N-phenyl-α-(3-hydroxyphenyl)nitrone | 19865-56-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N-phenyl-α-(3-hydroxyphenyl)nitrone
• 英文别名: Nitrone, alpha-(m-hydroxyphenyl)-N-phenyl-；1-(3-hydroxyphenyl)-N-phenylmethanimine oxide
• CAS: 19865-56-6
• 化学式: C₁₃H₁₁NO₂
• 分子量: 213.236
• InChiKey: JWXNHLANTZVNHY-UVTDQMKNSA-N

物化性质

• 熔点：
  230 °C
• 沸点：
  426.7±47.0 °C(Predicted)
• 密度：
  1.245±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  苯并呋咱 、 N-phenyl-α-(3-hydroxyphenyl)nitrone 以 环己烷 为溶剂， 反应 24.0h， 以51%的产率得到1-hydroxy-2-(3'-hydroxyphenyl)benzimidazole-3-N-oxide
  参考文献：
  名称：

  Synthesis of Neutral Spin-Delocalized Electron Acceptors for Multifunctional Materials

  摘要：

  A new synthetic route to stable spin-delocalized radicals, annelated nitronyl nitroxides, has been developed on the basis of the condensation of benzofuroxan with aryl nitrones. The electronic structure of the resulting radicals was investigated through absorption spectroscopy, EPR, electrochemistry, and computation (DFT-UB3LYP). The annelated radicals exhibit electronic transitions in the near IR (850-900 nm) and are excellent electron acceptors (E-red similar to 0.0 vs SCE) ideal for the development of multifunctional magnetic materials.

  DOI：

  10.1021/ol701725r
• 作为产物：
  描述：

  间羟基苯甲醛 、 苯基羟胺 以 乙醇 为溶剂， 生成 N-phenyl-α-(3-hydroxyphenyl)nitrone
  参考文献：
  名称：

  Synthesis of Neutral Spin-Delocalized Electron Acceptors for Multifunctional Materials

  摘要：

  A new synthetic route to stable spin-delocalized radicals, annelated nitronyl nitroxides, has been developed on the basis of the condensation of benzofuroxan with aryl nitrones. The electronic structure of the resulting radicals was investigated through absorption spectroscopy, EPR, electrochemistry, and computation (DFT-UB3LYP). The annelated radicals exhibit electronic transitions in the near IR (850-900 nm) and are excellent electron acceptors (E-red similar to 0.0 vs SCE) ideal for the development of multifunctional magnetic materials.

  DOI：

  10.1021/ol701725r

文献信息

• Indium mediated allylation of CN compounds in aqueous media
  作者：H.M Sampath Kumar、S Anjaneyulu、E Jagan Reddy、J.S Yadav

  DOI：10.1016/s0040-4039(00)01676-2

  日期：2000.11
• JORGENSEN K. A.; SHABANA R.; SCHEIBYE S.; LAWESSON S.-O., BULL. SOC. CHIM. BELG., 1980, 89, NO 3, 247-253
  作者：JORGENSEN K. A.、 SHABANA R.、 SCHEIBYE S.、 LAWESSON S.-O.

  DOI：——

  日期：——
• KRISHAN, K.;SINGH, B., INDIAN J. CHEM., 1985, 23, N 7, 620-622
  作者：KRISHAN, K.、SINGH, B.

  DOI：——

  日期：——
• RUBBER COMPOSITION, AND PNEUMATIC TIRE AND CONVEYER BELT EACH MANUFACTURED USING SAME
  申请人：THE YOKOHAMA RUBBER CO., LTD.

  公开号：US20170327601A1

  公开（公告）日：2017-11-16

  The present invention is to provide: a rubber composition which has excellent wet grip performance and also has excellent wear resistance while maintaining high elongation; and a pneumatic tire and a conveyer belt each of which is manufactured using the rubber composition. The present invention provides: a rubber composition containing a modified diene rubber, in the modified rubber, from 0.02 to 4 mol % of double bonds contained in a diene rubber being modified into hydroxy groups by reacting at least one type of diene rubber selected from the group consisting of styrene butadiene rubbers, butadiene rubbers, and nitrile butadiene rubbers with a hydroxy group-containing nitrone compound having both a hydroxy group and a nitrone group; and a pneumatic tire and a conveyer belt each of which is manufactured using the rubber composition.
• US4153722A
  申请人：——

  公开号：US4153722A

  公开（公告）日：1979-05-08