[2-(4-bromophenyl)-5-pentylcyclohex-1-en-1-yl]methanol | 1345045-38-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [2-(4-bromophenyl)-5-pentylcyclohex-1-en-1-yl]methanol
• 英文别名: [2-(4-Bromophenyl)-5-pentylcyclohex-1-en-1-yl]methanol；[2-(4-bromophenyl)-5-pentylcyclohexen-1-yl]methanol
• CAS: 1345045-38-6
• 化学式: C₁₈H₂₅BrO
• 分子量: 337.3
• InChiKey: LLIVMDFHOWNIIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [2-(4-bromophenyl)-5-pentylcyclohex-1-en-1-yl]methanol 在 polyphosphoric acid (PPA) 作用下， 反应 0.33h， 以35%的产率得到7-bromo-2-pentyl-2,3,4,9-tetrahydro-1H-fluorene
  参考文献：
  名称：

  Synthesis of New Liquid Crystals with 2,3,4,9-Tetrahydro-1H-Fluorene Moiety

  摘要：

  A new range of liquid crystals containing the 2,3,4,9-tetrahydro-1H-fluorene system have been prepared and its thermal properties were examined. The mesomorphic properties are compared with those of the fluorene and trans-cyclohexane derivatives. Introduction of 2,3,4,9-tetrahydro-1H-fluorene in typical liquid crystal structure leads to decrease of melting point and the clearing point values. The chemical structures and mesogenic properties for the reported novel compounds are discussed.

  DOI：

  10.1080/15421406.2011.570542
• 作为产物：
  描述：

  对戊基环己酮 在 lithium aluminium tetrahydride 、 四丁基溴化铵 、 palladium diacetate 、 potassium carbonate 、 三氯氧磷 作用下， 以 乙醚 、 氯仿 、 水 为溶剂， 反应 4.17h， 生成 [2-(4-bromophenyl)-5-pentylcyclohex-1-en-1-yl]methanol
  参考文献：
  名称：

  Synthesis of New Liquid Crystals with 2,3,4,9-Tetrahydro-1H-Fluorene Moiety

  摘要：

  A new range of liquid crystals containing the 2,3,4,9-tetrahydro-1H-fluorene system have been prepared and its thermal properties were examined. The mesomorphic properties are compared with those of the fluorene and trans-cyclohexane derivatives. Introduction of 2,3,4,9-tetrahydro-1H-fluorene in typical liquid crystal structure leads to decrease of melting point and the clearing point values. The chemical structures and mesogenic properties for the reported novel compounds are discussed.

  DOI：

  10.1080/15421406.2011.570542

文献信息

• Synthesis of New Liquid Crystals with 2,3,4,9-Tetrahydro-1<i>H</i>-Fluorene Moiety
  作者：R. Ch. Geivandov、V. Mezhnev、T. Geivandova

  DOI：10.1080/15421406.2011.570542

  日期：2011.6.30

  A new range of liquid crystals containing the 2,3,4,9-tetrahydro-1H-fluorene system have been prepared and its thermal properties were examined. The mesomorphic properties are compared with those of the fluorene and trans-cyclohexane derivatives. Introduction of 2,3,4,9-tetrahydro-1H-fluorene in typical liquid crystal structure leads to decrease of melting point and the clearing point values. The chemical structures and mesogenic properties for the reported novel compounds are discussed.