(S)-6,6'-bis(4''-pyridyl)-2,2'-bis(tert-butyldimethylsiloxy)-1,1'-binaphthalene | 785786-53-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (S)-6,6'-bis(4''-pyridyl)-2,2'-bis(tert-butyldimethylsiloxy)-1,1'-binaphthalene
• 英文别名: Tert-butyl-[1-[2-[tert-butyl(dimethyl)silyl]oxy-6-pyridin-4-ylnaphthalen-1-yl]-6-pyridin-4-ylnaphthalen-2-yl]oxy-dimethylsilane；tert-butyl-[1-[2-[tert-butyl(dimethyl)silyl]oxy-6-pyridin-4-ylnaphthalen-1-yl]-6-pyridin-4-ylnaphthalen-2-yl]oxy-dimethylsilane
• CAS: 785786-53-0；785786-48-3
• 化学式: C₄₂H₄₈N₂O₂Si₂
• 分子量: 669.026
• InChiKey: FDLWOXRXTAOSDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.55
• 重原子数：
  48
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [Pt(1,2-bis(diphenylphosphino)ethane)(OTf)2] 、 (S)-6,6'-bis(4''-pyridyl)-2,2'-bis(tert-butyldimethylsiloxy)-1,1'-binaphthalene 以 二氯甲烷 为溶剂， 以81%的产率得到(S)-[Pt(1,2-bis(diphenylphosphino)ethane)(6,6'-bis(4''-pyridyl)-2,2'-bis(tert-butyldimethylsiloxy)-1,1'-binaphthalene)]4[OTf]8
  参考文献：
  名称：

  Chiral Molecular Squares Based on Angular Bipyridines:  Self-Assembly, Characterization, and Photophysical Properties

  摘要：

  Chiral molecular squares 1-12 based on [M(dppe)](2+) metallocorners (M = Pd or Pt, and dppe = bis-(diphenylphosphino)ethane) and new angular bipyridine bridging ligands derived from the 1,1'-binaphthyl framework were readily assembled and characterized by a variety of techniques including infrared, UV-vis, circular dichroism (CD), and NMR spectroscopy, and ESI mass spectrometry. All these chiral metallocycles are highly luminescent in solution at room temperature with quantum efficiency of 0.06-0.63. Interestingly, when equal molar enantiopure molecular squares of opposite handedness were mixed in solution, a new meso dimeric metallocycle with C-2 symmetry formed. This result indicates the lability of the M-pyridyl bonds in these metallocycles, which may hinder their applications in many enantioselective processes.

  DOI：

  10.1021/ic0497937

文献信息

• Chiral Molecular Squares Based on Angular Bipyridines:  Self-Assembly, Characterization, and Photophysical Properties
  作者：Suk Joong Lee、Jason S. Kim、Wenbin Lin

  DOI：10.1021/ic0497937

  日期：2004.10.1

  Chiral molecular squares 1-12 based on [M(dppe)](2+) metallocorners (M = Pd or Pt, and dppe = bis-(diphenylphosphino)ethane) and new angular bipyridine bridging ligands derived from the 1,1'-binaphthyl framework were readily assembled and characterized by a variety of techniques including infrared, UV-vis, circular dichroism (CD), and NMR spectroscopy, and ESI mass spectrometry. All these chiral metallocycles are highly luminescent in solution at room temperature with quantum efficiency of 0.06-0.63. Interestingly, when equal molar enantiopure molecular squares of opposite handedness were mixed in solution, a new meso dimeric metallocycle with C-2 symmetry formed. This result indicates the lability of the M-pyridyl bonds in these metallocycles, which may hinder their applications in many enantioselective processes.