1,4-bis(3-phenyltriazen-1-yl)benzene | 1616272-00-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(3-phenyltriazen-1-yl)benzene
• 英文别名: 1,4-Bis(3-phenyltriazenyl)benzene；N-[[4-(anilinodiazenyl)phenyl]diazenyl]aniline
• CAS: 1616272-00-4
• 化学式: C₁₈H₁₆N₆
• 分子量: 316.365
• InChiKey: WSFFVRFJSIKWKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  73.5
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  benzene-1,4-bis(diazonium) chloride 、 苯胺 在 sodium acetate 作用下， 以 乙醇 、 水 为溶剂， 以54.3%的产率得到1,4-bis(3-phenyltriazen-1-yl)benzene
  参考文献：
  名称：

  Synthesis and study of a polymer containing di- and triazenyl-p-phenylene groups

  摘要：

  A polymer containing di- and triazenyl-p-phenylene groups in the main chain was synthesized for the first time. Doping of newly synthesized poly(triazene-1,3-diyl-p-phenylenes) and poly(triazene-1,3-diyl-pdiphenylenes) with perchloric acid is studied. The introduction of azophenylene groups in the chain of a polymer containing triazenylphenylene groups has almost no effect on electrical conductivity. The electrical conductivity of these polymers increases from 10(-9) to 0.8 S/m with increasing doping degree. The replacement of phenylene by diphenylene groups slightly reduces the electrical conductivity of the polymer doped with perchloric acid, while in the case of iodine doping, by contrast, the electrical conductivity slightly increases.

  DOI：

  10.1134/s1070363214050132

文献信息

• Synthesis and study of a polymer containing di- and triazenyl-p-phenylene groups
  作者：A. A. Durgaryan、R. A. Arakelyan、N. A. Durgaryan、E. E. Matinyan

  DOI：10.1134/s1070363214050132

  日期：2014.5

  A polymer containing di- and triazenyl-p-phenylene groups in the main chain was synthesized for the first time. Doping of newly synthesized poly(triazene-1,3-diyl-p-phenylenes) and poly(triazene-1,3-diyl-pdiphenylenes) with perchloric acid is studied. The introduction of azophenylene groups in the chain of a polymer containing triazenylphenylene groups has almost no effect on electrical conductivity. The electrical conductivity of these polymers increases from 10(-9) to 0.8 S/m with increasing doping degree. The replacement of phenylene by diphenylene groups slightly reduces the electrical conductivity of the polymer doped with perchloric acid, while in the case of iodine doping, by contrast, the electrical conductivity slightly increases.