poly[Ni(II) N,N'-bis(salicylidene)-o-phenylenediamine] | 6846-97-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: poly[Ni(II) N,N'-bis(salicylidene)-o-phenylenediamine]
• 英文别名: nickel(II) o-phenylene-N,N'-di(salicylaldiminate)；disalicylidene-o-phenylenediamine; nickel (II)-salt；Disalicyliden-o-phenylendiamin; Nickel(II)-Salz；Nickel(2+);2-[[2-[(2-oxidophenyl)methylideneamino]phenyl]iminomethyl]phenolate
• CAS: 6846-97-5
• 化学式: C₂₀H₁₄N₂O₂*Ni
• 分子量: 373.033
• InChiKey: IBHJSYHQCPRJSS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.33
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N'-o-phenylenebis(salicylideneiminato)nickel(II) 在 高氯酸四乙基铵 作用下， 以 乙腈 为溶剂， 生成 poly[Ni(II) N,N'-bis(salicylidene)-o-phenylenediamine]
  参考文献：
  名称：

  Electrochemical Synthesis of Thin Films of Polymers Derived from [NiSalen] and [NiSalphen]

  摘要：

  Electrochemical synthesis of conducting polymeric Ni(II) complexes with N,N'-bis(salicylidene)- ethylenediamine and N,N'-bis(salicylidene)-o-phenylenediamine was studied. The kinetic of this process was examined. The possibility of preparing the polymeric films with a definite thickness ranging from 0.01 to 2 mum was assessed.

  DOI：

  10.1023/b:rjac.0000015726.55537.c1

文献信息

• Infrared spectral studies on the stability of some binuclear transition metal—Schiff base complexes
  作者：Rajesh Nagar、R.C. Sharma、R.K. Parashar

  DOI：10.1016/0584-8539(90)80112-c

  日期：1990.1
• ——
  作者：A. Aidyn、A. A. Medzhidov、P. A. Fatullaeva、S. Tashchioglu、B. Yalchin、S. Saiyn

  DOI：10.1023/a:1011389632581

  日期：——

  Potentially tetradentate ligands N,N ' -di(2-hydroxybenzyl)ethylenediamine (L-1) and N,N ' -di(2-hydroxybenzyl)o-phenylenediamine (L-2) and complexes of Cu(II), Co(II), and Ni(II) with L-1 and L-2 were synthesized. The EPR and electronic spectroscopy methods were used to reveal the octahedral structure of the Cu(II) complex with L-1 in the solid state. In water-alcohol solutions, the Cu(II) and Ni(II) complexes with both ligands have distorted octahedral structures. The Co(II) complexes form dioxygen adduct with L-1. In the presence of oxygen, the ligands in the obtained complex compounds can undergo oxidative dehydrogenation with selective formation of the respective disalicylaldimines. In the case of L-2, the oxidative dehydrogenation is observed for the complexes of all studied metals in comparatively mild conditions (T = 30 degreesC, methanol and other solvents), while in the case of L-1, it occurs only with the Co(II) complexes in the presence of pyridine.