1,6:3,4-Dianhydro-2-O-p-toluenesulfonyl-b-D-galactopyranose

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6:3,4-Dianhydro-2-O-p-toluenesulfonyl-b-D-galactopyranose
• 英文别名: 3,7,9-trioxatricyclo[4.2.1.02,4]nonan-5-yl 4-methylbenzenesulfonate
• 化学式: C₁₃H₁₄O₆S
• mdl: MFCD01820797
• 分子量: 298.31
• InChiKey: XIOHREILWINAMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• METHOD FOR PREPARING 1,6:2,3-DIANHYDRO-BETA-D-MANNOPYRANOSE
  申请人：Grossi Pierre Jean

  公开号：US20110213141A1

  公开（公告）日：2011-09-01

  The invention relates to a method for preparing 1,6:2,3-dianhydro-â-D-mannopyranose and is characterized in that it includes a step of cyclizing the compound C, where R is an alykyl group and R′ is an activating agent, in an alcohol/alcoholate mixture under anhydrous conditions.

  本发明涉及一种制备1,6:2,3-二去氢-α-D-甘露糖的方法，其特征在于包括在无水条件下，在醇/醇酸盐混合物中环化化合物C的步骤，其中R为烷基，R'为活化剂。
• SHORT SYNTHETIC PATHWAY FOR 1,6:2,3-DIANHYDRO-BETA-D-MANNOPYRANOSE
  申请人：Bouvenot Laurent

  公开号：US20110224446A1

  公开（公告）日：2011-09-15

  The invention relates to a method for preparing 1,6:2,3-dianhydro-β-D-mannopyranose and is characterized in that it includes a step of cyclizing the compound B, where R is an activating agent, in the presence of a base selected from among ammonium hydroxides and mineral bases.

  本发明涉及一种制备1,6:2,3-二去水-β-D-甘露糖苷的方法，其特征在于，它包括在氨水和矿物质碱中选择一种碱的存在下，将化合物B环化的步骤，其中R是一种活性剂。
• PROCEDE DE PREPARATION DU 1,6:2,3-DIANHYDRO-BETA-D-MANNOPYRANOSE
  申请人：SANOFI

  公开号：EP2331549B1

  公开（公告）日：2014-10-22
• VOIE COURTE DE SYNTHESE DU 1,6:2,3-DIANHYDRO-BETA-D-MANNOPYRANOSE
  申请人：SANOFI

  公开号：EP2331550B1

  公开（公告）日：2013-11-13
• Water-Soluble Carbohydrate Polyethers
  申请人：GORKOVENKO Alexander A.

  公开号：US20120046435A1

  公开（公告）日：2012-02-23

  The present invention relates to novel carbohydrate polyether compositions that are soluble in aqueous media and particularly to carbohydrate polyether compositions exhibiting reverse thermogelation properties in aqueous media. Also, since the carbohydrate polyethers of the present invention can be conveniently controlled with respect to functionality, molecular weight, polydispersity index, microstructure and tertiary structure, they can be customized for use in a variety of applications.