3-(Trifluoromethyl)phenyltrimethylaminium

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(Trifluoromethyl)phenyltrimethylaminium
• 英文别名: trimethyl-[3-(trifluoromethyl)phenyl]azanium
• 化学式: C10H13F3N+
• 分子量: 204.21
• InChiKey: ZLBCBMSHZLXLQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-(Trifluoromethyl)phenyltrimethylaminium 在 potassium ozonide 、 氨 作用下， 生成
  参考文献：
  名称：

  通过臭氧化物和氨之间的级联反应形成过氧亚硝酸盐，[ON−N−O−O]−

  摘要：

  [ONOO] -在 KO 3和氨之间的级联反应中以部分氟化苯胺基阳离子的形式出现。首次获得了过氧亚硝酸根离子的高分辨率结构数据，并通过拉曼光谱研究了单晶。

  DOI：

  10.1002/chem.202400585

文献信息

• METHOD OF PRODUCING OLEFIN HAVING 2 TO 4 CARBON ATOMS AND METHOD OF PRODUCING PROPYLENE
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20150225309A1

  公开（公告）日：2015-08-13

  A method of producing olefin having 2 to 4 carbon atoms, including a process of reacting at least one kind of a catalyst (D) selected from the group consisting of below catalysts (A) to (C) with synthesis gas in the presence of a dispersion medium through a Fischer-Tropsch reaction, in which the catalyst (A) contains iron and one to three kinds of elements selected from the group consisting of alkali metal and alkali earth metal, the catalyst (B) contains cobalt, provided that the catalyst (B) is a catalyst except a catalyst obtained by reducing a cobalt ion and an iron ion in a dispersion liquid or a solution containing the cobalt ion, the iron ion and a dispersant that interacts with the cobalt ion and the iron ion, and the catalyst (C) contains nickel or ruthenium.

  一种生产具有2至4个碳原子的烯烃的方法，包括通过费舍尔-特罗普反应，在存在分散介质的情况下，将来自以下催化剂（A）至（C）组成的组中至少一种催化剂（D）与合成气反应的过程。其中，催化剂（A）包含铁和从碱金属和碱土金属组成的组中选择的一到三种元素，催化剂（B）含有钴，但催化剂（B）是除了在含有钴离子、铁离子和与钴离子和铁离子相互作用的分散剂的分散液或溶液中还原得到的催化剂之外的催化剂，催化剂（C）含有镍或钌。
• METHOD OF MANUFACTURING OLEFIN HAVING 2 TO 4 CARBON ATOMS BY FISCHER-TROPSCH REACTION
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20140045955A1

  公开（公告）日：2014-02-13

  Provided are a method of manufacturing an olefin having 2 to 4 carbon atoms including: reacting a catalyst with synthesis gas through a Fischer-Tropsch reaction, thereby obtaining the olefin having 2 to 4 carbon atoms, in which the catalyst is a catalyst obtained by reducing the iron ion and the cobalt ion in a dispersion liquid or a solution containing the iron ion, the cobalt ion and a dispersant that interacts with the iron ion and the cobalt ion, and a method of manufacturing propylene, which uses the above manufacturing method.

  提供一种制造含有2至4个碳原子的烯烃的方法，包括：通过费舍尔-特普斯反应将催化剂与合成气反应，从而获得含有2至4个碳原子的烯烃，其中催化剂是通过在含有铁离子、钴离子和与铁离子、钴离子相互作用的分散液或溶液中还原铁离子和钴离子而获得的催化剂，以及一种利用上述制造方法制造丙烯的方法。
• SEALING AGENT FOR OPTICAL SEMICONDUCTOR ELEMENT, AND OPTICAL SEMICONDUCTOR ELEMENT
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP2159242A1

  公开（公告）日：2010-03-03

  An object of the present invention is to provide a highly transparent, heat-resistant and light-resistant sealing agent for an optical semiconductor which provides excellent adhesion, and is capable of stably maintaining its shape and preventing sedimentation of a phosphor when used to seal a light emitting device of an optical semiconductor device. A further object of the present invention is to provide an optical semiconductor device formed by using the sealing agent for an optical semiconductor device. The sealing agent for an optical semiconductor device, which comprises: a silicone resin having a cyclic ether-containing group in the molecular structure; a heat curing agent capable of reacting with the cyclic ether-containing group; and a fine particulate material of silicon oxide, and the sealing agent having a viscosity of 500 to 10,000 mPa·s measured by an E-type viscometer at 25°C at 5 rpm, a thixotropic value of 1.2 to 2.5 calculated by dividing a viscosity measured by the E-type viscometer at 25°C at 1 rpm by a viscosity measured at 10 rpm (viscosity at 1 rpm/viscosity at 10 rpm), and a minimum viscosity of 100 mPa·s or higher measured at 1s-1 in the temperature range of 25°C to a curing temperature by a parallel plate rheometer.

  本发明的目的是提供一种高透明度、耐热性和耐光性的光学半导体密封剂，该密封剂具有优异的粘附性，在用于密封光学半导体器件的发光装置时，能够稳定地保持其形状并防止荧光粉沉淀。本发明的另一个目的是提供一种通过使用光半导体器件密封剂形成的光半导体器件。光学半导体器件用密封剂包括：分子结构中含有环醚基团的硅树脂；能与环醚基团反应的热固化剂；氧化硅细颗粒材料，密封剂在 25℃、5 转/分条件下用 E 型粘度计测量的粘度为 500 至 10,000 mPa-s，触变值为 1.2 至 2.5，计算方法是用 E 型粘度计在 25℃、1 转/分钟时测得的粘度除以 10 转/分钟时测得的粘度（1 转/分钟时的粘度/10 转/分钟时的粘度），以及用平行板流变仪在 25℃至固化温度范围内以 1s-1 测得的最小粘度为 100 mPa-s 或更高。
• CHEMICALLY AMPLIFIED RESIST COMPOSITION AND PATTERNING PROCESS
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20180143532A1

  公开（公告）日：2018-05-24

  A chemically amplified resist composition comprising a quencher containing a quaternary ammonium iodide, dibromoiodide, bromodiiodide or triiodide, and an acid generator exhibits a sensitizing effect and an acid diffusion suppressing effect and forms a pattern having improved resolution, LWR and CDU.
• RESIST COMPOSITION AND PATTERNING PROCESS
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US20210294211A1

  公开（公告）日：2021-09-23

  A resist composition comprising a base polymer and a quencher containing an onium salt of iodized benzene ring-containing fluorosulfonamide offers a high sensitivity and minimal LWR or improved CDU, independent of whether it is of positive or negative tone.