N,4-dimethyl-N-(p-tolyl)naphthalen-1-amine | 1365910-46-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,4-dimethyl-N-(p-tolyl)naphthalen-1-amine
• 英文别名: N,4-dimethyl-N-(4-methylphenyl)naphthalen-1-amine
• CAS: 1365910-46-8
• 化学式: C₁₉H₁₉N
• 分子量: 261.367
• InChiKey: WJBBBSRYVGIUKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-甲基-对甲基苯胺 、 (氯甲基)萘 在 sodium hydride 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 20.03h， 以81%的产率得到N,4-dimethyl-N-(p-tolyl)naphthalen-1-amine
  参考文献：
  名称：

  Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines

  摘要：

  Palladium-catalyzed amination of chloromethylnaphthalene and chloromethylanthracene derivatives to produce naphthylamines and anthrylamines in satisfactory to good yields has been developed. The unprecedented amination reactions proceeded smoothly under mild conditions in the presence of Pd(PPh3)(4) as a catalyst.

  DOI：

  10.1021/ja300164d

文献信息

• Fluorescent Organic Light Emitting Elements Having High Efficiency
  申请人：UDC IRELAND LIMITED

  公开号：US20170186976A1

  公开（公告）日：2017-06-29

  The present invention relates to organic light emitting elements, comprising thermally activated delayed fluorescence (TADF) emitters and/or hosts on basis of benzotriazoles, which have a sufficiently small energy gap between S 1 and T 1 (ΔE ST ) to enable up-conversion of the triplet exciton from T 1 to S 1 . The organic light emitting elements show high electroluminescent efficiency.
• FLUORESCENT ORGANIC LIGHT EMITTING ELEMENTS HAVING HIGH EFFICIENCY
  申请人：UDC IRELAND LIMITED

  公开号：US20180114925A1

  公开（公告）日：2018-04-26

  The present invention relates to organic light emitting elements, comprising thermally activated delayed fluorescence (TADF) emitters and/or hosts on basis of benzotriazoles, which have a sufficiently small energy gap between S 1 and T 1 (ΔE ST ) to enable up-conversion of the triplet exciton from T 1 to S 1 . The organic light emitting elements show high electroluminescent efficiency.
• US9853224B2
  申请人：——

  公开号：US9853224B2

  公开（公告）日：2017-12-26