4,4'-Dihydroxy-3-methyl-diphenylsulfon | 23328-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-Dihydroxy-3-methyl-diphenylsulfon
• 英文别名: 6-Hydroxy-3-(4-hydroxy-phenylsulfon)-toluol；(4-Hydroxy-phenyl)-(4-hydroxy-3-methyl-phenyl)-sulfon；2-Methyl-4,4'-sulfonyl-di-phenol；4-(4-Hydroxyphenyl)sulfonyl-2-methylphenol
• CAS: 23328-75-8
• 化学式: C₁₃H₁₂O₄S
• 分子量: 264.302
• InChiKey: VLWWFHUHAUULFE-UHFFFAOYSA-N

物化性质

• 熔点：
  244-245 °C
• 沸点：
  511.4±50.0 °C(Predicted)
• 密度：
  1.384±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  83
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4,4'-Dihydroxy-3-methyl-diphenylsulfon 生成 2-benzoyloxy-5-(4-benzoyloxy-benzenesulfonyl)-toluene
  参考文献：
  名称：

  Zehenter; Plass, Journal fur praktische Chemie (Leipzig 1954), 1930, vol. <2> 127, p. 263,264

  摘要：

  DOI：
• 作为产物：
  描述：

  (4-acetoxy-3-methyl-phenyl)-(4-acetoxy-phenyl)-sulfone 在 sodium hydroxide 作用下， 生成 4,4'-Dihydroxy-3-methyl-diphenylsulfon
  参考文献：
  名称：

  Reich,G.; Hebestreit,G., Journal fur praktische Chemie (Leipzig 1954), 1961, vol. 13, p. 39 - 46

  摘要：

  DOI：

文献信息

• Positive photosensitive resin composition, photo-curable dry film and method for producing the same, patterning process, and laminate
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10197914B2

  公开（公告）日：2019-02-05

  The present invention provides a positive photosensitive resin composition containing (A) a polymer compound containing a siloxane chain, the polymer compound having a repeating unit shown by the general formula (1) and a weight average molecular weight of 3,000 to 500,000, (B) a photosensitive material capable of generating an acid by light and increasing a dissolution rate in an aqueous alkaline solution, (C) a crosslinking agent, and (D) a solvent. There can be provided a positive photosensitive resin composition that can remedy the problem of delamination caused on a metal wiring such as Cu and Al, an electrode, and a substrate, especially on a substrate such as SiN, and can form a fine pattern having a forward tapered shape without generating a scum and a footing profile in the pattern bottom and on the substrate when a widely used 2.38% TMAH aqueous solution is used as the developer.

  本发明提供了一种含有（A）含有硅氧烷链的聚合物化合物的阳性感光树脂组合物，该聚合物化合物具有由通式（1）所示的重复单元和重量平均分子量为3,000至500,000，（B）能够通过光生成酸并增加在水性碱性溶液中的溶解速率的感光材料，（C）交联剂和（D）溶剂。可以提供一种阳性感光树脂组合物，可以解决在金属线路（如Cu和Al）、电极和基板上引起的剥离问题，特别是在SiN等基板上，可以在使用广泛的2.38％TMAH水溶液作为显影剂时，在图案底部和基板上形成具有前向锥形形状的细微图案，而不会产生污点和底部轮廓。
• 4-HYDROXY-4'-ISOPROPOXYDIPHENYL SULFONE DEVELOPER COMPOSITION, WET PULVERIZING METHOD, AND DISPERSION
  申请人：NIPPON SODA CO., LTD.

  公开号：EP0697291A1

  公开（公告）日：1996-02-21

  A method of preventing hydration of 4-hydroxy-4'-isopropoxydiphenyl sulfone characterized by wet pulverizing the sulfone in water in the presence of a diphenyl sulfone derivative represented by general formula (I): (wherein R¹ represents hydrogen or lower alkyl; R² and R³ represent each independently lower alkyl; and n and m represent each an integer of 0, 1 to 4, provided when R¹ is hydrogen, not both of m and n are 0 at the same time). A highly sensitive recording paper free from scumming can be produced by using a dispersion of a developer comprising the above sulfone.

  一种防止4-羟基-4'-异丙氧基二苯砜水合的方法，其特征在于在通式(I)代表的二苯砜衍生物存在下，在水中湿法粉碎该砜：(其中R¹代表氢或低级烷基；R²和R³各自独立地代表低级烷基；n和m各自代表0、1至4的整数，条件是当R¹为氢时，m和n不能同时为0）。通过使用包含上述砜的显影剂的分散体，可以生产出无浮渣的高灵敏度记录纸。
• POLY(IMIDE-AMIDE)COPOLYMER, METHOD FOR PREPARING POLY(IMIDE-AMIDE)COPOLYMER, ARTICLE CONTAINING POLY(IMIDE-AMIDE)COPOLYMER, AND ELECTRONIC DEVICE INCLUDING SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3156436A1

  公开（公告）日：2017-04-19

  A poly(imide-amide) copolymer includes an imide structural unit being a reaction product of a first diamine and dianhydride, and an amide structural unit being a reaction product of a second diamine and diacyl halide, each of the first and the second diamines includes 2,2'-bis-trifluoromethyl-4,4'-biphenyldiamine (TFDB), and at least one of the first and the second diamines further includes a compound represented by Chemical Formula 1, the dianhydride includes 3,3',4,4'-biphenyltetracarboxylic dianhydride (BPDA) and 4,4'-hexafluoroisopropylidene diphthalicanhydride (6FDA), and the diacyl halide includes terephthaloylchloride (TPCl), and the compound represented by Chemical Formula 1 is included in an amount of less than or equal to about 10 mol% based on the total amount of the diamine. A film and an electronic device including the poly(imide-amide) copolymer are provided:         (Chemical Formula 1)     NH2-A-NH2 In Chemical Formula 1, A comprises a hydroxyl-substituted aryl group and is further described in the detailed description.

  一种聚(酰亚胺-酰胺)共聚物包括作为第一二胺和二酐反应产物的酰亚胺结构单元，以及作为第二二胺和二酰卤反应产物的酰胺结构单元，第一和第二二胺中的每一种都包括2,2'-双三氟甲基-4,4'-联苯二胺(TFDB)，第一和第二二胺中的至少一种进一步包括由化学式1表示的化合物、二酐包括 3,3',4,4'-联苯四羧酸二酐（BPDA）和 4,4'-六氟异丙亚基二酞酸酐（6FDA），二酰卤包括对苯二甲酰氯（TPCl），且化学式 1 所代表的化合物的含量小于或等于二胺总量的约 10 摩尔%。提供了一种包括聚（亚胺-酰胺）共聚物的薄膜和电子设备： (化学式 1）NH2-A-NH2 在化学式 1 中，A 包括羟基取代的芳基，详见详细说明。
• COMPOSITION FOR PREPARING POLY(IMIDE-AMIDE)COPOLYMER, POLY(IMIDE-AMIDE)COPOLYMER, ARTICLE CONTAINING POLY(IMIDE-AMIDE)COPOLYMER, AND ELECTRONIC DEVICE INCLUDING SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3461856A1

  公开（公告）日：2019-04-03

  A composition for preparing a poly(imide-amide) copolymer includes an amine-terminated oligomer, a diamine represented by Chemical Formula 1, 3,3',4,4'-biphenyltetracarboxylic dianhydride (BPDA) and 4,4'-hexafluoroisopropylidene diphthalicanhydride (6FDA), wherein the amine-terminated oligomer is a reaction product or 2,2'-bis-trifluoromethyl-4,4'-biphenyldiamine (TFDB) and terephthaloylchloride (TPCI) and wherein A in Chemical Formula 1 comprises at least two aromatically bound hydroxyl groups. A poly(imide-amide) prepared from the composition, as well as a film and an electronic device including the poly(imide-amide) copolymer are provided:         (Chemical Formula 1)     NH2-A-NH2 In Chemical Formula 1, A is the same as described in the detailed description.

  一种用于制备聚(酰亚胺-酰胺)共聚物的组合物，包括胺封端低聚物、化学式 1 所代表的二胺、3,3',4,4'-联苯四羧酸二酐(BPDA)和 4,4'-六氟异丙亚基二酞酸酐(6FDA)、其中胺封端低聚物是 2,2'-双三氟甲基-4,4'-联苯二胺（TFDB）和对苯二甲酰氯（TPCI）的反应产物，且化学式 1 中的 A 包含至少两个芳香结合的羟基。提供了由该组合物制备的聚（亚胺-酰胺）以及包括该聚（亚胺-酰胺）共聚物的薄膜和电子设备： (化学式 1）NH2-A-NH2 在化学式 1 中，A 与详细说明中所述相同。
• Reich; Hebenstreit, Journal fur praktische Chemie (Leipzig 1954), 1961, vol. <4> 13, p. 39,40, 43
  作者：Reich、Hebenstreit

  DOI：——

  日期：——