2-phenyl-tetrahydro-cyclopenta[c]pyrrole-1,3-dione | 100393-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 2-phenyl-tetrahydro-cyclopenta[c]pyrrole-1,3-dione
• 英文别名: 2-Phenyl-tetrahydro-cyclopenta[c]pyrrol-1,3-dion；2-phenyl-4,5,6,6a-tetrahydro-3aH-cyclopenta[c]pyrrole-1,3-dione
• CAS: 100393-26-8
• 化学式: C₁₃H₁₃NO₂
• 分子量: 215.252
• InChiKey: MSYQBKNNMCFRHE-UHFFFAOYSA-N

物化性质

• 沸点：
  436.8±14.0 °C(Predicted)
• 密度：
  1.257±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯胺 、 alkaline earth salt of/the/ methylsulfuric acid 生成 2-phenyl-tetrahydro-cyclopenta[c]pyrrole-1,3-dione
  参考文献：
  名称：

  Perkin, Journal of the Chemical Society, 1894, vol. 65, p. 588

  摘要：

  DOI：

文献信息

• Neuartige Ni0-katalysierte Herstellung von 3-cyclopentencarbonsäureaniliden aus Cyclopentenen und Phenylisocyanat
  作者：Heinz Hoberg、Matthias Nohlen

  DOI：10.1016/0022-328x(90)85236-r

  日期：1990.2

  Cyclopentenes react with isocyanate on (Lig)Ni0-systems to form the bicyclic 5-azanickelacyclopentan-4-one derivates. The geometry of these butterfly complexes favors β-elimination of the β′-hydrogen atoms over that of the β- or β″-hydrogen. In a catalytic reaction the unsaturated amides 3-cyclopentene-carboxylic amide or 2-methylcyclopentene-3-carboxylic amide, both of which are substituted in position

  环戊烯与（Lig）Ni 0-系统上的异氰酸酯反应形成双环5-氮杂镍-环戊烷-4-一衍生物。这些蝶形配合物的几何形状比β-或β''-氢的β-氢原子更倾向于β-消除。在催化反应中，以高选择性形成在3位被取代的不饱和酰胺3-环戊烯-羧酸酰胺或2-甲基环戊烯-3-羧酸酰胺。
• [EN] OPTICALLY PURE ENANTIOMERS OF RUTHENIUM COMPLEXES AND USES THEREOF<br/>[FR] ÉNANTIOMÈRES OPTIQUEMENT PURS DE COMPLEXES DE RUTHÉNIUM ET LEURS UTILISATIONS
  申请人：CENTRE NAT RECH SCIENT

  公开号：WO2022008656A1

  公开（公告）日：2022-01-13

  The present invention relates to an optically pure (+) or (-) enantiomer of a ruthenium complex having formula (I) as well as the preparation method of said enantiomer, and uses thereof as catalyst, in particular in asymmetric olefin metathesis.

  本发明涉及一种光学纯的(+ )或(-) 鲁铂络合物对映体，其化学式为(I)，以及该对映体的制备方法和催化剂用途，特别是在不对称烯烃转化中的应用。
• Preparation of N-substituted phthalimides by the palladium-catalyzed carbonylation and coupling of o-dihalo aromatics and primary amines
  作者：Robert J. Perry、S. Richard Turner

  DOI：10.1021/jo00023a023

  日期：1991.11

  A novel method for the formation of N-substituted phthalimides is described which is based on the palladium-catalyzed carbonylation and coupling of o-dihalo aromatics and primary amines. Optimal conditions established for the reaction using o-diiodobenzene and aniline were DMAc (0.2 M), 115-degrees-C, 90 psi of CO, 3% PdCl2L2, and 2.4 equiv of DBU. This process is tolerant of a wide variety of functional groups and gives good yields of the desired products. Variables such as temperature, catalyst type and loading, CO pressure, solvent, and base were examined to optimize this reaction. The reaction of aniline with 1,2-dibromocyclopentene under similar conditions gave a variety of products.
• Perkin, Journal of the Chemical Society, 1894, vol. 65, p. 588
  作者：Perkin

  DOI：——

  日期：——