申请人:——
公开号:US20010040008A1
公开(公告)日:2001-11-15
The invention relates to aqueous polymer dispersions suitable as reactive resin component (A) for a two-component reactive system. To obtain reactive systems which can be produced without solvents and which, in addition, combine good adhesion values with excellent optical properties of the laminates, good substrate wetting, high initial tack and high water resistance of the laminates, the dispersion is characterized in that at least 20% by weight of the polymer content emanates from an aqueous dispersion of OH-functional polyurethane prepolymers obtainable by reaction of
a polyol component (I) containing polyester polyols and
compounds containing at least two isocyanate-reactive groups and, in addition, groups capable of salt formation (II) with
a stoichiometric excess of an isocyanate component (III) consisting of at least 20% by weight tetramethyl xylylene diisocyanate (TMXDI),
subsequent dispersion in water and
at least partial reaction of the remaining NCO groups with aminoalcohols (IV) and
if desired, subsequent chain extension.
本发明涉及适用于双组分反应体系的反应树脂组分(A)的水性聚合物分散体。为了获得不使用溶剂就能生产的反应体系,并兼具良好的附着力、层压板的优异光学性能、良好的基材润湿性、高初粘性和高耐水性,该分散体的特点是至少 20%(按重量计)的聚合物含量来自 OH 官能团聚氨酯预聚物的水性分散体,该预聚物可通过以下反应获得
含有聚酯多元醇的多元醇组分 (I) 和
含有至少两个异氰酸酯反应基团和可形成盐的基团的化合物(II)与
按一定比例过量的异氰酸酯成分(III),该异氰酸酯成分包括至少 20% (按重量计)的四甲基二异氰酸酯(TMXDI)、
随后分散在水中
至少使剩余的 NCO 基团与氨基醇(IV)发生部分反应,并在需要时进行延链。
如果需要,还可以进行后续的链延伸。