号：EP2703081B1

  公开（公告）日：2019-08-07
• [EN] METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS<br/>[FR] CATALYSEURS DE MÉTATHÈSE ET RÉACTIONS UTILISANT LES CATALYSEURS
  申请人：XIMO AG

  公开号：WO2014139679A2

  公开（公告）日：2014-09-18

  The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1 : 500 or less, and the conversion of the first or the second olefin to said olefin is at least 50 %, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6-X-, wherein X = O and R6 is aryl, optionally substituted; or X = S and R6 is aryl, optionally substituted; or X = O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X = O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.