N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine | 622837-47-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine
• 英文别名: mppma；3-methoxy-N-(pyridin-2-ylmethyl)propan-1-amine
• CAS: 622837-47-2
• 化学式: C₁₀H₁₆N₂O
• mdl: MFCD03725084
• 分子量: 180.25
• InChiKey: JFILXRCRMWIJCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  34.2
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT

反应信息

• 作为反应物：
  描述：

  manganese(II) chloride tetrahydrate 、 N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine 以 甲醇 为溶剂， 以94.1%的产率得到[manganese(II)(μ-Cl)2(N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine)](n)
  参考文献：
  名称：

  Synthesis, structure and magnetic properties of a linear-chain manganese(II) complex [Mn(μ-Cl)2(mppma)]n, where mppma is N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine

  摘要：

  N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine (abbreviated as mppma) and its complex [Mn(mu-Cl)(2)(mppma)](n) have been synthesized. Single-crystal X-ray diffraction analysis has revealed that in the complex, mppma acts as a didentate ligand bound to the Mn(II) ion through two nitrogen atoms; [MnCl2(mppma)] units are connected by double chloride bridges to form one-dimensional zigzag chains of edge-sharing distorted MnCl4(mppma) octahedra. The temperature-dependent magnetic susceptibility data have been explained with Fisher model, with parameters J = -0.25 cm(-1) and g = 1.99, indicating weak antiferromagnetic coupling. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00156-7

文献信息

• Integrated capture and conversion of CO2 to methane, methanol, or methanol and glycol
  申请人：Battelle Memorial Institute

  公开号：US11492302B2

  公开（公告）日：2022-11-08

  A process for producing methane or methanol includes combining a hydrogenation catalyst, hydrogen, and CO2 with a condensed phase solution comprising an amine under conditions effective to form methane or methanol, and water. A process for coproduction of methanol and a glycol includes combining an epoxide, a hydrogenation catalyst, hydrogen, and CO2 with a condensed phase solution comprising an amine under conditions effective to form methanol and a glycol.

  一种生产甲烷或甲醇的工艺包括在有效形成甲烷或甲醇的条件下，将氢化催化剂、氢气和二氧化碳与包含胺的凝聚相溶液和水结合。 一种共同生产甲醇和乙二醇的工艺，包括在有效形成甲醇和乙二醇的条件下，将环氧化物、氢化催化剂、氢气和二氧化碳与包含胺的凝聚相溶液结合。
• NEAR INFRARED ABSORBING COMPOSITION, NEAR INFRARED CUT FILTER, METHOD OF MANUFACTURING NEAR INFRARED CUT FILTER, DEVICE, METHOD OF MANUFACTURING COPPER-CONTAINING POLYMER, AND COPPER-CONTAINING POLYMER
  申请人：FUJIFILM Corporation

  公开号：US20180094086A1

  公开（公告）日：2018-04-05

  The near infrared absorbing composition includes: a copper-containing polymer having a copper complex site at a polymer side chain; and a solvent, in which the copper complex site includes a site multidentate-coordinated to a copper atom and at least one selected from the group consisting of a site monodentate-coordinated to a copper atom and a counter ion to a copper complex skeleton, and a polymer main chain and a copper atom at the copper complex site are bonded to each other through the site monodentate-coordinated to a copper atom or the counter ion.
• INTEGRATED CAPTURE AND CONVERSION OF CO2 TO METHANE, METHANOL, OR METHANOL AND GLYCOL
  申请人：Battelle Memorial Institute

  公开号：US20210214287A1

  公开（公告）日：2021-07-15

  A process for producing methane or methanol includes combining a hydrogenation catalyst, hydrogen, and CO 2 with a condensed phase solution comprising an amine under conditions effective to form methane or methanol, and water. A process for coproduction of methanol and a glycol includes combining an epoxide, a hydrogenation catalyst, hydrogen, and CO 2 with a condensed phase solution comprising an amine under conditions effective to form methanol and a glycol.