3-Jodo-1-methylpyridinium-kation | 54560-56-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3-Jodo-1-methylpyridinium-kation
• 英文别名: 3-iodo-1-methyl-pyridinium；3-Iodo-1-methylpyridin-1-ium
• CAS: 54560-56-4
• 化学式: C₆H₇IN
• 分子量: 220.033
• InChiKey: MVBDRXROBNCUDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  3.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-Jodo-1-methylpyridinium-kation 、 苯硼酸 在 potassium carbonate 作用下， 以 乙醇 、 水 为溶剂， 反应 4.0h， 以92%的产率得到1-methyl-3-phenylpyridinium iodide
  参考文献：
  名称：

  Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity

  摘要：

  A new type of robust, heterogeneous, modular Pd catalyst with metal embedded in the gel matrix is presented. The regulatory element of its catalytic activity has been introduced via chemical changes in the gel. The concept is illustrated in a series of Suzuki-Miyaura cross-coupling reactions. The demonstrated catalyst activity variations depend on the structure of the gel.

  DOI：

  10.1021/acs.orglett.5b03480

文献信息

• Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity
  作者：Iva Stibingerova、Svatava Voltrova、Sarka Kocova、Matthew Lindale、Jiri Srogl

  DOI：10.1021/acs.orglett.5b03480

  日期：2016.1.15

  A new type of robust, heterogeneous, modular Pd catalyst with metal embedded in the gel matrix is presented. The regulatory element of its catalytic activity has been introduced via chemical changes in the gel. The concept is illustrated in a series of Suzuki-Miyaura cross-coupling reactions. The demonstrated catalyst activity variations depend on the structure of the gel.