2-<2-(3,4-Dimethoxyphenyl)ethyl>-1,3,3,4,6-pentamethyl-3H-indolinium perchlorate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-<2-(3,4-Dimethoxyphenyl)ethyl>-1,3,3,4,6-pentamethyl-3H-indolinium perchlorate
• 英文别名: 2-<2-(3,4-dimethoxyphenyl)ethenyl>-1,3,3,4,6-pentamethylindolenium perchlorate；2-(2-(3,4-Dimethoxyphenyl)ethenyl)-1,3,3,4,6-pentamethyl-3H-indolium perchlorate；2-[(E)-2-(3,4-dimethoxyphenyl)ethenyl]-1,3,3,4,6-pentamethylindol-1-ium;perchlorate
• 化学式: C₂₃H₂₈NO₂*ClO₄
• 分子量: 449.931
• InChiKey: UKBSZXQBPGXIKP-LBEJWNQZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.28
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  95.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-<2-(3,4-Dimethoxyphenyl)ethyl>-1,3,3,4,6-pentamethyl-3H-indolinium perchlorate 以 水 为溶剂， 生成 2-[(Z)-2-(3,4-Dimethoxy-phenyl)-vinyl]-1,3,3,4,6-pentamethyl-3H-indolium; perchlorate
  参考文献：
  名称：

  Crown ether-containing styryl dyes

  摘要：

  The method for the synthesis of indoles from nitropyridinium salts has been improved. A method for synthesizing novel derivatives of indoleninium quaternary salts has been developed. The condensation of indoleninium salts with formyl derivatives of crown ethers leading to styryl dyes is described. Photoisomerization and complexing of crown-ether dyes with ions of alkaline and alkaline-earth metals have been studied. The shift of the long-wave absorption maximum has been observed to depend on the size and charge density of the metal cation.

  DOI：

  10.1007/bf00699196
• 作为产物：
  描述：

  2-[(Z)-2-(3,4-Dimethoxy-phenyl)-vinyl]-1,3,3,4,6-pentamethyl-3H-indolium; perchlorate 以 水 为溶剂， 生成 2-<2-(3,4-Dimethoxyphenyl)ethyl>-1,3,3,4,6-pentamethyl-3H-indolinium perchlorate
  参考文献：
  名称：

  Gromov, S. L.; Fomina, M. V.; Ushakov, E. N., Doklady Chemistry, 1990, vol. 314, # 4,6, p. 279 - 282

  摘要：

  DOI：